填埋气体迁移气-热-力耦合动力学模型的研究

基于连续介质力学 势弹性力学原理 ,运用多场耦合理论建立了填埋场中可压缩垃圾气体迁移耦合的动力学模型 ,并采用摄动法及积分变换法对该强非线性数学模型进行拟解析求解。通过算例对比分析 ,探讨了耦僵动力场中气压、温度和应力变化对可压缩气体迁移的影响 ,得出了垃圾气体迁移过程中的孔隙压力分布规律。结果表明 ,三场耦合作用与非耦合作用相对差别较大 ,耦合效应不能忽略。这为定量化研究垃圾气体在填埋场中的扩散状况以及污染气体的排放和收集、防止二次污染提供了可靠的理论依据。

基于气液动力学热耦合模型的动力电池SOC估算

电池解析模型通常在准确估算电池在线荷电状态(State of charge,SOC)方面起到关键作用。分析气液动力学与电学的物理相似性原理,研究气体分子与锂离子之间扩散/平衡的内在联系、气液系统与锂离子电池之间的观测量滞后状态量的等效机制,改进气液动力学与电学之间的参数映射关系,建立直接耦合温度特性的气液动力学电池模型。依据电池工作中的温度场分布特性与能量守恒原理,构建气液动力学-热耦合模型,基于该模型与扩展卡尔曼滤波算法设计高效的锂离子电池在线SOC估算方法。以内置温度传感器的锂离子动力电池为研究对象,在多种恒流与动态测试工况下电池内部最高温度估计误差小于1.2K,在线SOC估计误差低于1.8%。提出的在线SOC估算方法具有良好的估计精度,以及较强抵抗初值输入误差的能力。

Pyrolysis Characteristics and Kinetics of Methyl Oleate Based on TG-FTIR Method

The thermal decomposition characteristics of methyl oleate were preliminarily investigated under nitrogen atmo-sphere by a thermogravimetric analyzer when the ester was heated at a heating rate of 10℃/min from room temperature to 600℃. Furthermore, the pyrolytic and kinetic characteristics of methyl oleate were intensively studied at different heating rates. The gaseous species obtained during thermal decomposition were also identiifed by the TG-FTIR coupling analysis. The results showed that the pyrolysis of methyl oleate proceeded in three stages, viz. the drying stage, the main pyrolysis stage and the residual pyrolysis stage. The initial decomposition temperature, the maximum weight loss temperature, the peak decomposition temperature and the rate of maximum weight loss of methyl oleate increased with the increasing heating rates. Gaseous CO, CO2 and H2O were the typical decomposition products from pyrolysis of methyl oleate. In addition, a kinetic model for thermal decomposition of methyl oleate was built up based on the experimental results using the Coats-Redfern integral method and the multiplelinear regression method. The activation energy, the preexponential factor, the reaction order and the kinetic equation for thermal decomposition of methyl oleate were obtained. Comparison of the experimental data with the calculated ones and analysis of statistical errors of pyrolysis ratios demonstrated that the kinetic model was reliable for studying the pyrolysis of methyl oleate. Finally, the kinetic compensation effect between the preexponential factors and the activation energy in the pyrolysis of methyl oleate was also conifrmed.

Numerical Simulation of Direct-contact Condensation from a Supersonic Steam Jet in Subcooled Water

The phenomenon of direct-contact condensation,used in steam driven jet injectors,nuclear reactor emergency core cooling systems and direct-contact heat exchangers,was investigated computationally by introducing a thermal equilibrium model for direct-contact condensation of steam in subcooled water.The condensation model presented was a two resistance model which takes care of the heat transfer process on both sides of the interface and uses a variable steam bubble diameter.The injection of supersonic steam jet in subcooled water tank was simulated using the Euler-Euler multiphase flow model of Fluent 6.3 code with the condensation model incorporated. The findings of the computational fluid dynamics（CFD） simulations were compared with the published experimental data and fairly good agreement was observed between the two,thus validating the condensation model.The results of CFD simulations for dimensionless penetration length of steam plume varies from 2.73-7.33,while the condensation heat transfer coefficient varies from 0.75-0.917 MW·（m ^2 ·K）^ -1 for water temperature in the range of 293-343 K.

