A novel type of metal oxide/activated carbon catalyst was prepared by sol-gel method for the hydrolysis of carbonyl sulfide （COS）. The influences of the calcination temperature, additive content （2.5%-10.0% Fe2O3, ...A novel type of metal oxide/activated carbon catalyst was prepared by sol-gel method for the hydrolysis of carbonyl sulfide （COS）. The influences of the calcination temperature, additive content （2.5%-10.0% Fe2O3, mass fraction） and the basic density of the activation process were thoroughly investigated. The surface of catalysts was characterized by Boehm titration. The products were characterized by scanning electron microscopy （SEM）, X-ray diffractometry （XRD） and X-ray photoelectron spectroscopy （XPS）. The results show that catalysts with 2.5%-5.0% Fe2O3 after calcining at 500 ℃ have superior activity. The conversion rate of COS increases with increasing the relative density of basic capacity loaded onto activated carbon（AC）, and the activity follows the order： KOH〉Na2CO3 〉NaHCO3. Boehm titration data clearly show that the total acidity increases （from 0.06 to 0.48 mmol/g） and the basic groups decrease （from 0.78 to 0.56 mmol/g） after COS hydrolysis and H2S adsorption. The XPS results show that the product of HzS may be absorbed by the interaction with metal compounds and 02 to form sulfate （171.28 eV） and element sulfur （164.44 eV）, which lead to catalysts poisoning.展开更多
This study was performed to investigate the spectral characteristics of micro-seismic signals observed during the rupture of coal. Coal rupture micro-seismic observations were obtained on a test system that included a...This study was performed to investigate the spectral characteristics of micro-seismic signals observed during the rupture of coal. Coal rupture micro-seismic observations were obtained on a test system that included an electro-hydraulic servo pressure tester controlled by a YAW microcomputer, a micro-seismic sensor, a loading system, and a signal collection system. The results show that the micro-seismic signal increases with increasing compressive stress at the beginning of coal rupture. The signal remains stable for a period at this stage. A large number of micro-seismic signals appear immediately before the main rupture event. The frequency of micro-seismic events reaches a maximum immediately after the coal ruptures. Micro-seismic signals were decomposed into several Intrinsic Mode Functions (IMF's) by the empirical mode decomposition (EMD) method using a Hilbert-Huang transform (HHT). The main fre- quency band of the micro-seismic signals was found to range from 10 to 100 Hz in the Hilbert energy spectrum and from marginal spectrum calculations. The advantage of applying an HHT is that this can extract the main features of the signal. This fact was confirmed by an HHT analysis of the coal micro-seis- mic signals that shows the technique is useful in the field of coal rupture.展开更多
基金Project(50908110) supported by the National Natural Science Foundation of ChinaProject(2008AA062602) supported by the National High-Tech Research and Development Program of China+1 种基金Project(20090451431) supported by China Postdoctoral Science FoundationProject(2007PY01-10) supported by Young and Middle-aged Academic and Technical Back-up Personnel Program of Yunnan Province,China
文摘A novel type of metal oxide/activated carbon catalyst was prepared by sol-gel method for the hydrolysis of carbonyl sulfide （COS）. The influences of the calcination temperature, additive content （2.5%-10.0% Fe2O3, mass fraction） and the basic density of the activation process were thoroughly investigated. The surface of catalysts was characterized by Boehm titration. The products were characterized by scanning electron microscopy （SEM）, X-ray diffractometry （XRD） and X-ray photoelectron spectroscopy （XPS）. The results show that catalysts with 2.5%-5.0% Fe2O3 after calcining at 500 ℃ have superior activity. The conversion rate of COS increases with increasing the relative density of basic capacity loaded onto activated carbon（AC）, and the activity follows the order： KOH〉Na2CO3 〉NaHCO3. Boehm titration data clearly show that the total acidity increases （from 0.06 to 0.48 mmol/g） and the basic groups decrease （from 0.78 to 0.56 mmol/g） after COS hydrolysis and H2S adsorption. The XPS results show that the product of HzS may be absorbed by the interaction with metal compounds and 02 to form sulfate （171.28 eV） and element sulfur （164.44 eV）, which lead to catalysts poisoning.
基金support for this work provided by the National Science and Technology Planning Project (No. 2009BAK54B03)the National Natural Science Foundation of China (No. 50834005)
文摘This study was performed to investigate the spectral characteristics of micro-seismic signals observed during the rupture of coal. Coal rupture micro-seismic observations were obtained on a test system that included an electro-hydraulic servo pressure tester controlled by a YAW microcomputer, a micro-seismic sensor, a loading system, and a signal collection system. The results show that the micro-seismic signal increases with increasing compressive stress at the beginning of coal rupture. The signal remains stable for a period at this stage. A large number of micro-seismic signals appear immediately before the main rupture event. The frequency of micro-seismic events reaches a maximum immediately after the coal ruptures. Micro-seismic signals were decomposed into several Intrinsic Mode Functions (IMF's) by the empirical mode decomposition (EMD) method using a Hilbert-Huang transform (HHT). The main fre- quency band of the micro-seismic signals was found to range from 10 to 100 Hz in the Hilbert energy spectrum and from marginal spectrum calculations. The advantage of applying an HHT is that this can extract the main features of the signal. This fact was confirmed by an HHT analysis of the coal micro-seis- mic signals that shows the technique is useful in the field of coal rupture.
