Vibrational IR spectra and light‐off investigations show that NH3forms via the“hydrogen down”reaction of adsorbed CO and NO with hydroxyl groups on a CeO2support during the catalytic reduction of NO by CO.The prese...Vibrational IR spectra and light‐off investigations show that NH3forms via the“hydrogen down”reaction of adsorbed CO and NO with hydroxyl groups on a CeO2support during the catalytic reduction of NO by CO.The presence of water in the reaction stream results in a significant increase in NH3selectivity.This result is due to water‐induced hydroxylation promoting NH3formation and the competitive adsorption of H2O and NO at the same sites,which inhibits the reactivity of NO reduction by NH3.展开更多
Coal is the dominant primary energy source in China and the major source of greenhouse gases and air pollutants. To facilitate the use of coal in an environmentally satisfactory and economically viable way, clean coal...Coal is the dominant primary energy source in China and the major source of greenhouse gases and air pollutants. To facilitate the use of coal in an environmentally satisfactory and economically viable way, clean coal technologies （CCTs） are necessary. This paper presents a review of recent research and development of four kinds of CCTs： coal power generation; coal conversion; pollution control; and carbon capture, utilization, and storage. It also outlines future perspectives on directions for technology re search and development （R＆D）. This review shows that China has made remarkable progress in the R＆D of CCTs, and that a number of CCTs have now entered into the commercialization stage.展开更多
A three stage equilibrium model is developed for coal gasification in the Texaco type coal gasifiersbased on Aspen Plus to calculate the composition of product gas, carbon conversion, and gasification teml^erature. Th...A three stage equilibrium model is developed for coal gasification in the Texaco type coal gasifiersbased on Aspen Plus to calculate the composition of product gas, carbon conversion, and gasification teml^erature. The model is divided into three stages including pyrolysis and combustion stage, char gas reaction stage, and gas p.hase reaction stage. Part of the water produced in thepyrolysis and combust!on stag.e is assumed to be involved inthe second stage to react with the unburned carbon. Carbon conversion is then estimated in the second stage by steam participation ratio expressed as a function of temperature. And the gas product compositions are calculated from gas phase reactions in the third stage. The simulation results are consistent with published experimental data.展开更多
Exhaustion of profitable coal resources makes for need of innovation including underground coal gasification(UCG).One of the most important problems of UCG is evaluation of the combustion area in underground coal seam...Exhaustion of profitable coal resources makes for need of innovation including underground coal gasification(UCG).One of the most important problems of UCG is evaluation of the combustion area in underground coal seams.Physicochemical parameters of coal,in a whole,and coal mineral substance are changed under heating and combusting.Thermo-chemical conversion of coal mineral components has an effect on magnetic characteristics of coal seam and can be used for real-time control of combusting area.To this guessing check laboratory experiments have been made as an activity of the Far Eastern Federal University.Our investigation based on a theoretical analysis and laboratory simulation tests.Typical results of the laboratory experiments are presented below.Under heating coal thermo-chemical magnetization is forming.Coal's magnetic parameters varieties from anti-ferromagnetiсto ferromagnetic.Anti-ferromagnetic pyrite and siderite presented into coal mass is transformed into magnetic hematite and magnetite under heating.Therefore,geomagnetic is expected to be a useful geophysical tool to for evaluation of combustion volume and its migration for underground coal gasification.展开更多
The idea of the transformation of coal in underground into synthetic gas so-called syngas is interested in world in many centuries. Underground Coal Gasification （UCG） is an in-situ technique to recover the fuel or ...The idea of the transformation of coal in underground into synthetic gas so-called syngas is interested in world in many centuries. Underground Coal Gasification （UCG） is an in-situ technique to recover the fuel or feedstock value of coal that is not economically available through conventional recovery technologies. Today, less than one sixth of the world＇s coal is economically accessible. Today, similarly to all other countries in the world also in Slovakia there is an interest in the revival and perfection of the UCG technology. From the viewpoint of content the research is directed toward to increasing heating capacity of syngas. From the standpoint of the methods used the research can be divided into 2 approaches： experiments in UCG laboratory and mathematical modeling, including simulation studies. Both approaches have helped to discover complicated relationships during UCG and they will be the subject of this paper. The most important factors are methods, the humidity of the coal, heat losses, temperatures in relevant zones, the composition of oxidation agents and the permeability of the coal. The calorific value of syngas was found generally to be 0.55-4.45 MJ.Nm^-3 with a maximum of 25.51 MJ.m^-3 if only air is used as the oxidation agent. Where a mixture of air and oxygen is used, calorific values in the range 0.43-6.38 MJ.m^-3 were generally obtained, with maximum 27.53 MJ·m^-3. Analysis was carried out on these big differences in order to improve UCG.展开更多
基金supported by the National Natural Science Foundation of China (21463015)the Provincial Applied Fundamental Research Program of Yunnan (2014FA045)the National High Technology Research and Development Program of China (863 Program,2015AA034603)~~
文摘Vibrational IR spectra and light‐off investigations show that NH3forms via the“hydrogen down”reaction of adsorbed CO and NO with hydroxyl groups on a CeO2support during the catalytic reduction of NO by CO.The presence of water in the reaction stream results in a significant increase in NH3selectivity.This result is due to water‐induced hydroxylation promoting NH3formation and the competitive adsorption of H2O and NO at the same sites,which inhibits the reactivity of NO reduction by NH3.
