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KOH添加方式对煤热解活化气固产物的影响 被引量:3
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作者 罗云焕 张天开 +3 位作者 吕学枚 张永发 王影 刘俊 《煤炭转化》 CAS CSCD 北大核心 2020年第5期18-26,共9页
以陕西低阶烟煤为原料,研究了在低碱煤质量比(mKOH∶mcoal=1∶1)下,不同温度时浸渍法、超声法和干混法三种KOH添加方式对煤热解活化过程中气相产物CH4,CO和CO2释放规律及固相产物中活性炭和碳纳米管混合物的影响。结果表明:浸渍法中KOH... 以陕西低阶烟煤为原料,研究了在低碱煤质量比(mKOH∶mcoal=1∶1)下,不同温度时浸渍法、超声法和干混法三种KOH添加方式对煤热解活化过程中气相产物CH4,CO和CO2释放规律及固相产物中活性炭和碳纳米管混合物的影响。结果表明:浸渍法中KOH通过扩散作用进入煤颗粒内部孔隙,KOH充分分散与煤接触良好,活化反应剧烈,所制备固相产物的比表面积为1081.31 m^2/g(40℃),远大于超声法制备的固相产物的比表面积(880.39 m^2/g)和干混法制备的固相产物的比表面积(425.66 m^2/g);气相产物中CO和CO2累积量由大到小的KOH添加方式依次为浸渍法、超声法、干混法,CH4累积量由大到小的KOH添加方式依次为干混法、超声法、浸渍法;KOH在活化煤过程中,使煤中固有Fe等矿物元素暴露出来,二者共同催化煤热解过程中产生的CH4等烃类气体转化为碳纳米管,固相产物碳纳米管的表观含量由大到小的KOH添加方式依次为浸渍法、超声法、干混法。 展开更多
关键词 基活性炭 KOH活化 低碱法 碳纳米管 煤中矿物质元素
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Distribution and occurrence of trace elements in the No.14 coal from the Huolinhe mine 被引量:5
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作者 Xiangfei Bai Yue Wang Wenhua Li 《International Journal of Coal Science & Technology》 EI 2017年第3期199-213,共15页
Optical microscopy, and scanning electron microscopy in conjunction with energy dispersed X-ray spectrometry (SEM-EDX), have been used to study the minerals and the concentrations of 12 trace elements in the No.14 c... Optical microscopy, and scanning electron microscopy in conjunction with energy dispersed X-ray spectrometry (SEM-EDX), have been used to study the minerals and the concentrations of 12 trace elements in the No.14 coal from the Huolinhe mine, Inner Mongolia China. The distribution, affinity and removability of the trace elements were studied by float-sink experiments and petrological methods. A high mineral content, dominated by clay minerals, was found in the No.14 coal from the Huolinhe mine. The concentrations of As, Sb and Hg are relatively high compared to the average values for Chinese coals. As, Cr, Hg, Li, Mn, Pb are mainly associated with the minerals while Cd, Co, Ni, Sb, and Se are evenly distributed between the minerals and the organic matter. Be and Ba are mainly distributed in the minerals with a minor proportion in the organic matter. Most elements have a low organic affinity, although Sb, Se, Co, Cd, Ni are closely integrated with the organic matter. High theoretical removabilities are indicated for most trace elements. So it may be possible to lower the concentrations of trace elements during coal preparation. 展开更多
关键词 Trace elements Modes of occurrence - Organic affinity REMOVABILITY Huolinhe coal
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