In order to investigate the effects of two mineral admixtures (i. e., fly ash and ground slag)on initial defects existing in concrete microstructures, a high-resolution X-ray micro-CT( micro-focus computer tomogra...In order to investigate the effects of two mineral admixtures (i. e., fly ash and ground slag)on initial defects existing in concrete microstructures, a high-resolution X-ray micro-CT( micro-focus computer tomography)is employed to quantitatively analyze the initial defects in four series of highperformance concrete (HPC)specimens with additions of different mineral admixtures. The nigh-resolution 3D images of microstructures and filtered defects are reconstructed by micro- CT software. The size distribution and volume fractions of initial defects are analyzed based on 3D and 2D micro-CT images. The analysis results are verified by experimental results of watersuction tests. The results show that the additions of mineral admixtures in concrete as cementitious materials greatly change the geometrical properties of the microstructures and the spatial features of defects by physical-chemistry actions of these mineral admixtures. This is the major cause of the differences between the mechanical behaviors of HPC with and without mineral admixtures when the water-to-binder ratio and the size distribution of aggregates are constant.展开更多
[Objective] This study aimed to investigate the effects of cigarette auxiliary material parameters on release amounts of tar, CO and free radicals in cigarette mainstream smoke. [Method] The effects of cigarette paper...[Objective] This study aimed to investigate the effects of cigarette auxiliary material parameters on release amounts of tar, CO and free radicals in cigarette mainstream smoke. [Method] The effects of cigarette paper air-permeability, cigarette paper gram weight, filter rod pressure drop and filter tip ventilating strength parameters on the release amounts of tar, CO and free radicals in cigarette mainstream smoke were investigated by single factor experiment and orthogonal experiment. [Result] The cigarette paper air-permeability, filter rod pressure drop and filter tip ventilating strength showed significantly negative correlation with the release amounts of tar, CO and free radicals in cigarette mainstream smoke, to be specific, the cigarette paper air-permeability showed the greatest effect on the release amounts of tar and CO, filter tip ventilating strength showed the greatest effect on the release amounts of gaseous-phase free radicals and particulate-phase free radicals, while cigarette paper gram weight showed relatively slight effect on the release amounts of tar, CO and free radicals. Within the orthogonal experimental range, the optimal program is identified as cigarette paper airpermeability of 70 CU, filter rod pressure drop of 4500 Pa/unit, and filter tip ventilating strength of 60 CU. Compared to the results without optimization, the release amounts of tar, CO and free radicals after optimization were all reduced. [Conclusion] This study laid the foundation for the research of cigarette tar reduction and harm reduction.展开更多
The properties and blending recipe of petroleum cokes used to make high quality carbon anodes for aluminium electrolysis were studied. Three kinds of green cokes were selected for bench scale study to illustrate the e...The properties and blending recipe of petroleum cokes used to make high quality carbon anodes for aluminium electrolysis were studied. Three kinds of green cokes were selected for bench scale study to illustrate the effects of cokes properties and its blending recipe on anode performances. The results show that impurities derived mainly fi'om cokes remarkably affect the CO2 reactivity and air reactivity of carbon anodes. Ca, Na and V can increase CO2 reactivity of calcined cokes but S has the contrary effect, and the cokes of high V level generally present high air reactivity. The anodes with good quality can be made by properly selecting and scientifically blending of cokes, some poor quality cokes can also be used to produce high quality anodes with a reasonable blending recipe. Na contaminated anodes have high CO2 reactivity and air reactivity, so the recycled anode butts should be well cleaned to reduce Na content before being introduced into anode production, which is especially important to the low S cokes.展开更多
