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吸附法分离焦化甲苯中的吡啶类物质及吸附剂的再生 被引量:2
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作者 牛丛丛 陈莉君 曾爱武 《化工进展》 CAS CSCD 北大核心 2012年第7期1458-1463,共6页
采用气相吸附法以NaY分子筛作为吸附剂,对焦化甲苯进行精制脱氮,当吸附温度为115℃时,可以将焦化甲苯原料中吡啶和甲基吡啶的含量从5595μg/g和1633μg/g均降到500μg/g以下,NaY原粉和成型吸附剂的穿透处理量分别为12.44 g/g和5.94 g/g... 采用气相吸附法以NaY分子筛作为吸附剂,对焦化甲苯进行精制脱氮,当吸附温度为115℃时,可以将焦化甲苯原料中吡啶和甲基吡啶的含量从5595μg/g和1633μg/g均降到500μg/g以下,NaY原粉和成型吸附剂的穿透处理量分别为12.44 g/g和5.94 g/g,对应的吸附量分别为0.90 mmol/g和0.44 mmol/g。热重分析(TGA)和核磁C谱(13C-NMR)的结果表明,采用250℃水蒸气再生的方法可以将吡啶和甲基吡啶脱附,但无法将积炭完全脱除。通过对比分子筛原粉和成型后吸附剂的吸附性能和再生性能,发现成型后的分子筛穿透处理量有所降低,但黏合剂的加入使其吸附性能更加稳定。并且在相同的吸附条件下,成型吸附剂比原粉吸附剂具有更强的深度脱氮能力。 展开更多
关键词 吡啶类 焦化甲苯 吸附 水蒸气再生
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焦化甲苯的加氢精制
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作者 赵艳斌 曾爱武 《现代化工》 CAS CSCD 北大核心 2012年第6期104-106,108,共4页
对焦化甲苯原料首先进行加氢处理,之后采用连续精馏的方法进行分离与提纯,以得到纯度较高的甲苯产品。加氢阶段有效去除并转化了焦化甲苯中的噻吩、吡啶和烯烃类杂质。精馏阶段采用2塔连续精馏的实验流程,并对流程进行了模拟,分别对2塔... 对焦化甲苯原料首先进行加氢处理,之后采用连续精馏的方法进行分离与提纯,以得到纯度较高的甲苯产品。加氢阶段有效去除并转化了焦化甲苯中的噻吩、吡啶和烯烃类杂质。精馏阶段采用2塔连续精馏的实验流程,并对流程进行了模拟,分别对2塔的操作参数进行了优化。通过连续精馏实验对模拟结果进行了验证,结果表明,对加氢处理之后的焦化甲苯原料采用NRTL热力学方法得到的精馏模拟结果可得到纯度为99.39%的甲苯产品,证明实验结果与模拟结果吻合较好。 展开更多
关键词 连续精馏 焦化甲苯 NRTL热力学方法
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Ni nanoparticles supported on carbon as efficient catalysts for steam reforming of toluene(model tar) 被引量:8
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作者 Chun Shen Wuqing Zhou +1 位作者 Hao Yu Le Du 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第2期322-329,共8页
This paper investigated the influences of surface properties of carbon support and nickel precursors(nickel nitrate, nickel chloride and nickel acetate) on Ni nanoparticle sizes and catalytic performances for steam re... This paper investigated the influences of surface properties of carbon support and nickel precursors(nickel nitrate, nickel chloride and nickel acetate) on Ni nanoparticle sizes and catalytic performances for steam reforming of toluene. Treatment with nitric acid helped to increase the amount of functional groups on the surface and hydrophilic nature of carbon support, leading to a homogeneous distribution of Ni nanoparticles. The thermal decomposition products of nickel precursor also played an important role, Ni nanoparticles supported on carbon treated with acid using nickel nitrate as the precursor exhibited the smallest mean diameter of 4.5 nm. With the loading amount increased from 6 wt% to 18 wt%, the mean particle size of Ni nanoparticles varied from4.5 nm to 9.1 nm. The as-prepared catalyst showed a high catalytic activity and a good stability for toluene steam reforming: 98.1% conversion of toluene was obtained with the Ni content of 12 wt% and the S/C ratio of3, and the conversion only decreased to 92.0% after 700 min. Because of the high activity, good stability, and low cost, the as-prepared catalyst opens up new opportunities for tar removing. 展开更多
关键词 Ni nanoparticles Steam reforming Tar removing Catalytic performance
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Separation of Toluene Insoluble Matter from Syncrude Coker Heavy Gas Oil 被引量:1
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作者 许志明 王宗贤 +1 位作者 L.S.Kotlyar K.H.Chung 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2003年第6期747-750,共4页
Toluene insoluble matter (TIM) in coker heavy gas oil (CHGO) from oil sands bitumen is harmful to the downstream hydrotreating, and it may be difficult to be removed by conventional filtration. In order to determine i... Toluene insoluble matter (TIM) in coker heavy gas oil (CHGO) from oil sands bitumen is harmful to the downstream hydrotreating, and it may be difficult to be removed by conventional filtration. In order to determine its origin, the TIM must first be separated from CHGO for characterization. Two techniques are described to accomplish this goal. In the ultra-centrifugation approach used in this work, CHGO is blended with a miscible liquid and centrifuged under 366000 G (gravity) force. Through this procedure toluene and hexane diluents yielded TIM contents of 24μg·g-1 and 88μg·g-1 respectively. In an alternative simplified procedure, the initial ultra-centrifugation step is omitted. Several different solvents are evaluated for use as diluents but, in each case, toluene is still used in the subsequent washing steps. TIM contents determined by this method range from 23 to about 200μg·g-1. The amount of TIM separated by means of this method depends primarily on the initial diluent used. Other conditions, such as diluent-oil ratio, water-oil ratio, mixing time, temperature and water pH value, are also studied. 展开更多
关键词 SEPARATION toluene insoluble matter coker heavy gas oil
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