基金Acknowledgements The authors gratefully acknowledge the funding support from the National Key Basic Research Program of China （2013CB228500）, the National Natural Science Foundation of Chi- na （71203119）, and the Advanced Coal Technology Consortium of CERC （2016YFE0102500）.
文摘Coal is the dominant primary energy source in China and the major source of greenhouse gases and air pollutants. To facilitate the use of coal in an environmentally satisfactory and economically viable way, clean coal technologies （CCTs） are necessary. This paper presents a review of recent research and development of four kinds of CCTs： coal power generation; coal conversion; pollution control; and carbon capture, utilization, and storage. It also outlines future perspectives on directions for technology re search and development （R＆D）. This review shows that China has made remarkable progress in the R＆D of CCTs, and that a number of CCTs have now entered into the commercialization stage.
基金Supported by the Major State Basic Research Development Program of China(2012CB720500)the National Natural Science Foundation of China(U1162202,61174118)+1 种基金the National Science Fund for Outstanding Young Scholars(61222303)Shanghai Leading Academic Discipline Project(B504)
文摘A three stage equilibrium model is developed for coal gasification in the Texaco type coal gasifiersbased on Aspen Plus to calculate the composition of product gas, carbon conversion, and gasification teml^erature. The model is divided into three stages including pyrolysis and combustion stage, char gas reaction stage, and gas p.hase reaction stage. Part of the water produced in thepyrolysis and combust!on stag.e is assumed to be involved inthe second stage to react with the unburned carbon. Carbon conversion is then estimated in the second stage by steam participation ratio expressed as a function of temperature. And the gas product compositions are calculated from gas phase reactions in the third stage. The simulation results are consistent with published experimental data.
文摘Exhaustion of profitable coal resources makes for need of innovation including underground coal gasification(UCG).One of the most important problems of UCG is evaluation of the combustion area in underground coal seams.Physicochemical parameters of coal,in a whole,and coal mineral substance are changed under heating and combusting.Thermo-chemical conversion of coal mineral components has an effect on magnetic characteristics of coal seam and can be used for real-time control of combusting area.To this guessing check laboratory experiments have been made as an activity of the Far Eastern Federal University.Our investigation based on a theoretical analysis and laboratory simulation tests.Typical results of the laboratory experiments are presented below.Under heating coal thermo-chemical magnetization is forming.Coal's magnetic parameters varieties from anti-ferromagnetiсto ferromagnetic.Anti-ferromagnetic pyrite and siderite presented into coal mass is transformed into magnetic hematite and magnetite under heating.Therefore,geomagnetic is expected to be a useful geophysical tool to for evaluation of combustion volume and its migration for underground coal gasification.
文摘The idea of the transformation of coal in underground into synthetic gas so-called syngas is interested in world in many centuries. Underground Coal Gasification （UCG） is an in-situ technique to recover the fuel or feedstock value of coal that is not economically available through conventional recovery technologies. Today, less than one sixth of the world＇s coal is economically accessible. Today, similarly to all other countries in the world also in Slovakia there is an interest in the revival and perfection of the UCG technology. From the viewpoint of content the research is directed toward to increasing heating capacity of syngas. From the standpoint of the methods used the research can be divided into 2 approaches： experiments in UCG laboratory and mathematical modeling, including simulation studies. Both approaches have helped to discover complicated relationships during UCG and they will be the subject of this paper. The most important factors are methods, the humidity of the coal, heat losses, temperatures in relevant zones, the composition of oxidation agents and the permeability of the coal. The calorific value of syngas was found generally to be 0.55-4.45 MJ.Nm^-3 with a maximum of 25.51 MJ.m^-3 if only air is used as the oxidation agent. Where a mixture of air and oxygen is used, calorific values in the range 0.43-6.38 MJ.m^-3 were generally obtained, with maximum 27.53 MJ·m^-3. Analysis was carried out on these big differences in order to improve UCG.