Prediction of Structure-H Gas Hydrate Formation Conditions for Reservoir Fluids

In this work, a thermodynamic model is developed for prediction of structure H hydrate formation. The model combines the Peng-Robinson equation of state for the vapor, liquid and aqueous phases with the extended Ng-Robinson hydrate model for gas hydrate formation of all three structures. The parameters of 14 structure- H hydrate formers are determined based on the experimental data of structure-H hydrates in the literature. The expression of fugacity of water in the empty hydrate phase is correlated for calculating structure-H hydrate formation conditions in the absence of free water. The model is tested by predicting hydrate formation conditions of a number of structure-H hydrate forming systems which are in good agreement with the experimental data. The proposed model is also applied to the prediction of hydrate formation conditions for various reservoir fluids such as natural gas and gas condensate.

Kinetic Modeling of Isothermal or Non-isothermal Adsorption in a Pellet：Application to Adsorption Heat Pumps

Understanding the interaction between a fluid and a solid phase is of fundamental importance to the design of an adsorption process.Because the heat effects associated with adsorption are comparatively large,the as-sumption of isothermal behavior is a valid approximation only when uptake rates are relatively slow.In this article,we propose to determine when it is needed to choose the isothermal or non-isothermal assumption according to two physical parametersα（ratio convection/capacity） andβ（quantity of energy/capacity） .The proposed problem is solved by a mathematical method in the Laplace domain.Whenα→∞（infinitely high heat transfer coefficient） or β→0（infinitely large heat capacity） ,the limiting case is isothermal.When the diffusion is rapid（α10） the kinetics of sorption is controlled entirely by heat transfer.If the adsorption process is to be used as a heat pump,it shall be represented by an isotherm model withαandβas high as possible.

Experimental study on co-pyrolysis characteristics of typical medical waste compositions

Thermal decomposition of 21 kinds of binary mixtures between typical medical compositions was investigated under nitrogen conditions by dynamic thermogravimetric analysis(TGA) at 25–800 °C. The weighed sum method(WSM) coupled with thermal analysis was applied to study the interaction between components. Then, co-pyrolysis kinetic model of the binary mixtures(tube for transfusion(TFT) and gauze) was established to verify the reliability of conclusions. The results show the follows. 1) Strong or weak interactions are shown between binary mixtures containing polyvinyl chloride(PVC), the main ingredient of TFT. The addition of other medical waste could enhance first stage decomposition of TFT. While, the secondary stage pyrolysis may be suppressed or enhanced or not affected by the addition. 2) There exists no interaction between catheter and other component, the DTG peak temperature representing Ca CO3 decomposition in catheter fraction is obviously lower than that of pure catheter; while,the shape of DTG peak keeps unchanged. 3) No evident reaction occurs between the other mix-samples, it is considered that their co-pyrolysis characteristics are linear superposition of mono-component pyrolysis characteristics.

Comparative Study on the Pyrolysis Behaviors of Corn Stalk and Pine Sawdust Using TG-MS

The pyrolysis behaviors of corn stalk(CS) and pine sawdust(PS) were investigated with thermogravimetry-mass spectroscopy(TG-MS).The peak temperature of PS was higher and the main decomposition region shifted to higher temperature compared with CS,which implied that the hemicellulose and cellulose of PS were more thermally stable than those of CS.However,the hemicellulose and cellulose of PS were more easily decomposed into gaseous products than those of CS during pyrolysis.The pyrolysis process of biomass can be described by a two-step independent first-order kinetic model.This fundamental study provides a basic insight into the biomass pyrolysis,which is beneficial for understanding the pyrolysis mechanism of biomass and developing an advanced thermal process for effective utilization of biomass.