The acoustic focusing effect of metamaterial has a wide range of applications in medicine,acoustic imaging,signal detection,etc.This paper presents an acoustic metamaterial applied to the acoustic focusing effect.The ...The acoustic focusing effect of metamaterial has a wide range of applications in medicine,acoustic imaging,signal detection,etc.This paper presents an acoustic metamaterial applied to the acoustic focusing effect.The formation of acousticmetamaterial is designed into a cylindrical structure with three layers of ludox,cork and fluid rubber,which can produce a focusingphenomenon when acoustic waves propagate in air.For these strange phenomena,a scientific description is given theorietically.It can also be concluded that when the frequency of the incident acoustic wave increases?the number of peripheral bandsoutside the focusing poles will increase periodically.Besides,there are numerous groups of multipolar focusing phenomena inhigh frequency.The design of this acoustic metamaterial is successful through theorietical and experimental verification,therefore,it can be applied to acoustic communication and test.展开更多
This research evaluated the use of sewage sludge and refuse incineration bottom ash to replace calcium sulfoaluminate cement (CSA) in making controlled low-strength material (CLSM). Various properties of CLSM mixt...This research evaluated the use of sewage sludge and refuse incineration bottom ash to replace calcium sulfoaluminate cement (CSA) in making controlled low-strength material (CLSM). Various properties of CLSM mixtures were characterized in terms of unconfined compressive strength, microstructure and leachability. It was found that the strength of tested CLSM mixtures ranged from 3.6 to 9.0 MPa, over the upper excavatable limit of 2.1 MPa. The micro-structural analysis revealed that sewage sludge and bottom ash were crystallochemically in- corporated within CLSM system_s by forming the needle-like ettringite (C3A'3CS'_H32) with exiguous tu.bers via the typical Pozzolanic Reaction, leading to a dense and low-porosity microst;'ucture. Furthermore,-the toxicity characteristic leaching procedure evidenced that the cumulative leachable metals in the leachate were much below the regulatory thresholds. The potential for us!ng sewage sludge and bottom ash!n CLSM makin.g was thus confirmed.展开更多
Thermal upgrading of vacuum residue mixed with waste plastics was studied in a laboratory scale delayed coking unit.The model of feed thermal decomposition was set up and the first order reaction kinetics was used to ...Thermal upgrading of vacuum residue mixed with waste plastics was studied in a laboratory scale delayed coking unit.The model of feed thermal decomposition was set up and the first order reaction kinetics was used to predict products distribution during the coking process.The distillate yield was higher(70%) for the vacuum residue/polystyrene(VR/PS) feed system and the vacuum residue/low density polyethylene(VR/LDPE) feed system.The resulted distillate yield was separated into fractions according to their boiling points,with gasoline and diesel being our fractions of concern.The activation energy was higher for gasoline production(around 60 kcal/mol) varying with the type of feed system,while it was 33 kcal/mol for diesel fraction.The regression coefficient R was 0.990.展开更多
A new approach is provided to resolve the large-scale applications of coal tar pitch. Carbon foams with uniform pore size are prepared at the foaming pressure of normal pressure using coal tar pitch as raw materials. ...A new approach is provided to resolve the large-scale applications of coal tar pitch. Carbon foams with uniform pore size are prepared at the foaming pressure of normal pressure using coal tar pitch as raw materials. The physical and chemical performance of high softening point pitch(HSPP) can be regulated by vacuumizing owing to the cooperation of vacuumizing and polycondensation. Results indicate that the optimum softening point and weight ratio of quinoline insoluble are about 292℃ and 65.7%, respectively. And the optimum viscosity of HSPP during the foaming process is distributed in the range of 1000-10000 Pa·s. The resultant carbon foam exhibits excellent performance, such as uniform pore structure, high compressive strength(4.7 MPa), low thermal conductivity(0.07 W·m^(-1) ·K^(-1)), specially, it cannot be fired under the high temperature of 1200 ℃.Thus, this kind of carbon foam is a potential candidate for thermal insulation material applied in energy saving building.展开更多
