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CO_2+DME混合体系跨临界吸收式动力循环热转换机理 被引量:1
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作者 冯乐军 郑丹星 +1 位作者 陈静 史琳 《工程热物理学报》 EI CAS CSCD 北大核心 2019年第5期968-973,共6页
本文以CO_2+DME二元体系作为吸收式动力循环的潜力工质对.引入"化学热机"概念,用子循环划分的方法将整个循环分为化学热机子循环和热机子循环.基于循环系统的操作压力和与热源的匹配程度,对比分析了CO_2+DME体系跨临界操作条... 本文以CO_2+DME二元体系作为吸收式动力循环的潜力工质对.引入"化学热机"概念,用子循环划分的方法将整个循环分为化学热机子循环和热机子循环.基于循环系统的操作压力和与热源的匹配程度,对比分析了CO_2+DME体系跨临界操作条件优于亚临界和超临界条件的本质原因.建立了一套典型的CO_2+DME跨临界吸收式动力循环模拟模型.基于文献报道的气液相平衡数据,选择PR方程作为物性计算模型,分别计算了循环物流的组成、流率、焓值和熵值.根据循环系统的T-s和lgp-h图,分别分析了两个子循环之间的耦合关系与能量转换.从分析结果可以看出,由于耦合了化学热机,不仅实现了对能量的梯级利用,同时进一步降低了透平出口压力,热转功过程得到强化,使得热机子循环热转功效率由14.06%提升到15.79%.最后,采用参数分析法,探索了不同吸收温度(25, 30, 35和40℃)下,化学热机子循环高压端压力对整个循环热转功效率的影响.结果表明,降低化学热机子循环运行压力是循环优化的一个方向,有助于提高对能量的二次利用率。 展开更多
关键词 吸收式动力循环 化学 能量梯级利用 热转功效率 CO2+DME
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Analyses of thermodynamic performance for the endoreversible Otto cycle with the concepts of entropy generation and entransy 被引量:7
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作者 WU YanQiu 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2017年第5期692-700,共9页
In this paper, the endoreversible Otto cycle is analyzed with the entropy generation minimization and the entransy theory. The output power and the heat-work conversion efficiency are taken as the optimization objecti... In this paper, the endoreversible Otto cycle is analyzed with the entropy generation minimization and the entransy theory. The output power and the heat-work conversion efficiency are taken as the optimization objectives, and the relationships of the output power, the heat-work conversion efficiency, the entropy generation rate, the entropy generation numbers, the entransy loss rate, the entransy loss coefficient, the entransy dissipation rate and the entransy variation rate associated with work are discussed. The applicability of the entropy generation minimization and the entransy theory to the analyses is also analyzed. It is found that smaller entropy generation rate does not always lead to larger output power, while smaller entropy generation numbers do not always lead to larger heat-work conversion efficiency, either. In our calculations, both larger entransy loss rate and larger entransy variation rate associated with work correspond to larger output power, while larger entransy loss coefficient results in larger heat-work conversion efficiency. It is also found that the concept of entransy dissipation is not always suitable for the analyses because it was developed for heat transfer. 展开更多
关键词 entropy generation minimization entransy finite time thermodynamics endoreversible Otto cycle applied mathematics
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Quantum dot-sensitized solar cells employing Pt/C_(60) counter electrode provide an efficiency exceeding 2%
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作者 YUE GenTian WU JiHuai +4 位作者 XIAO YaoMing LIN JianMing HUANG MiaoLiang FAN LeQing LAN Zhang 《Science China Chemistry》 SCIE EI CAS 2013年第1期93-100,共8页
A microporous platinum/fullerenes (Pt/C 60) counter electrode was prepared by using a facile rapid thermal decomposition method,and the quantum-dot sensitized solar cell (QDSSC) of Pt/C 60-TiO 2-CdS-ZnS and Pt/C 60-Ti... A microporous platinum/fullerenes (Pt/C 60) counter electrode was prepared by using a facile rapid thermal decomposition method,and the quantum-dot sensitized solar cell (QDSSC) of Pt/C 60-TiO 2-CdS-ZnS and Pt/C 60-TiO 2-CdTe-ZnS was fabrication.The technique forms a good contact between QDs and TiO 2 films.The photovoltaic performances of the as-prepared cells were investigated.The QDSSCs with Pt/C 60 counter electrode show high power conversion efficiency of 1.90% and 2.06%,respectively (under irradiation of a simulated solar light with an intensity of 100 mW cm 2),which is comparable to the one fabricated using conventional Pt electrode. 展开更多
关键词 counter electrode quantum dot microporous platinum/fullerenes solar cell
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