西北某地煤田煤的煤岩和微量元素特征对比

我国目前的地质学研究理论主要是以华北地区的煤田资源为重点研究对象,未能足够重视对于西北地区的煤炭资源的研究。为了能够更好地开发与利用西北地区丰富优质的煤炭资源,为了丰富我国地质学理论,必须重视西北地区煤炭资源的研究。为此,文章重点选取西北地区的两个矿区,详细阐述西北地区煤田煤的煤岩和微量元素特征对比,以期更好地开发与利用西北地区的煤炭资源。

滕县煤田下组煤地应力特征与灰岩夹层顶板稳定性控制研究

滕县煤田锦丘煤矿16煤顶板灰岩存在弱面夹层,其厚度、破坏形态及下位坚硬岩层物理力学性质对巷道顶板整体的破裂形态产生影响,且地应力场不明,周边部分矿井存在支护设计中未考虑该因素引发的冒顶现象。本研究针对锦丘煤矿16煤162-206下轨道巷顶板破碎、两帮煤体大变形问题,通过地应力测量、顶底板力学测试、顶板钻孔窥视等综合研究方法,探究了滕县煤田16煤的地应力特征、灰层顶板力学特征及弱面位置,改进支护方案。通过数值模拟分析3种改进支护方案控制围岩的变形特征,优选最佳支护方案。通过工程监测评价最优支护方案的有效性。结果表明:16煤顶板灰岩夹层位于1~2 m深度内,特别是1.1~1.3 m和1.8~2.0 m范围;16煤最大主应力位于近水平方向,顶板受影响较两帮大,易发生较严重的剪切破坏,且顶板位移较两帮大。最大主应力以南东向为主,数值为16~20 MPa;综合控制效果、劳动强度和支护成本,选择方案2作为下轨道巷最优支护方案;工程中安装测点16~20天后,巷道围岩变形逐渐趋于稳定,顶底板和两帮的最大变形量为38和67 mm,验证了改进支护方案的有效性。

不同变质程度煤中镜质组的元素分布特征:基于Raman和原位微区XRF分析

为明确煤中元素与有机质之间的关系,本文选择山西太原西山煤田6个矿区石炭系—二叠系太原组8号煤层煤样(镜质体最大反射率为1.26%~2.03%)为研究对象,挑选其中的镜煤条带,利用激光共聚焦拉曼光谱仪(Raman)选出镜质组,结合微区X射线荧光光谱仪(μ-XRF)对镜质组中元素含量和分布特征进行分析,试图探讨不同变质程度煤中镜质组的拉曼光谱和元素的耦合关系。研究发现,镜质组中仍然存在着大量的纳米级矿物,在实验操作过程中即使Raman光谱的结果限定了有机组分,但是由于束斑大小的差异,μ-XRF测试时不可避免的受到了煤中纳米级矿物的影响;Al、Si、K、Ti、V、Fe、Co、Ca主要赋存于镜质组中的纳米级矿物中,Ni、Zn、Ga、Ge、Br、S则主要以有机结合态的形式存在。

东北地区地质构造对第三系煤田聚煤的控制作用初探

构造对第三纪含煤、含油盆地的生成、发展起到决定性作用。同沉积断裂及同沉积拗陷的形成不仅控制着第三纪盆地的展布,对聚煤古地理环境及聚煤条带展布也具有一定的控制作用。

国内外褐煤热解技术的应用及发展

褐煤资源作为煤炭资源中的一个庞大分支种类煤炭种类,其在我国现有的存储数量为一千多亿吨,为我国总体煤炭存储数量的百分之二十左右。而褐煤资源的开发、加工应用技术也日渐受到国内外有关行业、部门和企业的关注与重视。下文中,笔者将结合个人工作经验,从国内外褐煤热解技术的概论、褐煤热解技术的研发、褐煤热解技术的应用几个方面,介绍国内外典型的几种褐煤热解技术,并对其应用现状,及其发展趋势进行分析。

地震勘查技术在大井矿区找煤工作中的应用

利用合成地震记录标定反射波地质属性,采用多元多项式拟合速度进行空间归位,控制煤层底板的起伏形态。采用钻孔约束波动方程反演波阻抗,结合钻探资料及合成记录,分析煤层反射波特点和类型以及与波阻抗剖面和煤层宏观结构的关系,解释了煤层厚度及煤层结构。初步控制了煤层起伏形态和煤层宏观结构及煤层厚度变化规律。

