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1-丁基-3-甲基咪唑硫酸氢盐与双氧水用于煤脱硫试验研究 被引量:4
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作者 徐永亮 荆国松 +1 位作者 王兰云 孙燕 《河南理工大学学报(自然科学版)》 CAS 北大核心 2018年第6期22-29,共8页
工业燃煤产生了大量环境污染物,其中的SO_2气体对大气环境污染尤为严重。为减少传统脱硫法带来的安全隐患及环境污染问题,并提高煤中有机硫脱除率,采用1-丁基-3-甲基咪唑硫酸氢盐([Bmim][HSO4])离子液体(IL)结合30%的双氧水(H_2O_2)的方... 工业燃煤产生了大量环境污染物,其中的SO_2气体对大气环境污染尤为严重。为减少传统脱硫法带来的安全隐患及环境污染问题,并提高煤中有机硫脱除率,采用1-丁基-3-甲基咪唑硫酸氢盐([Bmim][HSO4])离子液体(IL)结合30%的双氧水(H_2O_2)的方法,用于脱除煤中含硫结构,降低煤中硫含量。通过硫分测试、红外光谱和X射线试验,对煤样处理前后的硫含量、煤中官能团及微观结构进行了测试。结果表明,在H_2O_2-[Bmim][HSO_4]作用下,试验煤样全硫脱除率达47.44%,高于H_2O_2作用下的全硫脱除率38.61%。红外光谱分析结果显示IL-H_2O_2处理的煤样中—SH、—S—S—等官能团下降比例高于H_2O_2处理的煤样,说明IL的加入有利于增强有机硫的脱除效果。XPS试验分析结果显示,经IL-H_2O_2处理后,煤样中硫醇(醚)、噻吩硫和(亚)砜硫含量均减少。但由于部分硫醇(醚)和部分噻吩硫被氧化为(亚)砜结构,导致硫醇(醚)和噻吩硫在有机硫中的相对含量明显减少,而(亚)砜硫相对比例有所增加。这主要是由于[Bmim][HSO_4]有效破坏了煤的氢键网络和小分子结构,使H_2O_2能更有效地氧化煤中有机硫,从而提高有机硫脱除率和全硫脱除率。 展开更多
关键词 煤脱硫方法 离子液体 双氧水
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Research on Factors Affecting Flotation and Desulfurization of Coal by Electrochemical Method 被引量:4
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作者 朱英 吕小莉 +1 位作者 朱红 赵炜 《Journal of China University of Mining and Technology》 2001年第2期138-141,共4页
Influence of factors such as potential of electrolyte, electrolyzing time, concentration of electrolyte, and pH value on flotation and desulfurization of coal was researched. The result shows that the electrochemical ... Influence of factors such as potential of electrolyte, electrolyzing time, concentration of electrolyte, and pH value on flotation and desulfurization of coal was researched. The result shows that the electrochemical reduction can enhance the desulfurization effect and increase the yield of clean coal under certain conditions. So it is an effective method. 展开更多
关键词 electrochemical reduction DESULFURIZATION high sulfur coal flotation
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AN ADVANCED COAL DESULFURIZATION PROCESS──SELECTIVE FLOCCULATION
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作者 蔡璋 刘红缨 +1 位作者 吴军 陈彩茶 《Journal of Coal Science & Engineering(China)》 1997年第2期82-85,共4页
Selective flocculation is an idea separation method to separate ultrafine pyrite from coal. A number of selective flocculation separation tests under different conditions have been done and the results are very encour... Selective flocculation is an idea separation method to separate ultrafine pyrite from coal. A number of selective flocculation separation tests under different conditions have been done and the results are very encouraging. The results also show that desulfurization and deashing can be finished simultaneously in selective fIocculation process. It is an advanced coal desulfurization process. 展开更多
关键词 COAL desulfurization process selective flocculation
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EXPERIMENTAL STUDY OF DESULFURIZATION OF ZHONG LIANG SHAN HIGH SULFUR COAL BY FLOTATION
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作者 姜志伟 黄波 曹炅 《Journal of China University of Mining and Technology》 1994年第2期39-46,共8页
Emission of large amount of SO2 from combustion of liigh sulfur ctal causes serious envitonmcntai pollution. Pre-combustion desunrization of high sulfur coal has become a necessity.Thts paper reports test results of f... Emission of large amount of SO2 from combustion of liigh sulfur ctal causes serious envitonmcntai pollution. Pre-combustion desunrization of high sulfur coal has become a necessity.Thts paper reports test results of fine coal dcaulfurization with different flotation technology and theeffect of pyrite depressant. Test work showed that when the coal sample from Zhong Liang Shanwas processed with a Free Jet Flotation Column its pyritic sulfur content was reduced from 3.08%to 0. 84%, with 72. 22% recovery ofcomhustiblc matter in clean coal. The coneept of Desulfuriza tion Efficiency Index E for comprehensive evaluation of desumirhation process is proposed, whichis deffeed as the product of the ratio of sulfur content reduction of clean ctal and the recovery ofcomhustihle matters. 展开更多
关键词 clean coal technology FLOTATION DESULFURIZATION desulfurization efficiency index
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