A new competitive adsorption isothermal model(CAIM)was developed for the coexistent and competitive binding of heavy metals to the soil surface.This model extended the earlier adsorption isothermal models by consideri...A new competitive adsorption isothermal model(CAIM)was developed for the coexistent and competitive binding of heavy metals to the soil surface.This model extended the earlier adsorption isothermal models by considering more than one kind of ion adsorption on the soil surface.It was compared with the Langmuir model using different conditions, and it was found that CAIM,which was suitable for competitive ion adsorption at the soil solid-liquid surface,had more advantages than the Langmuir model.The new competitive adsorption isothermal model was used to fit the data of heavy metal(Zn and Cd)competitive adsorption by a yellow soil at two temperatures.The results showed that CAIM was appropriate for the competitive adsorption of heavy metals on the soil surface at different temperatures.The fitted parameters of CAIM had explicit physical meaning.The model allowed for the calculation of the standard molar Gibbs free energy change,the standard molar enthalpy change,and the standard molar entropy change of the competitive adsorption of the heavy metals,Zn and Cd,by the yellow soil at two temperatures using the thermodynamic equilibrium constants.展开更多
Taking into account the Bekenstein-Hawking area law,based on the analysis of Zeng and Liu et al.that area spectrum is determined by the periodicity of an outgoing wave,we discuss on the quantization of entropy from a ...Taking into account the Bekenstein-Hawking area law,based on the analysis of Zeng and Liu et al.that area spectrum is determined by the periodicity of an outgoing wave,we discuss on the quantization of entropy from a neutral black string.In addition,applying the adiabatic invariant quantity method proposed by Majhi and Vagenas,we further verify the entropy quantum of the neutral black string.As a result,two different methods show that the quantum of entropy is △S = 2π,which is in agreement with Bekenstein's proposal.展开更多
We study a simplified version of the Sachdev-Ye-Kitaev(SYK) model with real interactions by exact diagonalization. Instead of satisfying a continuous Gaussian distribution, the interaction strengths are assumed to be ...We study a simplified version of the Sachdev-Ye-Kitaev(SYK) model with real interactions by exact diagonalization. Instead of satisfying a continuous Gaussian distribution, the interaction strengths are assumed to be chosen from discrete values with a finite separation. A quantum phase transition from a chaotic state to an integrable state is observed by increasing the discrete separation. Below the critical value, the discrete model can well reproduce various physical quantities of the original SYK model,including the volume law of the ground-state entanglement, level distribution, thermodynamic entropy,and out-of-time-order correlation(OTOC) functions. For systems of size up to N=20, we find that the transition point increases with system size, indicating that a relatively weak randomness of interaction can stabilize the chaotic phase. Our findings significantly relax the stringent conditions for the realization of SYK model, and can reduce the complexity of various experimental proposals down to realistic ranges.展开更多
基金Project supported by the Program for Changjiang Scholars and Innovative Research Team in University of China(No.IRT0749)
文摘A new competitive adsorption isothermal model(CAIM)was developed for the coexistent and competitive binding of heavy metals to the soil surface.This model extended the earlier adsorption isothermal models by considering more than one kind of ion adsorption on the soil surface.It was compared with the Langmuir model using different conditions, and it was found that CAIM,which was suitable for competitive ion adsorption at the soil solid-liquid surface,had more advantages than the Langmuir model.The new competitive adsorption isothermal model was used to fit the data of heavy metal(Zn and Cd)competitive adsorption by a yellow soil at two temperatures.The results showed that CAIM was appropriate for the competitive adsorption of heavy metals on the soil surface at different temperatures.The fitted parameters of CAIM had explicit physical meaning.The model allowed for the calculation of the standard molar Gibbs free energy change,the standard molar enthalpy change,and the standard molar entropy change of the competitive adsorption of the heavy metals,Zn and Cd,by the yellow soil at two temperatures using the thermodynamic equilibrium constants.
基金Supported by the Scientific Research Foundation of the Education Department of Liaoning Province under Grant No. L2011195
文摘Taking into account the Bekenstein-Hawking area law,based on the analysis of Zeng and Liu et al.that area spectrum is determined by the periodicity of an outgoing wave,we discuss on the quantization of entropy from a neutral black string.In addition,applying the adiabatic invariant quantity method proposed by Majhi and Vagenas,we further verify the entropy quantum of the neutral black string.As a result,two different methods show that the quantum of entropy is △S = 2π,which is in agreement with Bekenstein's proposal.
基金This work was supported by the National Natural Science Foundation of China(11434011,11522436,11774425,11704029)the National Key R&D Program of China(2018YFA0306501)+1 种基金the Beijing Natural Science Foundation(Z180013)the Research Funds of Renmin University of China(16XNLQ03 and 18XNLQ15)。
文摘We study a simplified version of the Sachdev-Ye-Kitaev(SYK) model with real interactions by exact diagonalization. Instead of satisfying a continuous Gaussian distribution, the interaction strengths are assumed to be chosen from discrete values with a finite separation. A quantum phase transition from a chaotic state to an integrable state is observed by increasing the discrete separation. Below the critical value, the discrete model can well reproduce various physical quantities of the original SYK model,including the volume law of the ground-state entanglement, level distribution, thermodynamic entropy,and out-of-time-order correlation(OTOC) functions. For systems of size up to N=20, we find that the transition point increases with system size, indicating that a relatively weak randomness of interaction can stabilize the chaotic phase. Our findings significantly relax the stringent conditions for the realization of SYK model, and can reduce the complexity of various experimental proposals down to realistic ranges.
