A novel method for predicting hotspots and coldspots using support vector machine （SVM） based on statistical learning theory is developed. This method is applied to published 303 hot and 48 cold open reading frames ...A novel method for predicting hotspots and coldspots using support vector machine （SVM） based on statistical learning theory is developed. This method is applied to published 303 hot and 48 cold open reading frames （ORFs） in Saccharomyces cerevisiae. The sequence features of general dinucleotide abundance and dinucleotide abundance based on codon usage are extracted, and then the data sets are classified with different parameters and kernel functions combined with the method of two-fold cross validation. The result indicates that 87.47% accuracy can be reached when classifying hot and cold ORF sequences with the kernel of radial basis function combined with dinucleotide abundance based on codon usage.展开更多
The potential combustion-supporting agents for three kinds of coals were selected according to the Thermal Gravity Analysis (TG). The TG analysis shows that the addition of FeCl3 can reduce the ignition point of clara...The potential combustion-supporting agents for three kinds of coals were selected according to the Thermal Gravity Analysis (TG). The TG analysis shows that the addition of FeCl3 can reduce the ignition point of clarain and fusain from Guangxi and also the raw coal from Xinwen. The combustion-supporting effect of FeCl3 on the clarain is quite obvious, with the maximum reduction of ignition point reaching 90 ℃ and that of the burn-out point reaching 95 ℃. What is more, it can make the coal burn more completely. The relationship between the amount of FeCl3 and the ig- nition point was also investigated and the optimum amount of FeCl3 obtained. When FeCl3 is added in doses of 6%, 4%, 2%, and 1%, the reduction of ignition point is proportional to the amount of agent. If 6% of FeCl3 is added, the combus- tion-supporting effect is very significant; while if only 1% of FeCl3 is added, the combustion-supporting effect can be negligible. Therefore the optimum amount of FeCl3 is between 3% and 6% for achieving an obvious combus- tion-supporting effect. In addition, the combustion supporting mechanism of FeCl3 was also studied, which is the com- bined action of chloride and iron in the compound.展开更多
The catalysts Ni/Al2O3, Ni/ZrO2-CeO2-Al2O3 and Ni/CuO-ZrO2-CeO2-Al2O3 were prepared by the co-precipitation method at a pH of 9 using Na2CO3 as the precipitant. The Ni loading(mass fraction) of the catalysts was 10%. ...The catalysts Ni/Al2O3, Ni/ZrO2-CeO2-Al2O3 and Ni/CuO-ZrO2-CeO2-Al2O3 were prepared by the co-precipitation method at a pH of 9 using Na2CO3 as the precipitant. The Ni loading(mass fraction) of the catalysts was 10%. The ignition process on the catalysts for the autothermal reforming of methane to hydrogen was investigated and the surface properties of the catalysts were characterized by XPS. The results showed that the Ni/Al2O3 catalyst could not ignite the process of autothermal reforming of methane to hydrogen. However, the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst could ignite the process of autothermal reforming of methane to hydrogen at lower reaction temperature(650 ℃) with the conversion of methane reaching 76%. The result of XPS analysis indicated that the promoters could change the binding energy(BE) of Ni2p3/2 obviously. The species of Cu in the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst comprised Cu2 O and Cu2+. The formation of ZrO2-CeO2 solid solution and a large amount of Cu2 O might be the reason leading to good oxygen storage capacity and mobility of lattice oxygen of the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst, which could ignite the process of autothermal reforming of methane to hydrogen at lower reaction temperature.展开更多
Energy conversion and utilization, particularly carbon-based fuel burning in air phase, have caused great environmental pollution and serious problems to society. The reactions in water phase may have the potential to...Energy conversion and utilization, particularly carbon-based fuel burning in air phase, have caused great environmental pollution and serious problems to society. The reactions in water phase may have the potential to realize clean and efficient energy conversion and utilization. Coal gasification in supercritical water is a typical carbon-based fuel conversion process in water phase, and it takes the advantages of the unique chemical and physical properties of supercritical water to convert organic matter in coal to H2 and CO2. N, S, P, Hg and other elements are deposited as inorganic salts to avoid pollution emission. The State Key Laboratory of Multiphase Flow in Power Engineering has obtained extensive experimental and theoretical results based on coal gasification in supercritical water. Supercritical water fluidized bed reactor was developed for coal gasification and seven kinds of typical feedstock were selected. The hydrogen yield covers from 0.67 to 1.74 Nm3/kg and the carbon gasification efficiency is no less than 97%. This technology has a bright future in industrialization not only in electricity generation but also in hydrogen production and high value-added chemicals. Given the gas yield obtained in laboratory-scale unit, the hydrogen production cost is U.S.$ 0.111 Nm3 when the throughput capacity is 2000 t/d. A novel thermodynamic cycle power generation system based on coal gasification in supercritical water was proposed with the obvious advantages of high coal-electricity conversion efficiency and zero pollutant emission. The cost of U.S.$ 3.69 billion for desulfuration, denitration and dust removal in China in 2013 would have been saved with this technology. Five kinds of heat supply methods are analyzed and the rates of return of investment are roughly estimated. An integrated cooperative innovation center called a new type of high-efficient coal gasification technology and its large-scale utilization was founded to enhance the industrialization of the technology vigorously.展开更多
文摘A novel method for predicting hotspots and coldspots using support vector machine （SVM） based on statistical learning theory is developed. This method is applied to published 303 hot and 48 cold open reading frames （ORFs） in Saccharomyces cerevisiae. The sequence features of general dinucleotide abundance and dinucleotide abundance based on codon usage are extracted, and then the data sets are classified with different parameters and kernel functions combined with the method of two-fold cross validation. The result indicates that 87.47% accuracy can be reached when classifying hot and cold ORF sequences with the kernel of radial basis function combined with dinucleotide abundance based on codon usage.