洞口井田含煤岩系沉积特征及其沉积环境浅析

含煤岩系也称之为含煤建造或者含煤沉积,往往受到地理环境影响,加上煤田地质构造情况直接影响开采安全,分析煤田含煤岩系沉积特征及沉积环境具有重要意义。本文以贵州洞口井田为例,重点分析煤田含煤岩系沉积特征及其沉积环境。

Effect of magma intrusion on the occurrence of coal gas in the Wolonghu coalfield

Chemical analysis, methane isothermal adsorption studies, and mercury porosimetry were performed on ten samples taken from the magma intrusion boundary in the Wolonghu coalfield. The physico-chemical properties of coals from the magma intrusion region are compared to those from the normal regions. The results show that the volatile content (Vad), the limiting adsorption constant (a), and the initial methane diffusion rate of samples from the magma intrusion region are generally smaller than those values from samples from the normal region. The number three coal sample from the magma intrusion region has a large vitrinite reflectance, well developed macropores, a small surface area, and weak methane adsorp- tion capacity. The number ten coal sample from the normal region has a small vitrinite reflectance, well developed micropores, a large surface area, and a strong methane adsorption capacity. The maceral of the coal samples from the magma intrusion region and the normal region are similar. The coal in the area near the magma intrusion boundary is rich in methane and is an area where coal and gas outbursts often occur.

HIGH-RESOLUTION SEQUENCE STRATIGRAPHIC ANALYSIS OF THE PERMIAN IN THE WESTERN SHANDONG AND HUAINAN-HUAIBEI COALFIELDS

The sedimentary characteristics and their combination succession of the Permian in the Shandong nd Huainan-Huaibei coalfields are analyzed. The mid-and short-term stratigraphic base-level cycles are identified. High-resolution sequences are divided based on the above results. The study shows that the stratigraphic base-level cyclic method is an efficient way in the determination of the high-resolution sequences, especially in the classification of tbe terrestrial and transitional depositional succession.

Deformed coal types and pore characteristics in Hancheng coalmines in Eastern Weibei coalfields

Based on SEM observance,the methods of low-temperature nitrogen and isothermal adsorption were used to test and analyze the coal samples of Hancheng,and pore structure characteristics of tectonic coals were discussed.The results indicate that in the same coal rank,stratification and crack are well developed in cataclastic coal,which is mostly filled by mineral substance in the geohydrologic element abundance,results in pore connectivity variation.Granulated and mylonitic coal being of these characteristics,as develop microstructures and exogenous fractures as well as large quantity of pores resulted from gas generation and strong impermeability,stimulate the recovery of seepage coal,improve coal connectivity and enhance reservoir permeability.Absorption pore(micro-pore) is dominant in coal pore for different coal body structure,the percentage of which pore aperture is from 1 to 100 nm is 71.44% to 88.15%,including large of micro-pore with the 74.56%-94.70%;with the deformation becoming more intense in the same coal rank,mesopore enlarge further,open-end pores become thin-neck-bottle-shaped pores step by step,specific surface area of micro-pore for cataclastic coal is 0.0027 m 2 /g,while mylonitic coal increases to 7.479 m 2 /g,micro-pore gradually play a dominant role in effecting pore structural parameters.

Coal petrology and facies of No.6 coal of the Haerwusu Mine, Jungar Coalfield, Inner Mongolia

This paper discussed the petrological characteristics and coal facies of No.6 coal seam from the Haerwusu Mine, Jungar Coalfield, Inner Mongolia by using of coal petrology and geochemistry. No.6 coal facies can be divided into 3 types, arid forest peat swamp （including two subfacies） and reed peat swamp, respectively. From bottom to top, the development of peat swamps present wavy changes, and three coal facies types appear alternately, with obvious thyme. According to the parameters, 11 secondary sequences were identified of the peat swamps of No.6 coal seam. The results indicate that the mire formed in brackish water-fresh water weak regression environment, changed in excess oxygen and poor oxygen, and reflected the characteristics of transition phase.

Explanation for peat-forming environments of coal seam 2 and 9^(-2)based on the maceral composition and aromatic compounds in the Xingtai coalfield,China

Maceral composition and aromatic compounds were determined on columnsamples to study the peat-forming environments of Permian coal seam 2 and Carboniferouscoal seam 9^(-2) from the Xingtai coalfield,China.The macerals were dominated by inertinitein seam 2 and by vitrinite in seam 9^(-2).Three maceral groups were selected as indicatorsof peat-forming environments.Two triangle diagrams were drawn based on the indicatorsto explicate the peat-forming environments of permian seam 2 and Carboniferousseam 9^(-2).The results indicate that the peat of carboniferous seam 9^(-2) formed dominantlyin wet swamps,whereas the peat of Permian seam 2 formed dominantly in dry swampsand open moor environments.

