The combustion and explosion characteristics of lithium-ion battery vent gas is a key factor in determining the fire hazard of lithium-ion batteries.Investigating the combustion and explosion hazards of lithium-ion ba...The combustion and explosion characteristics of lithium-ion battery vent gas is a key factor in determining the fire hazard of lithium-ion batteries.Investigating the combustion and explosion hazards of lithium-ion batteries vent gas can provide guidance for rescue and protection in explosion accidents in energy storage stations and new energy vehicles,thereby promoting the application and development of lithium-ion batteries.Based on this understanding and combined with previous research on gas production from lithium-ion batteries,this article conducted a study on the combustion and explosion risks of vent gas from thermal runaway of 18650 LFP batteries with different states of charge(SOCs).The explosion limit of mixed gases affected by carbon dioxide inert gas is calculated through the“elimination”method,and the Chemkin-Pro software is used to numerically simulate the laminar flame speed and adiabatic flame temperature of the battery vent gas.And the concentration of free radicals and sensitivity coefficients of major elementary reactions in the system are analyzed to comprehensively evaluate the combustion explosion hazard of battery vent gas.The study found that the 100%SOC battery has the lowest explosion limit of the vent gas.The inhibitory elementary reaction sensitivity coefficient in the reaction system is lower and the concentration of free radicals is higher.Therefore,it has the maximum laminar flame speed and adiabatic flame temperature.The combustion and explosion hazard of battery vent gas increases with the increase of SOC,and the risk of explosion is the greatest and most harmful when SOC reaches 100%.However,the related hazards decrease to varying degrees with overcharging of the battery.This article provides a feasible method for analyzing the combustion mechanism of vent gas from lithium-ion batteries,revealing the impact of SOC on the hazardousness of battery vent gas.It provides references for the safety of storage and transportation of lithium-ion batteries,safety protection of energy storage stations,and the selection of related fire extinguishing agents.展开更多
This paper investigates the effects of coflow O2 level and temperature on diffusion flame of a CH4/H2 jet in hot coflow （JHC） from a burner system similar to that of Dally et al. The coflow O2 mass fraction （ Yo2 ...This paper investigates the effects of coflow O2 level and temperature on diffusion flame of a CH4/H2 jet in hot coflow （JHC） from a burner system similar to that of Dally et al. The coflow O2 mass fraction （ Yo2 ） is varied from 3% to 80% and the temperature （Tcof） from 1200 K to 1700 K. The Eddy Dissipation Concept （EDC） model with detailed reaction mechanisms GRI-Mech 3.0 is used for all simulations. To validate the modeling, several JHC flames are predicted under the experimental conditions of Dally et al. [Proc. Combust. Inst., 29 （1）, 1147-1154 （2002）] and the results obtained match well with the measurements. Results demonstrate that, when Yo2 decreased, the diffusion combustion is likely to transform from traditional combustion to MILD （Moderate or Intense Low-oxygen Dilution） combustion mode. When Tcof is higher, the temperature distribution over the whole domain trends to be more uniform. Reducing yo2 or Tcof leads to less production of intermediate species OH and CO. It is worth noting that if Yo2 is high enough （ Yo2 〉80%）, increasing Yo2 does not cause obvious temperature increase.展开更多
The convective heat transfer coefficient and surface emissivity before and after flame occurrence on a wood specimen surface and the flame heat flux were estimated using the repulsive particle swarm optimization algor...The convective heat transfer coefficient and surface emissivity before and after flame occurrence on a wood specimen surface and the flame heat flux were estimated using the repulsive particle swarm optimization algorithm and cone heater test results. The cone heater specified in the ISO 5660 standards was used, and six cone heater heat fluxes were tested. Preservative-treated Douglas fir 21 mm in thickness was used as the wood specimen in the tests. This study confirmed that the surface temperature of the specimen, which was calculated using the convective heat transfer coefficient, surface emissivity and flame heat flux on the wood specimen by a repulsive particle swarm optimization algorithm, was consistent with the measured temperature. Considering the measurement errors in the surface temperature of the specimen, the applicability of the optimization method considered in this study was evaluated.展开更多
基金supported by the National Natural Science Foundation of China(52106284)the Natural Science Foundation of Hebei Province(B2021507001)support of Project to Promote Innovation in Doctoral Research at CPPU(BSKY202302).