In order to choose the appropriate reference surface on the machined surface roughness of Si Cp/Al composites, the cutting experiments of Si Cp/Al composites were carried out, and the machined surface topography was m...In order to choose the appropriate reference surface on the machined surface roughness of Si Cp/Al composites, the cutting experiments of Si Cp/Al composites were carried out, and the machined surface topography was measured by OLS3000 Confocal laser scanning microscope. The 3D measured data of machined surface topography were analyzed by the area power spectrum density. The result shows that the texture of machined surface topography in milling of Si Cp/Al composites is almost isotropic. This is the reason that the values of Rq at different locations on the same machined surface are obviously different. Through the comparison of performance of different filtering methods, the robust least squares reference surface can be used to extract the surface roughness of SiC p/Al composites effectively.展开更多
The semi-solid antiburning AZ61-1.0%Y magnesium alloy slurry with fine circular solid phase was fabricated by a novel type continuous mechanical stirring in this work.The microstructure of the semisolid slurry was cha...The semi-solid antiburning AZ61-1.0%Y magnesium alloy slurry with fine circular solid phase was fabricated by a novel type continuous mechanical stirring in this work.The microstructure of the semisolid slurry was characterized by a metallography microscope.The results show that the fine circular solid phase distributes uniformly in the slurry when the stirring temperature ranges from 600 to 605℃.With the increase of the stirring velocity,the size of the solid phase becomes smaller and smaller.With the increase of the stirring time,the size of solid phase gets finer,but if the stirring time is longer than the critical time,it will be coarsened abnormally.The mechanical properties of semi-solid AZ61-1.0%Y alloy are superior to those of the normally casting magnesium alloy.展开更多
The current technology for producing the petroleum needle coke is apt to cause overflow of feedstock from the coke drums, instability in operation of coking unit, low mechanical strength of petroleum coke, and high pe...The current technology for producing the petroleum needle coke is apt to cause overflow of feedstock from the coke drums, instability in operation of coking unit, low mechanical strength of petroleum coke, and high percentage of coke powder, leading to difficulties in improving the overall quality of needle coke. Therefore, we have developed a new technology for producing the needle coke,featuring the manipulation of temperature range in a narrow scale at high pressure coupled with feedstock alternations. This new kind of technology has been successfully applied in a 60kt/a commercial coking unit. Provided that demand for the feedstock quality is satisfied, petroleum needle coke meeting the international quality standard can be manufactured using RIPP's technology for producing petroleum needle coke.展开更多
In many experiments, plastic scintillators are used as a counter instead of Geiger Muller counter, because they are so fast and they are used for pulsed neutron sources. So a silver activation counter has been constru...In many experiments, plastic scintillators are used as a counter instead of Geiger Muller counter, because they are so fast and they are used for pulsed neutron sources. So a silver activation counter has been constructed by plastic scintillator plates along with silver foils for determination the neutron yield of a 2.48 kJ plasma focus device, SBUPF1. This counter was calibrated by source removal method with an Am-Be 5 Ci neutron source which was placed above the anode of plasma focus device. Deuterium gas up to 8 mbar pressure was injected to this device, and the neutron yield produced by pulsed D-D fusion of plasma focus device was measured by the counter. The neutron yield of SBUPF1 in 8 mbar pressure was obtained (3.71± 0.32)×10^7 neutrons per shot. This result has relatively agreed with the neutron yield measured by silver activation Geiger counters.展开更多