THE THRUST AND NAPPE TECTONIC ZONE ALONG THE SOUTHERN MARGIN OF THE COAL-FORMING REGION OF NORTH CHINA

A thrust and nappe tectonic zone with imbricate branch thrusts is developed along the southern margin of the coal-forming region of North China. This tectonic zone is tightly related to the Qinling-Dabie collision orogen in genesis and belongs to the frontal zone of a huge thrust system developed during Yanshanian episode at the northern foot of the orogen. It is pointed out that thrusting had distorted the original depositional margin of the coal-forming region and some new coal-bearing blocks would be found out in the frontal sheets and under the undulate sole thrust.

DETECTION OF IGNEOUS BODIES IN HUAIBEI COAL MINESBY HIGH RESOLUTION MAGNETIC SURVEY

The present paper investigates the application of high resolution magnetic survey to detecting igneous bodies. The slight difference in magnetism between igneous bodies and their surrounding rocks is measured first and then the magnetic survey data are processed to determine whether there exist igneous bodies by analog among several measuring lines, and finally the modified Marquart inversion was used to determine the occurrence and distribution of the igneous bodies.

Forecasting the underground waters regime in the pitching aquifers in Huainan mining area

Huainan area is an important coal base of the east of China. In the early part of the 1980s, the study of the underground waters dynamic state in the area was gradually paid close attention to. This paper introduces the observation system of the groundwater dynamic state in the multilayered pitching aquifer, and expounds the hydrogeologic feature and the waterpower relations among aquifers. Furthermore, based on the analysis of the relations of the groundwater dynamic state to surface water, meteoric water and mining shaft outflow rate, this paper establishes main water filled aquifers of mining shaft (C 3-1 ,C 3-2 ,C 3-3 and O 2).In the light of the actual situation of the greatly changing aquifer occurrence and steep dip angle, the “two layer space curved surface seepage model" and the calculating step are all suggested. Since 1991,the groundwater dynamic state of the next year has been predicted (numerical simulation) every year. Contracting with the measured data, we gain a relatively ideal effect.

Analysis on geological structures influencing gas occurrence at Qidong coalmine

The occurrence state of methane is mostly controlled by coalfield geologicalstructures.The coal-bearing strata at Qidong coalmine experienced many tectonic cyclessince their formation.The gas content made by the complicated structural geologic systemat the coalfield is very different, which is obviously higher on the north side of the Weimiaofracture belt than that on the south side and near itself.This thesis discussed the gas occurrenceregularity based on the geometric characteristics of the geological structure andits regional tectonic evolution.This study can provide a foundation for coalfield exploitationand deal with coal and gas outburst.

Comparison of coalbed gas generation between Huaibei-Huainan coalfields and Qinshui coal basin based on the tectono-thermal modeling

The geothermal history and the tectonic subsidence history of the Huaibei-Huainan coalfields were reconstructed by using the vitrinite reflectance data, and their correlative restriction on coalbed gas generation of Huaibei-Huainan coalfields and Qinshui coal basin was discussed. The burial, thermal, and maturity histories of are similar between Huaibei coalfield and Huainan coalfield, obviously different from those of Qinshui coal basin. Based on the tectono-thermal evolution characters of Huaibei-Huainan coalfields and Qinshui basin, the process of coalbed gas generation can be divided into three stages： （1） Dur- ing Early Mesozoic, both in Huaibei-Huainan and Qinshui, the buried depth of Permian coal seams increased rapidly, which resulted in strong metamorphism and high burial temperature of coal seams. At this stage, the coal rank was mainly fat coal, and locally reached coking coal. These created an environment favoring the generation of thermogenic gas. （2） From Late Ju- rassic to Cretaceous, in the areas of Huaibei-Hualnan, the strata suffered from erosion and the crust became thinning, and the Permian coal-bearing strata were uplifted to surface. At this stage, the thermogenic gas mostly escaped. Conversely, in Qinshui basin, the cover strata of coal seams kept intact during this stage, and the thermogenic gas were mostly preserved. Furthermore, with the interaction of magmatism, the burial temperature of coal seams reached higher peak value, and it was suitable for the secondary generation of thermogenic gas. （3） From Paleogene onward, in area of Huainan-Huaibei, the maturity of coal and burial temperature were propitious to the generation of secondary biogenic gases. However, in Qinshui basin, the maturity of coal went against genesis of second biogenic gas or thermogenic gas. By comparison, Huaibei-Huainan coalfields are dominated by thermogenic gas with a significant biogenic gas and hydrodynamic overprint, whereas Qinshui basin is dominated mainly by thermogenic gas.

