混凝─生物接触氧化─煤渣灰吸附工艺治理废乳化液的研究

本文研究利用适当混凝剂对废乳化液破乳絮凝，其出水通过生物接触氧化装置，然后辅以煤渣灰吸附，可使ＣＯＤｃｒ＝１５６６０ｍｇ／Ｌ，油含量１３６００ｍｇ／Ｌ，ｐＨ为１１左右的呈乳白色的废乳化液处理为ＣＯＤｃｒ为８８ｍｇ／Ｌ，含油３．ｌｍｇ／Ｌ，ｐＨ为７．１，清澈透明，无色无嗅的出水，并可回收乳化油，减轻了由于混凝絮渣引起的二次污染。

基质配比对厚朴穴盘苗生长的影响初报

采用穴盘育苗方法,研究了基于煤渣灰为主料的不同基质配比处理对厚朴(Magnolia officinalis Rehd.et Wils.)幼苗生长的影响。结果表明,厚朴育苗过程中,100%煤渣灰基质所育厚朴幼苗各生长因子均低于100%商用基质,人工复合基质以20%的葛渣+80%煤渣灰基质处理效果最好,与对照相比,其所育厚朴苗各生长因子无显著差异,可以替代以泥炭为主的商用育苗基质。

Air-void parameters measurement of fresh concrete and hardened concrete

Air content, spacing factor and specific surface of fresh concrete and hardened concrete with different air contents, slumps and mineral admixtures (fly ash, slag, fly ash + slag, fly ash + slag + silica fume composite) were studied by the air-void analyzer (AVA) method and the microscopical method. The correlations between the test results obtained from different methods were analyzed. The results show that, there is a close correlation of air content and spacing factor between the fresh concrete and the hardened concrete, but the specific surface correlation is weak. The air content of concrete measured by the AVA method is smaller than that of the pressure method and the microscopical method, because AVA device captures only the air voids with the size smaller than 3 mm. Spacing factor of the fresh concrete measured by the AVA method is greater than that of the hardened concrete measured by the microscopical method, while the specific surface is smaller. When the criterion of 4%-7% air content measured by the pressure method and microscopical method is acceptable for concrete freezing-thawing (F-T) durability in cold weather, the air content measured by the AVA method should be 2.4%-4.6%. For the concrete F-T durability, when the criterion of the spacing factor measured by the microscopical method is 300 μm, the spacing factor measured by the AVA method should be 360 μm.

Effect of activator on rheological properties of alkali-activated slag-fly ash pastes

The time-dependent rheological behaviors of alkali-activated cement(AAC)are expected to be precisely controlled,in order to meet the requirements of modern engineering practices.In this paper,the effects of activator,including the Na_(2)O concentration and SiO_(2)/Na_(2)O(S/N)molar ratio,on the rheological behavior of alkali-activated slag fly ash pastes were investigated.The small amplitude oscillatory shear(SAOS)and shear test were used to evaluate the structural build-up and flowability of pastes.Besides,zeta potential measurement,calorimetric test and thermogravimetric analysis(TGA)were carried out to reveal the physico-chemical mechanisms behind the rheological evolution of fresh pastes.It was found that high Na_(2)O concentration and low S/N molar ratio improved the flowability and structural build-up rate of paste.Moreover,the structural build-up of alkali-activated slag-fly ash pastes consists of two stages,which is controlled by the dissolution of solid reactants and formation of C-(A)-S-H gels,respectively.

Durability of Seawater Mixed Concrete with Different Replacement Ratio of BFS （Blast Furnace Slag） and FA （Fly Ash）

Using seawater in concrete can be considered as one of the sustainable approaches in construction industry not only to save the freshwater resource but also to promote the use of abandoned seawater resource, especially in the construction at the uninhabited area close to the sea where the procurement of fresh water is difficult. In this study, durability against chloride attack of seawater mixed concrete with different replacement ratio of BFS （blast furnace slag） and FA （fly ash） is discussed and the life time until the occurrence of corrosion crack is evaluated. The results show that： （1） Chloride penetration rate of seawater mixed specimens with BFS and FA is lower than that of freshwater mixed OPC （ordinary Portland cement） specimens; （2） Oxygen permeability of seawater mixed specimens with BFS and FA is almost the same or lower than that of freshwater mixed OPC specimens; （3） Total life time （corrosion incubation period and propagation period） of seawater mixed specimens with BFS and FA is almost the same or only slightly shorter than that of freshwater mixed OPC specimens. From the results, it was confirmed that the usage of seawater in concrete mixing is feasible in concrete with the appropriate BFS and FA replacement ratio.

Slagging characteristics of molten coal ash on silicon-aluminum combustion liners of boiler

In order to study the slagging characteristics of boiler combustion liners during pulverized coal stream combustion, the slag samples on the surface of combustion liner were investigated by X-ray diffractometry, scan electron microscopy and energy dispersive X-ray analysis, and the transformation characteristics of the compositions and crystal phases were studied. The results show that the size of slag granules decreases as the slagging temperature increases; the crystallinity of coal ash I reduces to about 48.6% when the temperature is increased up to 1 350 ℃, and that of the coal ash II reduces to about 65% when the temperature is increased up to 1 500 ℃; the encroachment of molten coal ash to the combustion liner is strengthened. At the same time, the diffusion and the segregation of the compositions in combustion liners have selectivity, which is in favor of enhancing the content of crystal phases, weakening the conglutination among molten slag compositions and combustion liner, and avoiding yielding big clinkers. But the diffusion of the compositions in combustion liners increases the porosity and decreases the mechanical intensity of combustion liner, and makes the slag encroachment to the liner become more serious.

