The change rules of displacement field characteristics of coal seam and tunners surrounding rock were obtained by means of numerical simulation-FLAC^3D and site observation, and according to engineering geology and ex...The change rules of displacement field characteristics of coal seam and tunners surrounding rock were obtained by means of numerical simulation-FLAC^3D and site observation, and according to engineering geology and exploitation technology of 1151 （3） fully mechanized top coal caving （FMTC） face in Xieqiao colliery. The research＇s results show that the top coal displacement on the top of FMTC face is apparently larger than those of the middle and the bottom, the top coal begins to move in the front of the face＇s wall, and the sub-level top coal-rock moves ahead of the low-level top coal-rock, the vertical displacement of top coal-rock increases gradually as the decreasing of distance to face Top coal and overlying strata in vertical direction are always in compressed state in the front of face, then the top coal begins to separate from the overlying strata at the upside of face. The support loading at face is mainly the deformation pressure due to top coal and main roof＇s movement, and it is not suitable for the FMTC face with traditional support design. Surrounding rock movement of the face is of near-field effect, the surrounding rock deformation is acute greatly near to the face, the ideas of supporting design for the tailentry and headentry should be changed from loading control to deformation control.展开更多
An insoluble β-cyclodextrin polymer cross-linked with epichlorohydrin was prepared, and its structure was identified with infrared spectrum. Colloid stationary phase was prepared by dissolving the polymer in the mixe...An insoluble β-cyclodextrin polymer cross-linked with epichlorohydrin was prepared, and its structure was identified with infrared spectrum. Colloid stationary phase was prepared by dissolving the polymer in the mixed solvent of diisopropyl ether, methylene dichloride and benzene and treated for 0.5 h by ultrasonication, and then was coated on a fused silica capillary column. The optimun reaction conditions are as follows: the mole ratio of epichlohydrin to β-cyclodextrin is 12.1:1, reacting at 65 °C for 24 h. The Chromatographic performance such as column efficiency, thermal stabilities and polarity were studied, two kinds of disubstituted benzene isomers and eight pairs of enantiomers were separated on the capillary column. The results show that the β-cyclodextrin polymer is suitable for use as a capillary gas chromatographic stationary phase, and possess excellent chromatographic properties in separating enantiomers and position isomers.展开更多
In view of the stress concentration problem left by the joint coal seams mining since the reservation of the coal pillar, it was proposed that non-pillar mining technology be used in Dongrong No.2 coal mine. The numer...In view of the stress concentration problem left by the joint coal seams mining since the reservation of the coal pillar, it was proposed that non-pillar mining technology be used in Dongrong No.2 coal mine. The numerical simulation software FLAG2D was used to draw the relationship between surrounding rock deformation of roadway driving along next goaf and the size of the coal pillar, so the safety and suitable position of roadway was determined. The distribution of lateral abutment pressure was measured by using the ZYJ-30 drilling stress gauge in the coal wall. The conclusions of the numerical simulation were verified.展开更多
This paper seeks to enhance the understanding that the horizontal stresses build up and release during coal pillar loading and unloading(post-failure) drawing upon three decades of observations, geomechanical monitori...This paper seeks to enhance the understanding that the horizontal stresses build up and release during coal pillar loading and unloading(post-failure) drawing upon three decades of observations, geomechanical monitoring and numerical modeling in bump-prone U.S. mines. The focus is on induced horizontal stress in mine pillars and surrounding strata as highly stressed pillars punch into the roof and floor, causing shear failure and buckling of strata; under stiff stratigraphic units of some western US mines, these events could be accompanied by violent failure of pillar cores. Pillar punching eventually results in tensile stresses at the base of the pillar, facilitating transition into the post-failure regime; this transition will be nonviolent if certain conditions are met, notably the presence of interbedded mudstones with low shear strength properties and proper mine designs for controlling seismicity and dynamic loads. The study clearly shows high confining stress build-up in coal pillars resulting in up to twice higher peak vertical stress and high strain energy accumulations in some western US mines in comparison with peak stresses predicted using common empirical pillar design methods. It is the unstable release of this strain energy that can cause significant damage resulting from pillar dilation and ground movements. These forces are much greater than the capacity of most common internal support systems, resulting in horizontal stressinduced roof falls locally, in mines under unremarkable far-field horizontal stress. Attention should be placed on pillar designs as increasing support density may prove to be ineffective. This mechanism is analyzed using field measurements and generic finite-difference stress analyses. The study confirms the higher load carrying capacity of confinement-controlled coal seams in comparison with structurally controlled coal seams. Such significant differences in confining stresses are not taken into account when estimating peak pillar strength using most common empirical techniques such as those proposed by Bieniawski and Salamon. While using lower pillar strength estimates may be considered conservative,it underestimates the actual capacity of pillars in accumulating much higher stress and strain energies,misleading the designer and inadvertently diminishing mine safety. The role of induced horizontal stress in mine pillars and surrounding strata is emphasized in coal pillar mechanics of violent failure. The triggering mechanism for the violent events is sudden loss of pillar confinement due to dynamic loading resulting from failure of overlying stiff and strong strata. Evidence of such mechanism is noted in the field by observed red-dust at the coal-rock interfaces at the location of coal bumps and irregular, periodic caving in room-and-pillar mines quantified through direct pressure measurements in the gob.展开更多
