Catalytic converting CO2 into fuels with the help of solar energy is regarded as‘dream reaction’,as both energy crisis and environmental issue can be mitigated simultaneously.However,it is still suffering from low e...Catalytic converting CO2 into fuels with the help of solar energy is regarded as‘dream reaction’,as both energy crisis and environmental issue can be mitigated simultaneously.However,it is still suffering from low efficiency due to narrow solar-spectrum utilization and sluggish heterogeneous reaction kinetics.In this work,we demonstrate that catalytic reduction of CO2 can be achieved over Au nanoparticles(NPs)deposited rutile under full solar-spectrum irradiation,boosted by solar-heating effect.We found that UV and visible light can initiate the reaction,and the heat from IR light and local surface-plasmon resonance relaxation of Au NPs can boost the reaction kinetically.The apparent activation energy is determined experimentally and is used to explain the superior catalytic activity of Au/rutile to rutile in a kinetic way.We also find the photo-thermal synergy in the Au/rutile system.We envision that this work may facilitate understanding the kinetics of CO2 reduction and developing feasible catalytic systems with full solar spectrum utilization for practical artificial photosynthesis.展开更多
To reach the target of smaller pressure drop and better heat transfer performance, packed beds with small tube-to-particle diameter ratio(D/dp<10) have now been considered in many areas. Fluid-to-wall heat transfer...To reach the target of smaller pressure drop and better heat transfer performance, packed beds with small tube-to-particle diameter ratio(D/dp<10) have now been considered in many areas. Fluid-to-wall heat transfer coefficient is an important factor determining the performance of this type of beds. In this work, local fluid-to-wall heat transfer characteristic in packed beds was studied by Computational Fluid Dynamics(CFD) at different Reynolds number for D/dp=1.5, 3.0 and 5.6. The results show that the fluid-to-wall heat transfer coefficient is oscillating along the bed with small tube-to-particle diameter ratio. Moreover, this phenomenon was explained by field synergy principle in detail. Two arrangement structures of particles in packed beds were recommended based on the synergy characteristic between flow and temperature fields. This study provides a new local understanding of fluid-to-wall heat transfer in packed beds with small tube-to-particle diameter ratio.展开更多
基金supported by the Belt and Road Initiative by Chinese Academy of Sciencesthe National Natural Science Foundation of China(21673052,11404074)
文摘Catalytic converting CO2 into fuels with the help of solar energy is regarded as‘dream reaction’,as both energy crisis and environmental issue can be mitigated simultaneously.However,it is still suffering from low efficiency due to narrow solar-spectrum utilization and sluggish heterogeneous reaction kinetics.In this work,we demonstrate that catalytic reduction of CO2 can be achieved over Au nanoparticles(NPs)deposited rutile under full solar-spectrum irradiation,boosted by solar-heating effect.We found that UV and visible light can initiate the reaction,and the heat from IR light and local surface-plasmon resonance relaxation of Au NPs can boost the reaction kinetically.The apparent activation energy is determined experimentally and is used to explain the superior catalytic activity of Au/rutile to rutile in a kinetic way.We also find the photo-thermal synergy in the Au/rutile system.We envision that this work may facilitate understanding the kinetics of CO2 reduction and developing feasible catalytic systems with full solar spectrum utilization for practical artificial photosynthesis.
基金supported by the National Natural Science Foundation of China(5127618151476173)the National Basic Research Program of China(2011CB 710705)
文摘To reach the target of smaller pressure drop and better heat transfer performance, packed beds with small tube-to-particle diameter ratio(D/dp<10) have now been considered in many areas. Fluid-to-wall heat transfer coefficient is an important factor determining the performance of this type of beds. In this work, local fluid-to-wall heat transfer characteristic in packed beds was studied by Computational Fluid Dynamics(CFD) at different Reynolds number for D/dp=1.5, 3.0 and 5.6. The results show that the fluid-to-wall heat transfer coefficient is oscillating along the bed with small tube-to-particle diameter ratio. Moreover, this phenomenon was explained by field synergy principle in detail. Two arrangement structures of particles in packed beds were recommended based on the synergy characteristic between flow and temperature fields. This study provides a new local understanding of fluid-to-wall heat transfer in packed beds with small tube-to-particle diameter ratio.