Organic light-emitting diodes (OLEDs) have been extensively studied since the first efficient device based on small molecular luminescent materials was reported by Tang. Organic electroluminescent material, one of t...Organic light-emitting diodes (OLEDs) have been extensively studied since the first efficient device based on small molecular luminescent materials was reported by Tang. Organic electroluminescent material, one of the centerpieces of OLEDs, has been the focus of studies by many material scientists. To obtain high luminosity and to keep material costs low, a few remarkable design concepts have been developed. Aggregation-induced emission (AIE) materials were invented to overcome the common fluorescence-quenching problem, and cross-dipole stacking of fluorescent molecules was shown to be an effective method to get high solid-state luminescence. To exceed the limit of internal quantum efficiency of conventional fluorescent materials, phosphorescent materials were successfully applied in highly efficient electroluminescent devices. Most recently, delayed flu- orescent materials via reverse-intersystem crossing (RISC) from triplet to singlet and the "hot exciton" materials based on hy- bridized local and charge-transfer (HLCT) states were developed to he a new generation of low-cost luminescent materials as efficient as phosphorescent materials. In terms of the device-fabrication process, solution-processible small molecular lumi- nescent materials possess the advantages of high purity (vs. polymers) and low procession cost (vs. vacuum deposition), which are garnering them increasing attention. Herein, we review the progress of the development of small-molecule luminescent materials with different design concepts and features, and also briefly examine future development tendencies of luminescent materials.展开更多
Coal-tar pitch(CP)is a promising carbon raw material for producing needle coke,carbon fiber etc.During processing,the H/C ratio,ash content,and quinoline insoluble(QI)in the CP are the key factors that influence the m...Coal-tar pitch(CP)is a promising carbon raw material for producing needle coke,carbon fiber etc.During processing,the H/C ratio,ash content,and quinoline insoluble(QI)in the CP are the key factors that influence the material preparation.In this study,NMP was selected to extract CP first;then[BMIM]Cl/NMP mixed solvent was used;and finally a series of ionic liquids(ILs)mixtures with NMP were developed for the extraction of CP to obtain the refined pitch.The extracts were analyzed via elemental analysis,TGA,FT-IR,and 13C-NMR.Results indicate that different NMP/IL mass ratios or different kinds of ILs have impact on the extraction yield.The relationship of the hydrogen to carbon(H/C)ratio changed with different solvents and QI extracts were obtained.Results showed that the H/C ratios changed little between NMP extracts and could be adjusted by changing the NMP/ILs mass ratio or using different ILs.The extracts are suitable for preparation mesophase pitch because of no ash content,low QI,and appropriate H/C ratios.As a result,NMP can be used to refine pitch.In addition,[BMIM]Cl is good mixed with NMP for CP extraction,because it can obtain a relatively high yield under the same extraction conditions.展开更多
基金The Scholarship Supported by Ministry of Education of China for Research Abroad(No.3037[2006])the Excellent Doctoral Dissertation Foundation of Southeast University (No.YBTJ-0512)the National Basic Research Program of China(973Program)(No.2009CB623203)
文摘In order to investigate the effects of two mineral admixtures (i. e., fly ash and ground slag)on initial defects existing in concrete microstructures, a high-resolution X-ray micro-CT( micro-focus computer tomography)is employed to quantitatively analyze the initial defects in four series of highperformance concrete (HPC)specimens with additions of different mineral admixtures. The nigh-resolution 3D images of microstructures and filtered defects are reconstructed by micro- CT software. The size distribution and volume fractions of initial defects are analyzed based on 3D and 2D micro-CT images. The analysis results are verified by experimental results of watersuction tests. The results show that the additions of mineral admixtures in concrete as cementitious materials greatly change the geometrical properties of the microstructures and the spatial features of defects by physical-chemistry actions of these mineral admixtures. This is the major cause of the differences between the mechanical behaviors of HPC with and without mineral admixtures when the water-to-binder ratio and the size distribution of aggregates are constant.