Physical characteristics of high-rank coal reservoirs in different coal-body structures and the mechanism of coalbed methane production

The physical characteristics of coal reservoirs are important for evaluating the potential for gas desorption, diffusion, and seepage during coalbed methane （CBM） production, and influence the performance of CBM wells. Based on data from mercury injection experiments, low-temperature liquid nitrogen adsorption, isothermal adsorption, initial velocity tests of methane diffusion, and gas natural desorption data from a CBM field, herein the physical characteristics of reservoirs of high-rank coals with different coal-body structures are described, including porosity, adsorption/desorption, diffusion, and seepage. Geometric models are constructed for these reservoirs. The modes of diffusion are discussed and a comprehensive diffusion-seepage model is constructed. The following conclusions were obtained. First, the pore distribution of tectonically deformed coal is different from that of normal coal. Compared to normal coal, all types of pore, including micropores （〈10 nm）, transitional pores （10-100 nm）, mesopores （100-1000 nm）, and macropores （〉1000 nm）, are more abundant in tectonically deformed coal, especially mesopores and macropores. The increase in pore abundance is greater with increasing tectonic deformation of coal; in addition, the pore connectivity is altered. These are the key factors causing differences in other reservoir physical characteristics, such as adsorption/desorption and diffusion in coals with different coal-body structures. Second, normal and cataclastic coals mainly contain micropores. The lack of macropores and its bad connectivity limit gas desorption and diffusion during the early stage of CBM production. However, the good connectivity of micropores is favorable for gas desorption and diffusion in later gas production stage. Thus, because of the slow decline in the rate of gas desorption, long-term gas production can easily be obtained from these reservoirs. Third, under natural conditions the adsorption/desorption properties of granulated and mylonitized coal are good, and the diffusion ability is also enhanced. However, for in situ reservoir conditions, the high dependence of reservoir permeability on stress results in a weak seepage of gas; thus, desorption and diffusion is limited. Fourth, during gas production, the pore range in which transitional diffusion takes place always increases, but that for Fick diffusion decreases. This is a reason for the reduction in diffusion capacity, in which micropores and transitional pores are the primary factors limiting gas diffusion. Finally, the proposed comprehensive model of CBM production under in situ reservoir conditions elucidates the key factors limiting gas production, which is helpful for selection of reservoir stimulation methods.

Controls on migration and aggregation for tectonically sensitive elements in tectonically deformed coal:An example from the Haizi mine, Huaibei coalfield, China

Tectonically deformed coal(TDC)develops because of the superimposed deformation and metamorphism of a coal seam by tectonic movements.The migration and accumulation of trace elements in TDC is largely in response to stress-strain conditions.To develop a law governing the migration and aggregation of sensitive elements and investigate the geological controls on TDC,coal samples from different deformation sequences were collected from the Haizi mine,in the Huaibei coalfield in Anhui Province,China,and the concentrations of 49 elements were determined by XRF and ICP-MS,and then microscopically analyzed.The results show that the distribution and morphology of minerals in coal is related to the deformation degree of TDC.The evolutionary process runs from orderly distribution of minerals in a weak brittle deformed coal to disordered distributions in ductile deformed coal.According to the elemental distribution characteristics in TDC,four types of element migration can be identified:stable,aggregate,declining,and undulate types,which are closely related to the deformation degree of TDC.Present data indicate that the overall distribution of rare earth elements(REE)does not change with metamorphism and deformation,but it shows obvious dynamic differentiation phenomena along with the deformation of TDC.Tectonic action after coal-formation,brittle or ductile deformation,and the metamorphic mechanism and its accompanying dynamic thermal effects are the main factors that influence the redistribution of elements in TDC.We conclude that tectonic movements provide the motivation and basis for the redistribution of elements and the paths and modes of element migration are controlled by brittle and ductile deformation metamorphic processes.The dynamic thermal effect has the most significant effect on coal metamorphism and tectonic-stress-accelerated element migration and accumulation.These factors then induce the tectonic-dynamic differentiation phenomenon of element migration.