风流与湿润围岩的热-质交换特性及其影响因素研究

为了分析风流与完全湿润岩壁的热-质交换特性及相关影响因素,通过相似理论建立了物理模型,解决了相关问题难以现场实测的难题,分析了冷风流与完全湿润围岩间的传热与传质过程,进一步研究了风流速度、湿度、温度、围岩岩壁温度等因素对降温控制区内传质及传热的影响。结果表明假定降温控制区域内风流的水蒸气分压力为线性分布时,计算结果的误差为5%~10%;交换过程中潜热传递约占总换热量的80%;其他条件一定时,风流速度增加25%,传质量增加约33%;送风相对湿度增加12.5%,传质量减少约11%;送风温度增加10%,换热系数增加约10%;围岩温度增加8℃,传质量增加约79%;对传质过程有影响的因素,对换热量及总换热系数也有同样重要的影响。

Combined mass and heat exchange network synthesis based on stage-wise superstructure model

Integrating multiple systems into one has become an important trend in Process Systems Engineering research field since there is strong demand from the modern industries. In this study, a stage-wise superstructurebased method is proposed to synthesize a combined mass and heat exchange network(CM&HEN) which has two parts as the mass exchange network(MEN) and heat exchange network(HEN) involved. To express the possible heat exchange requirements resulted from mass exchange operations, a so called "indistinct HEN superstructure(IHS)", which can contain the all potential matches between streams, is constructed at first. Then, a non-linear programming(NLP) mathematical model is established for the simultaneous synthesis and optimization of networks. Therein, the interaction between mass exchange and heat exchange is modeling formulated.The NLP model has later been examined using an example from literature, and the effectiveness of the proposed method has been demonstrated with the results.

New atom movement mechanism for tracking path on disordering AuCuI(A_8^(Au)A_4^(Cu)) compound

Taking experimental path on disordering AuCuI（AAuCu8A4）composed of A Au8 and ACu4 stem alloy genes as an example, three discoveries and a method were presented. The ability of Au Cu I（AAu Cu8 A4）to keep structure stabilization against changing temperature is attributed to the fact that the AAu8 and ACu4 potential well depths greatly surpass their vibration energies, which leads to the subequilibrium of experimental path. A new atom movement mechanism of AuCuI（AAuACu84）to change structure for suiting variation in temperature is the resonance activating-synchro alternating of alloy genes, which leads to heterogeneous and successive subequilibrium transitions. There exists jumping order degree, which leads to the existence of jumping Tj-temperature and an unexpected so-called ＂retro-effect＂ about jumping temperature retrograde shift to lower temperatures upon the increasing heating rate. A set of subequilibrium holographic network path charts were obtained by the experimental mixed enthalpy path method.

Arrangement Strategy of Ground Heat Exchanger with Groundwater

The orientation strategy of side pipe and the heat transfer performance of six ground heat exchangers(GHEs) were optimized by numerical simulation,with soil being treated as a porous medium.An experiment on the heat transfer of four GHEs was carried out in 2010.Results indicate that the velocity field is disturbed by GHEs.The optimal orientation strategy of side pipe is that the upward pipe is located upstream and the downward pipe downstream.The space between GHEs should be appropriately adjusted,depending on the direction and flow velocity.Groups of GHEs should be installed perpendicular to the mainstream in a single row,but if the acreage does not meet the requirements,GHEs should be installed in staggered multiple rows.Fewer GHEs parallel to the mainstream strengthen the heat transfer.Moreover,numerical results agree well with the test data,with the maximum relative error being less than 7.7%.