基金Supported by Major Project of China National Tobacco Corporation(110201101034),"Study on Redrying,Alcoholization and Processing Technologies to Reduce the Release Amount of Ammonia in Cigarette Smoke"General Project of China National Tobacco Corporation(2012-122-25):"Integrated Study on Systematical Design and Harm Reduction Technologies of Cigarette Products"+1 种基金Project of China National Tobacco Corporation(1001200701007):"Study on Selective Harm Reduction Technologies and Product Application"Project of Chongqing City(06-1-173):"Study on Preparation of Less Harmful Cigarette and Harm Reduction Mechanism"~~
文摘[Objective] This study aimed to investigate the effects of cigarette auxiliary material parameters on release amounts of tar, CO and free radicals in cigarette mainstream smoke. [Method] The effects of cigarette paper air-permeability, cigarette paper gram weight, filter rod pressure drop and filter tip ventilating strength parameters on the release amounts of tar, CO and free radicals in cigarette mainstream smoke were investigated by single factor experiment and orthogonal experiment. [Result] The cigarette paper air-permeability, filter rod pressure drop and filter tip ventilating strength showed significantly negative correlation with the release amounts of tar, CO and free radicals in cigarette mainstream smoke, to be specific, the cigarette paper air-permeability showed the greatest effect on the release amounts of tar and CO, filter tip ventilating strength showed the greatest effect on the release amounts of gaseous-phase free radicals and particulate-phase free radicals, while cigarette paper gram weight showed relatively slight effect on the release amounts of tar, CO and free radicals. Within the orthogonal experimental range, the optimal program is identified as cigarette paper airpermeability of 70 CU, filter rod pressure drop of 4500 Pa/unit, and filter tip ventilating strength of 60 CU. Compared to the results without optimization, the release amounts of tar, CO and free radicals after optimization were all reduced. [Conclusion] This study laid the foundation for the research of cigarette tar reduction and harm reduction.
文摘The properties and blending recipe of petroleum cokes used to make high quality carbon anodes for aluminium electrolysis were studied. Three kinds of green cokes were selected for bench scale study to illustrate the effects of cokes properties and its blending recipe on anode performances. The results show that impurities derived mainly fi'om cokes remarkably affect the CO2 reactivity and air reactivity of carbon anodes. Ca, Na and V can increase CO2 reactivity of calcined cokes but S has the contrary effect, and the cokes of high V level generally present high air reactivity. The anodes with good quality can be made by properly selecting and scientifically blending of cokes, some poor quality cokes can also be used to produce high quality anodes with a reasonable blending recipe. Na contaminated anodes have high CO2 reactivity and air reactivity, so the recycled anode butts should be well cleaned to reduce Na content before being introduced into anode production, which is especially important to the low S cokes.
基金National Natural Science Foundation of China(No.61671414)Natural Science Foundation for Young Scientists of Shanxi Province,China(No.201601D202035)
文摘The acoustic focusing effect of metamaterial has a wide range of applications in medicine,acoustic imaging,signal detection,etc.This paper presents an acoustic metamaterial applied to the acoustic focusing effect.The formation of acousticmetamaterial is designed into a cylindrical structure with three layers of ludox,cork and fluid rubber,which can produce a focusingphenomenon when acoustic waves propagate in air.For these strange phenomena,a scientific description is given theorietically.It can also be concluded that when the frequency of the incident acoustic wave increases?the number of peripheral bandsoutside the focusing poles will increase periodically.Besides,there are numerous groups of multipolar focusing phenomena inhigh frequency.The design of this acoustic metamaterial is successful through theorietical and experimental verification,therefore,it can be applied to acoustic communication and test.
基金Supported by the Science and Technology Commission of Shanghai Municipality (08 DZ 1202802,09 DZ 1204105,09 DZ2251700)the National Natural Science Foundation of China (51008322)
文摘This research evaluated the use of sewage sludge and refuse incineration bottom ash to replace calcium sulfoaluminate cement (CSA) in making controlled low-strength material (CLSM). Various properties of CLSM mixtures were characterized in terms of unconfined compressive strength, microstructure and leachability. It was found that the strength of tested CLSM mixtures ranged from 3.6 to 9.0 MPa, over the upper excavatable limit of 2.1 MPa. The micro-structural analysis revealed that sewage sludge and bottom ash were crystallochemically in- corporated within CLSM system_s by forming the needle-like ettringite (C3A'3CS'_H32) with exiguous tu.bers via the typical Pozzolanic Reaction, leading to a dense and low-porosity microst;'ucture. Furthermore,-the toxicity characteristic leaching procedure evidenced that the cumulative leachable metals in the leachate were much below the regulatory thresholds. The potential for us!ng sewage sludge and bottom ash!n CLSM makin.g was thus confirmed.