Effects of Characteristics of Fly Ash on the Properties of Geopolymer

The properties of two types of fly ash geopolymers made from class F fly ashes produced in wet bottom and dry bottom boilers were investigated in the present study. The source material used in the geopolymer concrete was activated with sodium hydroxide and sodium silicate solution. The results revealed that the geopolymer produced with wet bottom boiler fly ash(CZ-FA)hardened quickly, and had higher early-age strength and lower shrinkage than the geopolymer produced with dry bottom boiler fly ash(SX-FA). The compressive strength of the two geopolymers made from CZ-FA and SX-FA was 45 MPa and 15 MPa respectively when cured at 60 ℃ and delayed for 14 d. However, after 90 days' delay, the compressive strength of both the samples is almost the same, up to 80 MPa. Nearly 20% volume shrinkage of the samples made from SX-FA was much higher than that made from CZ-FA, which was almost zero. XRD, SEM/EDS and FT-IR were used to analyze the main reason of the differences.

Ash-and-Slag Wastes of Energy Sector as Raw Material for Production of Rare-Earth Metals and Alumina

The results to develop a complex technology of co-extraction of germanium and gallium from the ash-and-slag wastes of coal combustion in Ukraine were presented. Based on the study of phase changes occurring in initial raw materials as a result of its processing, it was proposed to carry out a preliminary enrichment of the raw materials in order to produce secondary sublimates. Their further processing involves a combination of leaching soluble material with distillation of germanium in the form of tetrachloride. The resulting acidic solutions are trended to the gallium extraction. Optimum conditions of carrying out of processes are recommended.The chemical and phase composition of the resulting dump products and solutions have been defined. On the basis of it ways of their processing for the purpose of reception of alumina and building materials are recommended.

Attenuation of Metal Bioavailability in Acidic Multi-Metal Contaminated Soil Treated with Fly Ash and Steel Slag

A pot experiment was conducted with multi-metal （Pb, Cd, Cu, and Zn） contaminated acidic soil to investigate changes in available metal burden resulting from the application of industrial wastes （fly ash and steel slag）. The efficiency of amendments- induced metal stabilization was evaluated by diffusive gradients in thin films （DGT）, sequential extraction, and plant uptake. The stability of remediation was assessed by an acidification test and by chemical equilibrium modeling. Addition of fly ash （20 g kg-1） and steel slag （3 g kg-1） resulted in similar increase in soil pH. Both amendments significantly decreased the concentrations of metals measured with DGT （CDGT） and the metal uptake by Oryza sativa L. Significant correlations were found between CDGT and the concentration of a combination of metal fractions （exchangeable, bound to carbonates, and bound to Fe/Mn oxides）, unraveling the labile species that participate in the flux of metal resupply. The capability of metal resupply, as reflected by the R （ratio of CDGT to pore water metal concentration） values, significantly decreased in the amended soils. The CDGT correlated well with the plant uptake, suggesting that DGT is a good indicator for bioavailability. Acidification raised the extractable metal concentration in amended soil but the concentration did not return to the pre-amendment level. Equilibrium modeling indicated that the soil amendments induced the precipitation of several Fe, A1 and Ca minerals, which may play a positive role in metal stabilization. Chemical stabilization with alkaline amendments could be an effective and stable soil remediation strategy for attenuating metal bioavailability and reducing plant metal uptake.

Research on the slagging characteristics of blended coals in a pilot-scale furnace

This paper applies digital image techniques to observe the slagging characteristics of blended coals in a pilot-scale furnace. Collected deposit samples were analyzed by scanning electron microscopy linked with energy-dispersive X-ray analysis （SEM-EDX）, X-ray diffraction （XRD）, and X-ray Fluorescence （XRF） to acquire the microstructure, chemical composition, and mineralogy. The deposit thickness of three blends was analyzed between their parent coal A （Datong） and coal B （Shan）, and we noted that the time to reach a stable stage decreased with the ratio of coal B. The addition of coal A into coal B could remarkably restrained the growth and thickness of ash deposits. The results of XRD analysis indicated the initial layer was predominantly comprised of the crystalline minerals quartz, anorthite, or albite except for coal B. All of the blends and coals contained quartz and Ca- to Al-silicates （Ca0.68Na0.32）（All.68Si0.32）Si2O8 in the slag layer where iron-bearing minerals （e.g., ilvaite） were altered into an amorphous phase. The result of SEM-EDX suggested that there was an elemental disparity between the coal ash and deposit.

Performance evaluation of fly ash-copper slag-based geopolymer bricks

This study investigates the production and evaluation of geopolymer bricks made from a blend of fly ash,copper slag,soda ash activator,and sand as fillers.Locally abundant industrial and mining waste materials were selected as the primary components.The bricks were synthesized using two binders:60%fly ash with 40%copper slag,or 70%fly ash with 30%copper slag.Both were milled with the activator at a 0.2 soda ash-to-precursor ratio.Fine sand was added to the mixes at 1:2 and 1:3 binders-to-sand ratios.The bricks’physical,mechanical,and durability properties were examined through compressive strength,modulus of rupture,density,water absorption,drying shrinkage,and efflorescence test,and their performance was compared to established industry standards.The experimental findings indicate that bricks made with 60%fly ash,40%copper slag,and a 1:2 binder-to-sand ratio exhibited optimal compressive strength(9.64 MPa)and water absorption(7.5%)at 28 days of curing age.Conversely,there was only a marginal increase of up to 4.7%in the strength of the formulation with 70%fly ash and 30%copper slag,attaining a compressive strength of 4.9 MPa between the curing ages.Furthermore,the results indicated a positive correlation between the density and compressive strength of the geopolymer bricks at similar curing ages.The bricks’density showed minimal variation with curing age and the highest modulus of rupture value observed was 2.5 MPa.The optimal bricks also exhibited relatively low linear shrinkage,good resistance to efflorescence,and met the relevant industry standards.