Research status of soil frost-heave theory and frost-heave prediction models

Soil frost heaving is a complex physical, mechanical, and chemical synthesis process. This paper summarizes the frost-heaving theory over half a century, including the capillary theory, the frozen-fringe theory, and those achievements recently made by scholars. In this paper, we also discus researching achievements of the soil-prediction model during the past 40 years, including the water-dynamics model, the rigid-ice model, the segregation-potential model, and the thermo-dynamic model. This summary and discussion will enable readers to understand the latest direction of research; it also summarizes the development of frost-heave prediction models and their advantages and shortcomings.

Two-Phase Flow Modeling in a Single Closed Loop Pulsating Heat Pipes

Mathematical modeling of pulsating heat pipes through ‘first’ principles is a contemporary problem which remains quite elusive. Simplifications and assumptions made in all the modeling approaches developed so far render them unsuitable for engineering design. In this paper, a more realistic modeling scheme is presented which provides considerable try for thought toward the next progressive step. At high enough heat flux level, closed loop pulsating heat pipes experience a bulk internal unidirectional fluid circulation. Under such a condition, conventional two-phase flow modeling in capillary tubes may be applied. This has been attempted for single-loop PHPs. A homogeneous model and a separated two-fluid flow model based on simultaneous conservation of mass, momentum and energy, have been developed for an equivalent ‘open flow’ system. The model allows prediction of two-phase flow parameters in each sub-section of the device thereby providing important insights into its operation. The concept of ‘void fraction constraint’ in pulsating heat pipe operation is introduced and its relevance to future modeling attempts is outlined.

Kinetic and Thermodynamic Studies of Acid Scarlet 3R Adsorption onto Low-cost Adsorbent Developed from Sludge and Straw

A low-cost adsorbent was prepared from sludge and straw by pyrolysis in a dried state with the surface area of the adsorbent of 829.49 ma. g-l, micropore volume of 0.176 cm2·g-1 and average pore radius of 5.0 nm. The kinetic, equilibrium isotherm and thermodynamic characteristics of trisodium 1-（1-naphthylazo）-2-hydroxynaphthalene- 4＇,6,8-trisulphonate （acid scarlet 3R） onto the adsorbent from sludge and straw were investigated. The results indicated that the pseudo second order adsorption was the predominant adsorption mechanism of acid scarlet 3R. Thus, the adsorption phenomenon was suggested as a chemical process. The adsorption data were fitted better with Langmuir model than Freundlich model, indicating that the adsorption of acid scarlet 3R belonged to the monolayer adsorption and mainly occurred in micropores.

Climate variability and predictability associated with the Indo-Pacific Oceanic Channel Dynamics in the CCSM4 Coupled System Model

An experiment using the Community Climate System Model(CCSM4), a participant of the Coupled Model Intercomparison Project phase-5(CMIP5), is analyzed to assess the skills of this model in simulating and predicting the climate variabilities associated with the oceanic channel dynamics across the Indo-Pacific Oceans. The results of these analyses suggest that the model is able to reproduce the observed lag correlation between the oceanic anomalies in the southeastern tropical Indian Ocean and those in the cold tongue in the eastern equatorial Pacific Ocean at a time lag of 1 year. This success may be largely attributed to the successful simulation of the interannual variations of the Indonesian Throughflow, which carries the anomalies of the Indian Ocean Dipole(IOD) into the western equatorial Pacific Ocean to produce subsurface temperature anomalies, which in turn propagate to the eastern equatorial Pacific to generate ENSO. This connection is termed the "oceanic channel dynamics" and is shown to be consistent with the observational analyses. However, the model simulates a weaker connection between the IOD and the interannual variability of the Indonesian Throughflow transport than found in the observations. In addition, the model overestimates the westerly wind anomalies in the western-central equatorial Pacific in the year following the IOD, which forces unrealistic upwelling Rossby waves in the western equatorial Pacific and downwelling Kelvin waves in the east. This assessment suggests that the CCSM4 coupled climate system has underestimated the oceanic channel dynamics and overestimated the atmospheric bridge processes.

