In accordance with the confusion on classification of source rocks, the authors raised a source rock classification for its enriched and dispersed organic matter types based on both Alpern’s idea and maceral genesis/...In accordance with the confusion on classification of source rocks, the authors raised a source rock classification for its enriched and dispersed organic matter types based on both Alpern’s idea and maceral genesis/composition. The determined rock type is roughly similar to palynofacies of Combaz , whereas it is "rock maceral facies (for coal viz. coal facies)" in strictly speaking. Therefore, it is necessary to use the organic ingredients classification proposed by the authors so that it can be used for both maceral analysis and environment research . This source rock classification not only shows sedimentology and diagenetic changes but also acquires organic matter type even if hydrocarbon potential derived from maceral’s geochemical parameters. So, it is considered as genetic classification. The "rock maceral facies" may be transformed to sedimentary organic facies , which is used as quantitative evaluation means if research being perfect.Now, there are many models in terms of structure either for coal or for kerogen. In our opinion, whatever coal or kerogen ought be polymer, then we follow Combaz’s thought and study structure of amorphous kerogens which are accordance with genetic mechanism showing biochemical and geochemical process perfectly. Here, we use the time of flight secondary ion mass spectrometry (TOFSIMS) to expand Combaz’s models from three to five. They are also models for coal.展开更多
In the eastern edge of the Ordos Basin,the coalbed methane(CBM)development has not made substantial progress in the past20 years,and the origin of gas can be used to guide the CBM block-selecting and development.Based...In the eastern edge of the Ordos Basin,the coalbed methane(CBM)development has not made substantial progress in the past20 years,and the origin of gas can be used to guide the CBM block-selecting and development.Based on the 37 sets of carbon isotope data,the origin of the gas was determined and the origin mechanism was studied in this work.The 13CPDB of methane ranges from 70.5‰to 36.19‰in the eastern edge in the Ordos Basin and the value becomes heavier from the north to the south.The secondary biogenic gas and the thermogenic gas are mixed in the shallow area and the thermogenic gas occurs in the medium and deep levels.The phenomenon is controlled mainly by the distribution of coal rank and hydrodynamics.Firstly,based on the relationship between China coal rank and methane 13CPDB,the medium rank coal is dominant in the eastern edge of the Ordos Basin,and the mixture of the secondary biogenic gas and the thermogenic gas is formed in the coal of vitrinite reflectant ratio(Rmax)between 0.5%and 2.0%if there is appropriate hydrodynamics;at the same time,because of the shallow burial depth,and the well-developed coal outcrop,meteoric water and other surface water carrying bacteria recharge the coal reservoir,metabolize the organic compounds at a relatively low temperature,and generate methane and carbon dioxide.Wherever the trapping mechanisms occur in the coal,such as Liulin and Hancheng,modern gas content should be high.展开更多
基金National Natural Science Foundation of China(4 9672 13 1)
文摘In accordance with the confusion on classification of source rocks, the authors raised a source rock classification for its enriched and dispersed organic matter types based on both Alpern’s idea and maceral genesis/composition. The determined rock type is roughly similar to palynofacies of Combaz , whereas it is "rock maceral facies (for coal viz. coal facies)" in strictly speaking. Therefore, it is necessary to use the organic ingredients classification proposed by the authors so that it can be used for both maceral analysis and environment research . This source rock classification not only shows sedimentology and diagenetic changes but also acquires organic matter type even if hydrocarbon potential derived from maceral’s geochemical parameters. So, it is considered as genetic classification. The "rock maceral facies" may be transformed to sedimentary organic facies , which is used as quantitative evaluation means if research being perfect.Now, there are many models in terms of structure either for coal or for kerogen. In our opinion, whatever coal or kerogen ought be polymer, then we follow Combaz’s thought and study structure of amorphous kerogens which are accordance with genetic mechanism showing biochemical and geochemical process perfectly. Here, we use the time of flight secondary ion mass spectrometry (TOFSIMS) to expand Combaz’s models from three to five. They are also models for coal.
基金supported by the National Basic Research Program of China(Grant No.2009CB219602)
文摘In the eastern edge of the Ordos Basin,the coalbed methane(CBM)development has not made substantial progress in the past20 years,and the origin of gas can be used to guide the CBM block-selecting and development.Based on the 37 sets of carbon isotope data,the origin of the gas was determined and the origin mechanism was studied in this work.The 13CPDB of methane ranges from 70.5‰to 36.19‰in the eastern edge in the Ordos Basin and the value becomes heavier from the north to the south.The secondary biogenic gas and the thermogenic gas are mixed in the shallow area and the thermogenic gas occurs in the medium and deep levels.The phenomenon is controlled mainly by the distribution of coal rank and hydrodynamics.Firstly,based on the relationship between China coal rank and methane 13CPDB,the medium rank coal is dominant in the eastern edge of the Ordos Basin,and the mixture of the secondary biogenic gas and the thermogenic gas is formed in the coal of vitrinite reflectant ratio(Rmax)between 0.5%and 2.0%if there is appropriate hydrodynamics;at the same time,because of the shallow burial depth,and the well-developed coal outcrop,meteoric water and other surface water carrying bacteria recharge the coal reservoir,metabolize the organic compounds at a relatively low temperature,and generate methane and carbon dioxide.Wherever the trapping mechanisms occur in the coal,such as Liulin and Hancheng,modern gas content should be high.