文摘The potential combustion-supporting agents for three kinds of coals were selected according to the Thermal Gravity Analysis (TG). The TG analysis shows that the addition of FeCl3 can reduce the ignition point of clarain and fusain from Guangxi and also the raw coal from Xinwen. The combustion-supporting effect of FeCl3 on the clarain is quite obvious, with the maximum reduction of ignition point reaching 90 ℃ and that of the burn-out point reaching 95 ℃. What is more, it can make the coal burn more completely. The relationship between the amount of FeCl3 and the ig- nition point was also investigated and the optimum amount of FeCl3 obtained. When FeCl3 is added in doses of 6%, 4%, 2%, and 1%, the reduction of ignition point is proportional to the amount of agent. If 6% of FeCl3 is added, the combus- tion-supporting effect is very significant; while if only 1% of FeCl3 is added, the combustion-supporting effect can be negligible. Therefore the optimum amount of FeCl3 is between 3% and 6% for achieving an obvious combus- tion-supporting effect. In addition, the combustion supporting mechanism of FeCl3 was also studied, which is the com- bined action of chloride and iron in the compound.
基金supported by the Guangdong Provincial Natural Science Foundation (030514)the Science and Technology Plan of Guangdong Province of China (2004B33401006)the Doctoral Startup Foundation of Guangdong Pharmaceutical University
文摘The catalysts Ni/Al2O3, Ni/ZrO2-CeO2-Al2O3 and Ni/CuO-ZrO2-CeO2-Al2O3 were prepared by the co-precipitation method at a pH of 9 using Na2CO3 as the precipitant. The Ni loading(mass fraction) of the catalysts was 10%. The ignition process on the catalysts for the autothermal reforming of methane to hydrogen was investigated and the surface properties of the catalysts were characterized by XPS. The results showed that the Ni/Al2O3 catalyst could not ignite the process of autothermal reforming of methane to hydrogen. However, the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst could ignite the process of autothermal reforming of methane to hydrogen at lower reaction temperature(650 ℃) with the conversion of methane reaching 76%. The result of XPS analysis indicated that the promoters could change the binding energy(BE) of Ni2p3/2 obviously. The species of Cu in the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst comprised Cu2 O and Cu2+. The formation of ZrO2-CeO2 solid solution and a large amount of Cu2 O might be the reason leading to good oxygen storage capacity and mobility of lattice oxygen of the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst, which could ignite the process of autothermal reforming of methane to hydrogen at lower reaction temperature.
基金supported by the National Natural Science Foundation of China(Grant Nos.5132301151306145&51236007)
文摘Energy conversion and utilization, particularly carbon-based fuel burning in air phase, have caused great environmental pollution and serious problems to society. The reactions in water phase may have the potential to realize clean and efficient energy conversion and utilization. Coal gasification in supercritical water is a typical carbon-based fuel conversion process in water phase, and it takes the advantages of the unique chemical and physical properties of supercritical water to convert organic matter in coal to H2 and CO2. N, S, P, Hg and other elements are deposited as inorganic salts to avoid pollution emission. The State Key Laboratory of Multiphase Flow in Power Engineering has obtained extensive experimental and theoretical results based on coal gasification in supercritical water. Supercritical water fluidized bed reactor was developed for coal gasification and seven kinds of typical feedstock were selected. The hydrogen yield covers from 0.67 to 1.74 Nm3/kg and the carbon gasification efficiency is no less than 97%. This technology has a bright future in industrialization not only in electricity generation but also in hydrogen production and high value-added chemicals. Given the gas yield obtained in laboratory-scale unit, the hydrogen production cost is U.S.$ 0.111 Nm3 when the throughput capacity is 2000 t/d. A novel thermodynamic cycle power generation system based on coal gasification in supercritical water was proposed with the obvious advantages of high coal-electricity conversion efficiency and zero pollutant emission. The cost of U.S.$ 3.69 billion for desulfuration, denitration and dust removal in China in 2013 would have been saved with this technology. Five kinds of heat supply methods are analyzed and the rates of return of investment are roughly estimated. An integrated cooperative innovation center called a new type of high-efficient coal gasification technology and its large-scale utilization was founded to enhance the industrialization of the technology vigorously.