文摘Thermal upgrading of vacuum residue mixed with waste plastics was studied in a laboratory scale delayed coking unit.The model of feed thermal decomposition was set up and the first order reaction kinetics was used to predict products distribution during the coking process.The distillate yield was higher(70%) for the vacuum residue/polystyrene(VR/PS) feed system and the vacuum residue/low density polyethylene(VR/LDPE) feed system.The resulted distillate yield was separated into fractions according to their boiling points,with gasoline and diesel being our fractions of concern.The activation energy was higher for gasoline production(around 60 kcal/mol) varying with the type of feed system,while it was 33 kcal/mol for diesel fraction.The regression coefficient R was 0.990.
基金Supported by the National Natural Science Foundation of China(51472086,51002051)CAS Key Laboratory of Carbon Materials(No KLCMKFJJ1703)
文摘A new approach is provided to resolve the large-scale applications of coal tar pitch. Carbon foams with uniform pore size are prepared at the foaming pressure of normal pressure using coal tar pitch as raw materials. The physical and chemical performance of high softening point pitch(HSPP) can be regulated by vacuumizing owing to the cooperation of vacuumizing and polycondensation. Results indicate that the optimum softening point and weight ratio of quinoline insoluble are about 292℃ and 65.7%, respectively. And the optimum viscosity of HSPP during the foaming process is distributed in the range of 1000-10000 Pa·s. The resultant carbon foam exhibits excellent performance, such as uniform pore structure, high compressive strength(4.7 MPa), low thermal conductivity(0.07 W·m^(-1) ·K^(-1)), specially, it cannot be fired under the high temperature of 1200 ℃.Thus, this kind of carbon foam is a potential candidate for thermal insulation material applied in energy saving building.
基金Projects(51305284,61203208) supported by the National Natural Science Foundation of China
文摘In order to choose the appropriate reference surface on the machined surface roughness of Si Cp/Al composites, the cutting experiments of Si Cp/Al composites were carried out, and the machined surface topography was measured by OLS3000 Confocal laser scanning microscope. The 3D measured data of machined surface topography were analyzed by the area power spectrum density. The result shows that the texture of machined surface topography in milling of Si Cp/Al composites is almost isotropic. This is the reason that the values of Rq at different locations on the same machined surface are obviously different. Through the comparison of performance of different filtering methods, the robust least squares reference surface can be used to extract the surface roughness of SiC p/Al composites effectively.
基金Project(50765005)supported by the National Natural Science Foundation of China
文摘The semi-solid antiburning AZ61-1.0%Y magnesium alloy slurry with fine circular solid phase was fabricated by a novel type continuous mechanical stirring in this work.The microstructure of the semisolid slurry was characterized by a metallography microscope.The results show that the fine circular solid phase distributes uniformly in the slurry when the stirring temperature ranges from 600 to 605℃.With the increase of the stirring velocity,the size of the solid phase becomes smaller and smaller.With the increase of the stirring time,the size of solid phase gets finer,but if the stirring time is longer than the critical time,it will be coarsened abnormally.The mechanical properties of semi-solid AZ61-1.0%Y alloy are superior to those of the normally casting magnesium alloy.
文摘The current technology for producing the petroleum needle coke is apt to cause overflow of feedstock from the coke drums, instability in operation of coking unit, low mechanical strength of petroleum coke, and high percentage of coke powder, leading to difficulties in improving the overall quality of needle coke. Therefore, we have developed a new technology for producing the needle coke,featuring the manipulation of temperature range in a narrow scale at high pressure coupled with feedstock alternations. This new kind of technology has been successfully applied in a 60kt/a commercial coking unit. Provided that demand for the feedstock quality is satisfied, petroleum needle coke meeting the international quality standard can be manufactured using RIPP's technology for producing petroleum needle coke.
