The thermal decomposition kinetics of dehydroabietic acid in static state air was investigated by TG/DTA/DSC techniques with various heating rates of 5,10,15 and 20 K·min-1.TG/DTA curves showed that decomposition...The thermal decomposition kinetics of dehydroabietic acid in static state air was investigated by TG/DTA/DSC techniques with various heating rates of 5,10,15 and 20 K·min-1.TG/DTA curves showed that decomposition proceeded through a well-defined step in air.The melting point,molar enthalpy and entropy of fusion of dehydroabietic acid were determined as 445.05 K,19.74 kJ·mol-1 and 44.35 J·mol-1·K-1,by differential scanning calorimetry(DSC).The non-isothermal kinetics parameters were analyzed by means of the Kissinger and Flynn-Wall-Ozawa methods,and the thermal decomposition mechanism of dehydroabietic acid was also studied with the Satava-Sestak method.The results showed that the thermal decomposition mechanism of dehydroabietic acid in air was controlled by interface reaction R3,and the apparent activation energy and pre-exponential factor were 107.89 kJ·mol-1 and 9.33×108 s-1,respectively.展开更多
The micro-cracking behaviors of two high-entropy alloys(HEAs) of the FeMnCoCrNi family prepared by selective laser melting were systematically studied. Residual stresses were also analyzed by X-ray diffraction techniq...The micro-cracking behaviors of two high-entropy alloys(HEAs) of the FeMnCoCrNi family prepared by selective laser melting were systematically studied. Residual stresses were also analyzed by X-ray diffraction technique. Results show that the equiatomic FeMnCoCrNi HEAs with a relatively stable single-phase face-centered cubic(FCC) structure suffered from micro-cracking with residual tensile stress after laser melting. In contrast, the metastable non-equiatomic Fe MnCoCr HEAs with reduced stacking fault energy are free of micro-cracks with residual compressive stress at various volumetric energy densities(VEDs). The displacive transformation from the FCC matrix to the hexagonal close-packed(HCP) phase during cooling prevents the micro-cracking via consuming thermal stress related internal energy. Further, the displacive transformation during tensile deformation contributes to the higher strength and ductility of the metastable dual-phase HEA compared to that of the stable single-phase HEA. These findings provide useful guidance for the design of strong, ductile, and crack-free alloys for additive manufacturing by tuning phase stability.展开更多
Analyzing the service behavior of high dams and establishing early-warning systems for them have become increasingly important in ensuring their long-term service.Current analysis methods used to obtain safety monitor...Analyzing the service behavior of high dams and establishing early-warning systems for them have become increasingly important in ensuring their long-term service.Current analysis methods used to obtain safety monitoring data are suited only to single survey point data.Unreliable or even paradoxical results are inevitably obtained when processing large amounts of monitoring data,thereby causing difficulty in acquiring precise conclusions.Therefore,we have developed a new method based on multi-source information fusion for conducting a comprehensive analysis of prototype monitoring data of high dams.In addition,we propose the use of decision information entropy analysis for building a diagnosis and early-warning system for the long-term service of high dams.Data metrics reduction is achieved using information fusion at the data level.A Bayesian information fusion is then conducted at the decision level to obtain a comprehensive diagnosis.Early-warning outcomes can be released after sorting analysis results from multi-positions in the dam according to importance.A case study indicates that the new method can effectively handle large amounts of monitoring data from numerous survey points.It can likewise obtain precise real-time results and export comprehensive early-warning outcomes from multi-positions of high dams.展开更多
文摘The thermal decomposition kinetics of dehydroabietic acid in static state air was investigated by TG/DTA/DSC techniques with various heating rates of 5,10,15 and 20 K·min-1.TG/DTA curves showed that decomposition proceeded through a well-defined step in air.The melting point,molar enthalpy and entropy of fusion of dehydroabietic acid were determined as 445.05 K,19.74 kJ·mol-1 and 44.35 J·mol-1·K-1,by differential scanning calorimetry(DSC).The non-isothermal kinetics parameters were analyzed by means of the Kissinger and Flynn-Wall-Ozawa methods,and the thermal decomposition mechanism of dehydroabietic acid was also studied with the Satava-Sestak method.The results showed that the thermal decomposition mechanism of dehydroabietic acid in air was controlled by interface reaction R3,and the apparent activation energy and pre-exponential factor were 107.89 kJ·mol-1 and 9.33×108 s-1,respectively.
基金financial support of the National Natural Science Foundation of China (51505166,51971248)the Huxiang Young Talents Project (2018RS3007,2019RS1001)+1 种基金the Innovation-Driven Project of Central South University,China (2020CX023)Science and Technology Project of Hunan Province (2020GK2031)。
文摘The micro-cracking behaviors of two high-entropy alloys(HEAs) of the FeMnCoCrNi family prepared by selective laser melting were systematically studied. Residual stresses were also analyzed by X-ray diffraction technique. Results show that the equiatomic FeMnCoCrNi HEAs with a relatively stable single-phase face-centered cubic(FCC) structure suffered from micro-cracking with residual tensile stress after laser melting. In contrast, the metastable non-equiatomic Fe MnCoCr HEAs with reduced stacking fault energy are free of micro-cracks with residual compressive stress at various volumetric energy densities(VEDs). The displacive transformation from the FCC matrix to the hexagonal close-packed(HCP) phase during cooling prevents the micro-cracking via consuming thermal stress related internal energy. Further, the displacive transformation during tensile deformation contributes to the higher strength and ductility of the metastable dual-phase HEA compared to that of the stable single-phase HEA. These findings provide useful guidance for the design of strong, ductile, and crack-free alloys for additive manufacturing by tuning phase stability.
基金Project supported by the National Natural Science Foundation of China (Nos. 51139001,51179066,51079046,and 50909041)
文摘Analyzing the service behavior of high dams and establishing early-warning systems for them have become increasingly important in ensuring their long-term service.Current analysis methods used to obtain safety monitoring data are suited only to single survey point data.Unreliable or even paradoxical results are inevitably obtained when processing large amounts of monitoring data,thereby causing difficulty in acquiring precise conclusions.Therefore,we have developed a new method based on multi-source information fusion for conducting a comprehensive analysis of prototype monitoring data of high dams.In addition,we propose the use of decision information entropy analysis for building a diagnosis and early-warning system for the long-term service of high dams.Data metrics reduction is achieved using information fusion at the data level.A Bayesian information fusion is then conducted at the decision level to obtain a comprehensive diagnosis.Early-warning outcomes can be released after sorting analysis results from multi-positions in the dam according to importance.A case study indicates that the new method can effectively handle large amounts of monitoring data from numerous survey points.It can likewise obtain precise real-time results and export comprehensive early-warning outcomes from multi-positions of high dams.