In order to improve the precision of mining subsidence prediction, a mathematical model using Support Vector Machine （SVM） was established to calculate the displacement factor. The study is based on a comprehensive ...In order to improve the precision of mining subsidence prediction, a mathematical model using Support Vector Machine （SVM） was established to calculate the displacement factor. The study is based on a comprehensive analysis of factors affecting the displacement factor, such as mechanical properties of the cover rock, the ratio of mining depth to seam thickness, dip angle of the coal seam and the thickness of loose layer. Data of 63 typical observation stations were used as a training and testing sample set. A SVM regression model of the displacement factor and the factors affecting it was established with a kernel function, an insensitive loss factor and a properly selected penalty factor. Given an accurate calculation algorithm for testing and analysis, the results show that an SVM regression model can calcu- late displacement factor precisely and reliable precision can be obtained which meets engineering requirements. The experimental results show that the method to calculation of the displacement factor, based on the SVM method, is feasible. The many factors affecting the displacement factor can be consid- ered with this method. The research provides an efficient and accurate approach for the calculation of displacement in mining subsidence orediction.展开更多
The commercial recovery of methane from coal is well established in the coalbed methane(CBM) blocks at the east margin of Ordos Basin, China. CBM forms with various carbon isotopic ratios(δ13CPDB) due to the carbon i...The commercial recovery of methane from coal is well established in the coalbed methane(CBM) blocks at the east margin of Ordos Basin, China. CBM forms with various carbon isotopic ratios(δ13CPDB) due to the carbon isotopic fractionation in biogenical or thermogenical processes. Based on the geologic evolution of coalbed reservoir and studies on the characteristics of δ13 CPDB values distributed spatially(e.g., horizontal CBM well location area, vertical coal burial zone, coal rank, etc.) and temporally(e.g., geologic evolution history), we explored the formation mechanism of carbon isotopic of methane. The relatively low δ13 CPDB values are widely distributed along the research area, indicating a trend of "lighter-heavier-lighter" from north to south. From a combination analysis of the relationship between δ13 CPDB and the relative effects, the essential aspects in determining CBM carbon isotope being light in the study area are: the genesis of secondary biogas in the north; water soluble effects in the active hydrodynamic areas in the middle; desorption fractionation effect promoted by tectonic evolution in the south; and the sudden warming hydrocarbon fractionation accelerated by magmatic event in particular areas(e.g., Linxian).展开更多
基金National Natural Science Foundation of China(50674003)National Basic Research Program(973)
文摘The change rules of displacement field characteristics of coal seam and tunners surrounding rock were obtained by means of numerical simulation-FLAC^3D and site observation, and according to engineering geology and exploitation technology of 1151 （3） fully mechanized top coal caving （FMTC） face in Xieqiao colliery. The research＇s results show that the top coal displacement on the top of FMTC face is apparently larger than those of the middle and the bottom, the top coal begins to move in the front of the face＇s wall, and the sub-level top coal-rock moves ahead of the low-level top coal-rock, the vertical displacement of top coal-rock increases gradually as the decreasing of distance to face Top coal and overlying strata in vertical direction are always in compressed state in the front of face, then the top coal begins to separate from the overlying strata at the upside of face. The support loading at face is mainly the deformation pressure due to top coal and main roof＇s movement, and it is not suitable for the FMTC face with traditional support design. Surrounding rock movement of the face is of near-field effect, the surrounding rock deformation is acute greatly near to the face, the ideas of supporting design for the tailentry and headentry should be changed from loading control to deformation control.
文摘An insoluble β-cyclodextrin polymer cross-linked with epichlorohydrin was prepared, and its structure was identified with infrared spectrum. Colloid stationary phase was prepared by dissolving the polymer in the mixed solvent of diisopropyl ether, methylene dichloride and benzene and treated for 0.5 h by ultrasonication, and then was coated on a fused silica capillary column. The optimun reaction conditions are as follows: the mole ratio of epichlohydrin to β-cyclodextrin is 12.1:1, reacting at 65 °C for 24 h. The Chromatographic performance such as column efficiency, thermal stabilities and polarity were studied, two kinds of disubstituted benzene isomers and eight pairs of enantiomers were separated on the capillary column. The results show that the β-cyclodextrin polymer is suitable for use as a capillary gas chromatographic stationary phase, and possess excellent chromatographic properties in separating enantiomers and position isomers.
文摘In view of the stress concentration problem left by the joint coal seams mining since the reservation of the coal pillar, it was proposed that non-pillar mining technology be used in Dongrong No.2 coal mine. The numerical simulation software FLAG2D was used to draw the relationship between surrounding rock deformation of roadway driving along next goaf and the size of the coal pillar, so the safety and suitable position of roadway was determined. The distribution of lateral abutment pressure was measured by using the ZYJ-30 drilling stress gauge in the coal wall. The conclusions of the numerical simulation were verified.