文摘In many experiments, plastic scintillators are used as a counter instead of Geiger Muller counter, because they are so fast and they are used for pulsed neutron sources. So a silver activation counter has been constructed by plastic scintillator plates along with silver foils for determination the neutron yield of a 2.48 kJ plasma focus device, SBUPF1. This counter was calibrated by source removal method with an Am-Be 5 Ci neutron source which was placed above the anode of plasma focus device. Deuterium gas up to 8 mbar pressure was injected to this device, and the neutron yield produced by pulsed D-D fusion of plasma focus device was measured by the counter. The neutron yield of SBUPF1 in 8 mbar pressure was obtained (3.71± 0.32)×10^7 neutrons per shot. This result has relatively agreed with the neutron yield measured by silver activation Geiger counters.
基金supported by the National Natural Science Foundation of China(21334002,51303057,51373054,91233113)the National Basic Research Program of China(2013CB834705,2014CB643504,2015CB655003)+1 种基金the Fundamental Research Funds for the Central Universities(2013ZZ0001)the Introduced Innovative R&D Team of Guangdong(201101C0105067115)
文摘Organic light-emitting diodes (OLEDs) have been extensively studied since the first efficient device based on small molecular luminescent materials was reported by Tang. Organic electroluminescent material, one of the centerpieces of OLEDs, has been the focus of studies by many material scientists. To obtain high luminosity and to keep material costs low, a few remarkable design concepts have been developed. Aggregation-induced emission (AIE) materials were invented to overcome the common fluorescence-quenching problem, and cross-dipole stacking of fluorescent molecules was shown to be an effective method to get high solid-state luminescence. To exceed the limit of internal quantum efficiency of conventional fluorescent materials, phosphorescent materials were successfully applied in highly efficient electroluminescent devices. Most recently, delayed flu- orescent materials via reverse-intersystem crossing (RISC) from triplet to singlet and the "hot exciton" materials based on hy- bridized local and charge-transfer (HLCT) states were developed to he a new generation of low-cost luminescent materials as efficient as phosphorescent materials. In terms of the device-fabrication process, solution-processible small molecular lumi- nescent materials possess the advantages of high purity (vs. polymers) and low procession cost (vs. vacuum deposition), which are garnering them increasing attention. Herein, we review the progress of the development of small-molecule luminescent materials with different design concepts and features, and also briefly examine future development tendencies of luminescent materials.
基金supported by the National Basic Research Program of China(2012CB214905)the National Natural Science Foundation of China(21076113)
文摘Coal-tar pitch(CP)is a promising carbon raw material for producing needle coke,carbon fiber etc.During processing,the H/C ratio,ash content,and quinoline insoluble(QI)in the CP are the key factors that influence the material preparation.In this study,NMP was selected to extract CP first;then[BMIM]Cl/NMP mixed solvent was used;and finally a series of ionic liquids(ILs)mixtures with NMP were developed for the extraction of CP to obtain the refined pitch.The extracts were analyzed via elemental analysis,TGA,FT-IR,and 13C-NMR.Results indicate that different NMP/IL mass ratios or different kinds of ILs have impact on the extraction yield.The relationship of the hydrogen to carbon(H/C)ratio changed with different solvents and QI extracts were obtained.Results showed that the H/C ratios changed little between NMP extracts and could be adjusted by changing the NMP/ILs mass ratio or using different ILs.The extracts are suitable for preparation mesophase pitch because of no ash content,low QI,and appropriate H/C ratios.As a result,NMP can be used to refine pitch.In addition,[BMIM]Cl is good mixed with NMP for CP extraction,because it can obtain a relatively high yield under the same extraction conditions.