文摘The combustion and explosion characteristics of lithium-ion battery vent gas is a key factor in determining the fire hazard of lithium-ion batteries.Investigating the combustion and explosion hazards of lithium-ion batteries vent gas can provide guidance for rescue and protection in explosion accidents in energy storage stations and new energy vehicles,thereby promoting the application and development of lithium-ion batteries.Based on this understanding and combined with previous research on gas production from lithium-ion batteries,this article conducted a study on the combustion and explosion risks of vent gas from thermal runaway of 18650 LFP batteries with different states of charge(SOCs).The explosion limit of mixed gases affected by carbon dioxide inert gas is calculated through the“elimination”method,and the Chemkin-Pro software is used to numerically simulate the laminar flame speed and adiabatic flame temperature of the battery vent gas.And the concentration of free radicals and sensitivity coefficients of major elementary reactions in the system are analyzed to comprehensively evaluate the combustion explosion hazard of battery vent gas.The study found that the 100%SOC battery has the lowest explosion limit of the vent gas.The inhibitory elementary reaction sensitivity coefficient in the reaction system is lower and the concentration of free radicals is higher.Therefore,it has the maximum laminar flame speed and adiabatic flame temperature.The combustion and explosion hazard of battery vent gas increases with the increase of SOC,and the risk of explosion is the greatest and most harmful when SOC reaches 100%.However,the related hazards decrease to varying degrees with overcharging of the battery.This article provides a feasible method for analyzing the combustion mechanism of vent gas from lithium-ion batteries,revealing the impact of SOC on the hazardousness of battery vent gas.It provides references for the safety of storage and transportation of lithium-ion batteries,safety protection of energy storage stations,and the selection of related fire extinguishing agents.
基金Supported by the National Natural Science Foundation of China （51276002）, and the Specific Research Fund for the Doctoral Program of Higher Education of China （20110001130014）.
文摘This paper investigates the effects of coflow O2 level and temperature on diffusion flame of a CH4/H2 jet in hot coflow （JHC） from a burner system similar to that of Dally et al. The coflow O2 mass fraction （ Yo2 ） is varied from 3% to 80% and the temperature （Tcof） from 1200 K to 1700 K. The Eddy Dissipation Concept （EDC） model with detailed reaction mechanisms GRI-Mech 3.0 is used for all simulations. To validate the modeling, several JHC flames are predicted under the experimental conditions of Dally et al. [Proc. Combust. Inst., 29 （1）, 1147-1154 （2002）] and the results obtained match well with the measurements. Results demonstrate that, when Yo2 decreased, the diffusion combustion is likely to transform from traditional combustion to MILD （Moderate or Intense Low-oxygen Dilution） combustion mode. When Tcof is higher, the temperature distribution over the whole domain trends to be more uniform. Reducing yo2 or Tcof leads to less production of intermediate species OH and CO. It is worth noting that if Yo2 is high enough （ Yo2 〉80%）, increasing Yo2 does not cause obvious temperature increase.
基金support from the research fund of the National Emergency Management Agency.(NEMA- Infra-2014-103)
文摘The convective heat transfer coefficient and surface emissivity before and after flame occurrence on a wood specimen surface and the flame heat flux were estimated using the repulsive particle swarm optimization algorithm and cone heater test results. The cone heater specified in the ISO 5660 standards was used, and six cone heater heat fluxes were tested. Preservative-treated Douglas fir 21 mm in thickness was used as the wood specimen in the tests. This study confirmed that the surface temperature of the specimen, which was calculated using the convective heat transfer coefficient, surface emissivity and flame heat flux on the wood specimen by a repulsive particle swarm optimization algorithm, was consistent with the measured temperature. Considering the measurement errors in the surface temperature of the specimen, the applicability of the optimization method considered in this study was evaluated.
