Coals consist of some molecules trapped within an organic matrix from which some organic compounds can be extracted by solvents. The Soxhlet technique has been widely used for extracting organic compounds. Microwave h...Coals consist of some molecules trapped within an organic matrix from which some organic compounds can be extracted by solvents. The Soxhlet technique has been widely used for extracting organic compounds. Microwave heating methods may be successfully applied in the field of coal science. Acetone extraction yields and the chemical composition of the extract were investigated using a typical Chinese coal, Shenfu coal, with microwave-assisted extraction. The acetone extract and residue were analyzed by GC/MS and carbon-13 nuclear magnetic resonance spectroscopy respectively. The carbon spectra were converted into several numerical parameters, fa, Ha, Xb, which indicate the difference in macromolecular structure between Shenfu coal and its residue. Furthermore, a hybrid genetic algorithm was employed using these parameters to approximate a coal macromolecule by assembling the structural fragments or functional groups into a large and complicated structure.展开更多
A liquid-solid fluidized bed separator, used for the separation of coarse slime, was developed. Test parti- cles sized in the range from 0.25 to 0.5, 0.5 to 1.0, and 0.25 to 1.0 mm were separated in the liquid-solid f...A liquid-solid fluidized bed separator, used for the separation of coarse slime, was developed. Test parti- cles sized in the range from 0.25 to 0.5, 0.5 to 1.0, and 0.25 to 1.0 mm were separated in the liquid-solid fluidized bed. Beds with column heights of 1200, 1500, and 1800 mm were tried. The clean coal and the railings were subsequently analyzed by float-sink testing. The results showed that the ash and yield of clean coal both decreased with increasing column height, for all three size fractions, and that the ash of the clean coal obtained from tests on the broader size fraction was less than that from the narrower sized fractions. The separation density decreased with increasing column height. The lowest E value was seen for a column height of 1500 ram, for which conditions the separation density was 1.45 g/cm3. The E value was 0.084 for the 0.25-0.5 mm fraction but the corresponding separation density was 1.48 g/cm3, and the E value 0.089, for the broader 0.25-1.0 mm fraction.展开更多
基金Project 40472082 supported by the National Natural Science Foundation of China
文摘Coals consist of some molecules trapped within an organic matrix from which some organic compounds can be extracted by solvents. The Soxhlet technique has been widely used for extracting organic compounds. Microwave heating methods may be successfully applied in the field of coal science. Acetone extraction yields and the chemical composition of the extract were investigated using a typical Chinese coal, Shenfu coal, with microwave-assisted extraction. The acetone extract and residue were analyzed by GC/MS and carbon-13 nuclear magnetic resonance spectroscopy respectively. The carbon spectra were converted into several numerical parameters, fa, Ha, Xb, which indicate the difference in macromolecular structure between Shenfu coal and its residue. Furthermore, a hybrid genetic algorithm was employed using these parameters to approximate a coal macromolecule by assembling the structural fragments or functional groups into a large and complicated structure.
基金supports for this work provided by the National Natural Science Foundation of China (No. 50974120)the Fundamental Research Funds for the Central Universities (No.2010QNB08)
文摘A liquid-solid fluidized bed separator, used for the separation of coarse slime, was developed. Test parti- cles sized in the range from 0.25 to 0.5, 0.5 to 1.0, and 0.25 to 1.0 mm were separated in the liquid-solid fluidized bed. Beds with column heights of 1200, 1500, and 1800 mm were tried. The clean coal and the railings were subsequently analyzed by float-sink testing. The results showed that the ash and yield of clean coal both decreased with increasing column height, for all three size fractions, and that the ash of the clean coal obtained from tests on the broader size fraction was less than that from the narrower sized fractions. The separation density decreased with increasing column height. The lowest E value was seen for a column height of 1500 ram, for which conditions the separation density was 1.45 g/cm3. The E value was 0.084 for the 0.25-0.5 mm fraction but the corresponding separation density was 1.48 g/cm3, and the E value 0.089, for the broader 0.25-1.0 mm fraction.