Modeling of metadynamic recrystallization kinetics after hot deformation of low-alloy steel Q345B

Based on the steady-state strain measured by single-pass hot compression tests,the method by a double-pass hot compression testing was developed to measure the metadynamic-recrystallization kinetics.The metadynamic recrystallization behavior of low-alloy steel Q345B during hot compression deformation was investigated in the temperature range of 1 000-1 100℃,the strain rate range of 0.01-0.10 s -1 and the interpass time range of 0.5-50 s on a Gleeble-3500 thermo-simulation machine.The results show that metadynamic recrystallization during the interpass time can be observed.As the deformation temperature and strain rate increase,softening caused by metadynamic recrystallization is obvious.According to the data of thermo-simulation,the metadynamic recrystallization activation energy is obtained to be Qmd=100.674 kJ/mol and metadynamic recrystallization kinetics model is set up.Finally,the error analysis of metadynamic recrystallization kinetics model proves that the model has high accuracy(correlation coefficient R=0.988 6).

Zirconium Diboride Powders Synthesized by Boro/Carbothermal Reaction Using Sol-Gel Technology

A single phase of zirconium diboride （ZrB2） powder was successfully synthesized by sol-gel method in Zr-B-C-O system, using zirconium oxychloride （ZrOC12 ~ 8H20）, nano-scale boron and suerose（C12H22011）as the starting materials and propylene oxide （PO） as complexing agent at a low temperature. Simultaneously, the experimen- tal and theoretical studies of ZrB2 synthesized by boro/carbothermal reduction from novel sol-gel technology were discussed. The results indicated that the pure rod-like ZrB2 powder without residual ZrO2 phase could be obtained with a B/Zr molar ratio of 3.5 at 1 400~C in argon atmosphere. Besides, in this study, a kinetic model for the Zr-B-C-O sys- tem producing ZrB2 by boro/carbothermal reaction was established based on thermodynamic analysis. It was also ob- served that, with the increase of reaction temperature, the reaction which produced ZrB2 powders changed from the borothermal reaction to boro/carbothermal reaction in the Zr-B-C-O system.

Modeling and simulation of dynamic performance of horizontal steam-launch system

Based on theory of variable-mass system thermodynamics, the dynamic mathematic models of each component of the horizontal steam-launch system were established, and by the numerical simulation of the system launching process, the thermodynamics and kinetics characteristics of the system with three valves of different flow characteristics were got. The simulation results show that the values of the peak-to-average ratios of dimensionless acceleration with the equal percentage valve, the linear valve and the quick opening valve are 1.355, 1.614 and 1.722, respectively, and the final values of the dimensionless velocities are 0.843, 0.957 and 1.0, respectively. In conclusion, the value of the dimensionless velocity with the equal percentage valve doesn't reach the set value of 0.90 when the dimensionless displacement is 0.82, while the system with the linear valve can meet the launching requirement, as well as the fluctuation range of dimensionless acceleration is less than that of the quick opening valve. Therefore, the system with the linear valve has the best performance among the three kinds of valves.

Three Dimensional Numerical Simulation of Convection-Condensation of Vapor with High Concentration Air in Tube with Inserts

A three-dimensional numerical model is presented for studying the convection-condensation of mixture with vapor in a tube with edgefold-twisted-tape inserts under transition flow.According to the diffusion layer theory and laminar species transport,a condensation model with user defined function is proposed and compared with heat and mass transfer analogy and experimental test.With the condensation model,the influences of gap width and op-erating parameters on thermal-hydrodynamics performance are simulated.As the gap width increases,convection and condensation heat transfer increase initially and then decrease,while convection heat transfer increases sharply and then decreases slightly.Increasing vapor fraction has a significant effect on condensation heat transfer but it has little effect on convective heat transfer.With the increase of inner wall temperature both convection and condensa-tion heat transfer all decrease and the ratio of condensation to total heat decrease dramatically.Increases inlet tem-perature mainly affects convection heat transfer.