文摘This paper seeks to enhance the understanding that the horizontal stresses build up and release during coal pillar loading and unloading(post-failure) drawing upon three decades of observations, geomechanical monitoring and numerical modeling in bump-prone U.S. mines. The focus is on induced horizontal stress in mine pillars and surrounding strata as highly stressed pillars punch into the roof and floor, causing shear failure and buckling of strata; under stiff stratigraphic units of some western US mines, these events could be accompanied by violent failure of pillar cores. Pillar punching eventually results in tensile stresses at the base of the pillar, facilitating transition into the post-failure regime; this transition will be nonviolent if certain conditions are met, notably the presence of interbedded mudstones with low shear strength properties and proper mine designs for controlling seismicity and dynamic loads. The study clearly shows high confining stress build-up in coal pillars resulting in up to twice higher peak vertical stress and high strain energy accumulations in some western US mines in comparison with peak stresses predicted using common empirical pillar design methods. It is the unstable release of this strain energy that can cause significant damage resulting from pillar dilation and ground movements. These forces are much greater than the capacity of most common internal support systems, resulting in horizontal stressinduced roof falls locally, in mines under unremarkable far-field horizontal stress. Attention should be placed on pillar designs as increasing support density may prove to be ineffective. This mechanism is analyzed using field measurements and generic finite-difference stress analyses. The study confirms the higher load carrying capacity of confinement-controlled coal seams in comparison with structurally controlled coal seams. Such significant differences in confining stresses are not taken into account when estimating peak pillar strength using most common empirical techniques such as those proposed by Bieniawski and Salamon. While using lower pillar strength estimates may be considered conservative,it underestimates the actual capacity of pillars in accumulating much higher stress and strain energies,misleading the designer and inadvertently diminishing mine safety. The role of induced horizontal stress in mine pillars and surrounding strata is emphasized in coal pillar mechanics of violent failure. The triggering mechanism for the violent events is sudden loss of pillar confinement due to dynamic loading resulting from failure of overlying stiff and strong strata. Evidence of such mechanism is noted in the field by observed red-dust at the coal-rock interfaces at the location of coal bumps and irregular, periodic caving in room-and-pillar mines quantified through direct pressure measurements in the gob.
基金the Research and Innovation Program for College and University Graduate Students in Jiangsu Province (No.CX10B_141Z)the National Natural Science Foundation of China (No.41071273) for support of this project
文摘In order to improve the precision of mining subsidence prediction, a mathematical model using Support Vector Machine （SVM） was established to calculate the displacement factor. The study is based on a comprehensive analysis of factors affecting the displacement factor, such as mechanical properties of the cover rock, the ratio of mining depth to seam thickness, dip angle of the coal seam and the thickness of loose layer. Data of 63 typical observation stations were used as a training and testing sample set. A SVM regression model of the displacement factor and the factors affecting it was established with a kernel function, an insensitive loss factor and a properly selected penalty factor. Given an accurate calculation algorithm for testing and analysis, the results show that an SVM regression model can calcu- late displacement factor precisely and reliable precision can be obtained which meets engineering requirements. The experimental results show that the method to calculation of the displacement factor, based on the SVM method, is feasible. The many factors affecting the displacement factor can be consid- ered with this method. The research provides an efficient and accurate approach for the calculation of displacement in mining subsidence orediction.
基金supported by the Major National Science and Technology Special Projects (Grant No. 2011ZX05062-01)the National Natural Science Foundation of China (Grant No. 41272175)+1 种基金the Special Fund for Scientific Research on Public Causes from Ministry of Land and Resources of the People’s Republic of China’s (Grant No. 201311015-01)the Fundamental Research Funds for the Central Universities (Grant No. 2652013057)
文摘The commercial recovery of methane from coal is well established in the coalbed methane(CBM) blocks at the east margin of Ordos Basin, China. CBM forms with various carbon isotopic ratios(δ13CPDB) due to the carbon isotopic fractionation in biogenical or thermogenical processes. Based on the geologic evolution of coalbed reservoir and studies on the characteristics of δ13 CPDB values distributed spatially(e.g., horizontal CBM well location area, vertical coal burial zone, coal rank, etc.) and temporally(e.g., geologic evolution history), we explored the formation mechanism of carbon isotopic of methane. The relatively low δ13 CPDB values are widely distributed along the research area, indicating a trend of "lighter-heavier-lighter" from north to south. From a combination analysis of the relationship between δ13 CPDB and the relative effects, the essential aspects in determining CBM carbon isotope being light in the study area are: the genesis of secondary biogas in the north; water soluble effects in the active hydrodynamic areas in the middle; desorption fractionation effect promoted by tectonic evolution in the south; and the sudden warming hydrocarbon fractionation accelerated by magmatic event in particular areas(e.g., Linxian).