Oxygen and hydrogen isotope exchange of geopressured thermal water in the central Guanzhong basin

Geothermal water of Xi＇an and Xianyang in the central Guanzhong basin is typically geopressured thermal water in China. 5180 and 5D data of geopressured thermal water＇in Xi＇an and Xianyang, combined with data from the perimeter of the basin, are analyzed to study features of hydrogen and oxygen shifts. The results show that ^18O exchange of geothermal water at the perimeter of the basin and in the non-geopressured thermal water in the center of the basin is not evident, while in most of the geopressured thermal water in the central basin, in cities such as Xi＇an and Xianyang, significant oxygen exchange had taken place as well as hydrogen exchange, suggesting that isotope exchanges would slowly move the geothermal water system towards equilibrium. Thermal water reservoirs in the central basin have passed through significant water-rock reactions. Moreover, the geothermal reservoir of Xianyang city is relatively much more enclosed than that of Xi＇an city. It has been observed that the more enclosed the geological environment of geothermal water is, the more obvious the oxygen shifts are. With the increasing of the depth, residence time, total amounts of dissolute solids and temperatures of geothermal waters, the oxygen exchange accelerates.

Mathematical Model of Coupled Heat and Mass Transfer in Unsaturated Soils *1

A systematic study of coupled heat and mass transfer in unsaturated soils under complex boundary conditions was carried out and a mathematical model of heat and mass transfer in unsaturated soils was established by non equilibrium thermodynamic theory. The gradient of volumetric moisture content, the gradient of temperature, the salt mass concentration and vapor pressure were the primary driving forces influencing the process of heat and mass transfer in unsaturated soils. Based on the thermodynamic analysis and the mass and energy conservation principles, a set of mass and energy equations were developed. The initial and boundary conditions of soil column for one dimension were also given out.

Research on a simulated 60 kW PEMFC cogeneration system for domestic application

The electrical and thermal performances of a simulated 60 kW Proton Exchange Membrane Fuel Cell (PEMFC) cogeneration system are first analyzed and then strategies to make the system operation stable and efficient are developed. The system configuration is described first, and then the power response and coordination strategy are presented on the basis of the electricity model. Two different thermal models are used to estimate the thermal performance of this cogeneration system, and heat management is discussed. Based on these system designs, the 60 kW PEMFC cogeneration system is analyzed in detail. The analysis results will be useful for further study and development of the system.

Preparation and Characterization of Indium Doped Tin Oxide （ITO） via a Solvothermal Method

Tin-doped Indium Oxide （ITO） has been successfully prepared via solvothermal method with a mixture of Indium（Ill） acetylacetonate and Tin（IV） bis（acetylacetonate）dichioride in oleyamine solvent under the condition of the different reaction time from 12 h to 48 h for the first time. The morphology, phase composition and particle size of the ITO powder were characterized by TEM and XRD. Two significant properties required for ITO samples to become noncarbon support for Pt in PEMFCs including specific surface area and electrical conductivity were studied.

Thermal Response Test for Kelix GHE System

The performance of a BTES （borehole thermal energy storage） system is primarily governed by ground heat flux, soil thermal properties and groundwater conditions. However, the design of the heat exchanger used within the BTES system can also make a significant difference in the efficiency of the system. A thermal response test was carded out for a Kelix GHE （ground heat exchanger） system, the latest innovation in geothermal ground loop construction, on an Ecofarm in the town of Caledon East, Ontario, Canada. In addition, a verifying test was performed for a CEES （conventional earth energy system） located 6 m away from the Kelix GHE. The boreholes for these two different heat exchanger designs were drilled with the same diameter, to the same depth and were located in the same/identical geo-hydrological conditions. The response test provided the effective average of undisturbed ground temperature, geothermal properties including thermal conductivity, heat capacity and thermal resistance between the fluid and the borehole wall. The mathematical analysis method used for the response test is presented here. Results of the response test were verified, analyzed and are further discussed.

Characterization of Thailand Rice Husk Ash from Biomass Power Plant and Synthesized Zeolite

Thailand rice husk ash was used to synthesize zeolite by hydrothermal treatment. Raw rice husk ash material and zeolitic products were characterized in terms of specific surface area （BET method）, morphological analysis （SEM）, mineralogical composition （XRD） and CEC （cation exchange capacity）. LOI （Loss of ignition） of rice husk ash was also evaluated. Result indicated that the rice husk ash sample from Roi-Et Green power plant in the Northeastern of Thailand with combustion temperature of 650 ℃ has a high content of SiO2 （above 90 wt.%）. Zeolite-X from rice husk ash with high content of Si was successfully synthesized using hydrothermal treatment. The zeolitic material synthesized with the optimal condition possessed a maximum value of CEC of 503 meq/100g, and it has potentiality to be used as ion exchangers.