Design of High-Speed PM Synchronous Motor Thermal and Mechanical Analyzes Study for Aerospace Retraction Wheel Motor Application

A 3-D modeling of FEA （finite element analysis） design provides for high-speed synchronous with PMs （permanent magnets） applied in aerospace application will be examined under design considerations ofn = 12,000 rpm, short-duty operation, and etc. for an ARWM （aerospace retraction wheel motor）. First, lumped-elements will be fine-tuned following numerical method results is reported steady-state and transient solutions. Besides, the equations of thermal modeling such as Re, N,,, G,. and Pr numbers in order to calculate heat-transfer coefficient of convection on the rotor and stator surfaces in the air-gap have calculated. This section illustrates the temperature distribution of each point in a clear view. By CFD （fluid dynamic analysis） analysis, the fluid dynamics were modeled, pressure and velocity streamlines of cooling-flow have analyzed. An optimization algorithm was derived in order to have optimized number of water-channels as well. Second, calculation of nodal and tangential forces which deal with mechanical stresses of the ARWM have represented. The paper discusses an accurate magnetic-field analysis that addresses equivalent stress distribution in the magnetic core through using the transient FEA to estimate motor characteristics. The whole model shear and normal mechanical stresses and total deformation oftbe ARWM has been investigated by transient FEA. The end-winding effects were included by the authors.

Simulation of Steady-State and Dynamic Behaviour of a Plate Heat Exchanger

The present paper deals with both the steady-state and dynamic simulation of a plate heat exchanger, in counter-flow arrangement. A CFD （computational fluid dynamics） program FLUENT has been used to predict the temperature distribution in steady-state conditions in plate heat exchanger as well as fluid temperatures at exit of flow channels in transient condition. The results are presented for the heat exchanger, which is simulated according to the configuration of the plate heat exchanger used in the experiment. The simulated results obtained by the CFD model have been compared with the experimental data from the literature, which shows that the CFD model developed in this study is capable of predicting the steady-state and transient performance of the plate heat exchangers satisfactorily.

MATHEMATICAL MODEL OF ~4He QUANTUM INTERFEROMETER GYROSCOPE

The mathematical model of 4He quantum interferometer gyroscope is presented. The model includes the driven equation, the current equation and the position equation. Therefore, it can sufficiently describe the gyro- scope system. The driven equation shows the thermally driven gyroscope can work for a long time but the pres- sure driven one cannot. From the current equation, the superfluid currents passing through the weak link contain the AC currents which show the rotation flux, and other currents caused by drive. As shown in the position equa- tion, the displacement of diaphragm is the only detectable parameter in the gyroscope system. The model is tested by the simulations based on experimental parameters, and can be used to research performance of the gyroscope and analyse the gyroscope error.

Local structure of calcium silicate melts from classical molecular dynamics simulation and a newly constructed thermodynamic model

The distributions of local structural units of calcium silicate melts were quantified by means of classical molecular dynamics simulation and a newly constructed structural thermodynamic model. The distribution of five kinds of Si-O tetrahedra Qi from these two methods was compared with each other and also with the experimental Raman spectra, an excellent agreement was achieved. These not only displayed the panorama distribution of microstructural units in the whole composition range, but also proved that the thermodynamic model is suitable for the utilization as the subsequent application model of spectral experiments for the thermodynamic calculation. Meanwhile, the five refined regions mastered by different disproportionating reactions were obtained. Finally, the distributions of two kinds of connections between Qi were obtained, denoted as Qi-Ca-Qj and Qi-[Ob]-Qj, from the thermodynamic model, and a theoretical verification was given that the dominant connections for any composition are equivalent connections.