低温熔相法烧结耐磨陶瓷在流化床锅炉中的应用

通过对耐磨骨料、耐磨填料、高温粘结剂及耐磨材料制作工艺的分析研究,从理论上解决了低温熔相法烧结耐磨陶瓷的可行性。采用低温熔相法烧结技术能使捣打方法和预制砖块的方法形成整体性、结晶性,解决了开裂、脱落问题,增强了耐磨性能。介绍了该陶瓷材料的配方研制和工艺试验,及其在流化床锅炉中的应用。

固相共熔法制备YAG:Ce荧光粉的工艺研究

本论文综述了YAG荧光粉的概况,介绍了制备YAG:Ce^(3+)荧光粉的几种方法。本实验采用了固相共熔法制备,固相共熔法比传统制备方法高温固相法有着烧结温度低、反应时间短、工艺简单等优点。

Phase-field crystal simulation of evolution of liquid pools in grain boundary pre-melting regions

Pre-melting is a phenomenon that below the melting point the liquid-like structure appears at the grainboundary while the grain interior remains a crystal structure. The phase-field crystal method was employed to investigate the early evolution of the liquid pools in pre-melting regions, mainly involving four structural transformations: solid-solid state → small droplet → large liquid pool → homogeneous liquid melting. The microscopic morphology and free energy variation with different average atomic densities demonstrate that the average atomic density is sensitive to the morphological characteristics of liquid pools. Both two-dimensional and three-dimensional simulation results show that the amplitude reduction of order parameters can promote the order-disorder transition of grain boundaries, causing pre-melting in the edge dislocation aggregation. The relationship between the average atomic density and the width of the liquid pools is verified from thermodynamics, which provides a prerequisite for the application of high-temperature strain in the later stage to some extent.

邻甲苯酚的生产与应用

介绍了邻甲苯酚的性质、生产方法和应用，重点介绍了苯酚甲醇气相烷基化法生产技术，并对国内邻甲苯酚的开发提出了建议。

Effect of compression ratio on microstructure evolution of Mg−10%Al−1%Zn−1%Si alloy prepared by SIMA process

A new Mg−10%Al−1%Zn−1%Si alloy with non-dendritic microstructure was prepared by strain induced melt activation(SIMA)process.The effect of compression ratio on the evolution of semisolid microstructure of the experimental alloy was investigated.The results indicate that the average size ofα-Mg grains decreases and spheroidizing tendency becomes more obvious with the compression ratios increasing from 0 to 40%.In addition,the eutectic Mg2Si phase in the Mg−10%Al−1%Zn−1%Si alloy transforms completely from the initial fishbone shape to globular shape by SIMA process.With the increasing of compression ratio,the morphology and average size of Mg2Si phases do not change obviously.The morphology modification mechanism of Mg2Si phase in Mg−10%Al−1%Zn−1%Si alloy by SIMA process was also studied.

Non-isothermal crystallization kinetics of Nylon 10T and Nylon 10T/1010 copolymers:Effect of sebacic acid as a third comonomer

Nylon 10 T and Nylon 10T/1010 samples were synthesized by direct melt polymerization. The non-isothermal crystallization kinetics of Nylon 10 T and Nylon 10T/1010 was investigated by means of differential scanning calorimetry(DSC). Jeziorny equation and Mo equation were applied to describe the non-isothermal crystallization kinetics of the Nylon 10 T and the Nylon 10T/1010. The activation energies for non-isothermal crystallization were obtained by Vyazovkin's method and Friedman's method, respectively. These results showed that Jeziorny equation and Mo equation well described the non-isothermal crystallization kinetics of the Nylon 10 T and the Nylon 10T/1010. It was found that the values of the activation energy for non-isothermal crystallization of the Nylon 10T/1010 were lower than those of the Nylon 10 T at a given temperature or relative crystallinity degree,which revealed that crystallization ability of the Nylon 10T/1010 was higher. The crystal morphology was observed by means of a polarized optical microscope(POM) and X-ray diffraction(XRD). It was found that the addition of sebacic acid comonomer not only did not change the crystal form of the Nylon 10 T, but also significantly increased the number and decreased the size of spherulites. Comparing with the Nylon 10 T, the crystallization rate was increased with the addition of the sebacic acid comonomer.

A δ-function-like peak in the specific heat of two-dimensional vortex lattice： Monte carlo study

A repulsive vortex\|vortex interaction model was used to numerically study the melting transition of the two\|dimensional vortex system with Monte Carlo method. Then a δ\|function\|like peak in the specific heat was observed and the internal energy showed a sharp drop at the melting temperature, which indicated that there exists a first\|order melting transition at finite temperatures. The Lindemann criterion was also investigated and valid, but different from previous simulation results.

Comparative Study on Two Melting Simulation Methods:Melting Curve of Gold

Melting simulation methods are of crucial importance to determining melting temperature of materials efficiently.A high-efficiency melting simulation method saves much simulation time and computational resources.To compare the efficiency of our newly developed shock melting(SM)method with that of the well-established two-phase(TP)method,we calculate the high-pressure melting curve of Au using the two methods based on the optimally selected interatomic potentials.Although we only use 640 atoms to determine the melting temperature of Au in the SM method,the resulting melting curve accords very well with the results from the TP method using much more atoms.Thus,this shows that a much smaller system size in SM method can still achieve a fully converged melting curve compared with the TP method,implying the robustness and efficiency of the SM method.