Constructal optimization for H-shaped multi-scale heat exchanger based on entransy theory

Analogizing with the definition of thermal efficiency of a heat exchanger,the entransy dissipation efficiency of a heat exchanger is defined as the ratio of dimensionless entransy dissipation rate to dimensionless pumping power of the heat exchanger.For the constraints of the total tube volume and total tube surface area of the heat exchanger,the constructal optimization of an H-shaped multi-scale heat exchanger is carried out by taking entransy dissipation efficiency maximization as optimization objective,and the optimal construct of the H-shaped multi-scale heat exchanger with maximum entransy dissipation efficiency is obtained.The results show that for the specified total tube volume of the heat exchanger,the optimal constructs of the first order T-shaped heat exchanger based on the maximizations of the thermal efficiency and entransy dissipation efficiency are obviously different with the lower mass flow rates of the cold and hot fluids.For the H-shaped multi-scale heat exchanger,the entransy dissipation efficiency decreases with the increase in mass flow rate when the heat exchanger order is fixed;for the specified dimensionless mass flow rate M(M<32.9),the entransy dissipation efficiency decreases with the increase in the heat exchanger order.The performance of the multi-scale heat exchanger is obviously improved compared with that of the single-scale heat exchanger.Moreover,the heat exchanger subjected to the total tube surface area constraint is also discussed in the paper.The optimization results obtained in this paper can provide a great compromise between the heat transfer and flow performances of the heat exchanger,provide some guidelines for the optimal designs of heat exchangers,and also enrich the connotation of entransy theory.

Three Dimensional Transient Coupled Radiative Conductive Heat Transfer in Cylinders Filled with Semi－Transparent Media with Complicated Surface Characteristics

Using the Control Volume and the Discrete Transfer (DT) methods incorporating the Spectral Band Model, the transient coupled radiative-conductive heat transfer is investigated in cylinders filled with semi-transparent media with both opaque and send-transparent surfaces. This is a three dimensional problem with nonlinear boundary conditions of the second and third kinds. The temperature field in the optical window of a space camera is calculated with complicated boundary conditions. By comparing with the zone and the improved Monte-Carlo methods, the reliability and calculating precision of this method are shown.

Determination of a Vapor Compression Refrigeration System Refrigerant Charge

A physical model is established in this paper to describe the heat transfer and two phase flow of a refrigerant in the evaporator and condenser of a vapor compression refrigeration system. The model is then used to determine the refrigerant charge in vapor compression units. The model is used for a sensitivity analysis to determine the effect that yaring design parameters on the refrigerant charge. The model is also used to evaluate the effect of refrigerant charge and the thermal physical properties on the refrigeration cycle. The predicted value of the refrigerant charge and experimental data agree well.The model and the method presented in this paper could be used to design vapour compression units such as domestic refrigerators and air conditioners.

Excellent photothermal conversion of core/shell CdSe/ Bi2Se3 quantum dots

Water-dispersed CdSe/Bi2Se3 core/shell QDs with a photothermal conversion coefficient of 27.09% have been synthesized by a cation exchange reaction. The microstructure and crystal structure of the QDs, which were confirmed by TEM and XRD, showed that partial cation exchange occurred inside the CdSe QDs. Two main mechanisms are responsible for the excellent photothermal conversion： inhibition of radiative recombination of carriers due to the formation of type-II semiconductor heterostructures, and the large surface-to-volume ratio of the QDs. Photothermal conversion experiments indicated that the CdSe/Bi2Se3 QDs showed high photothermal conversion efficiency and excellent NIR photostability.