A polystyrene-based ion-exchange resin was employed as the precursor for preparation of resin-derived carbon spheres （RCSs） through KOH activation with various impregnation ratios. Pore structure, yield and hardness...A polystyrene-based ion-exchange resin was employed as the precursor for preparation of resin-derived carbon spheres （RCSs） through KOH activation with various impregnation ratios. Pore structure, yield and hardness, surface functional groups of the samples and their adsorption performance towards dibenzothiophene （DBT） were investigated. The RCSs with large surface areas （up to 2696 m2/g） and total pore volumes （up to 1.46 cm3/g） exhibited larger adsorption capacities than a commercial ac- tivated carbon, F400. Polanyi-Dubinin-Mane （PDM） model was applied to fit the adsorption data, which proved that micropore filling was involved during the adsorption process. Moreover, a good linear relationship was observed between the ex- tra-micropore volume and adsorption capacity. Intra-particle diffusion （IPD） model was used to describe the kinetic data of DBT onto the adsorbents. The adsorption processes were divided into three stages according to the different diffusion parame- ter. The selective adsorption towards DBT in the presence of competing compounds was also investigated and the high selec- tivity of the RSCs towards DBT may be attributed to the large quantity of acidic oxygen-containing groups.展开更多
The Ba Ce0.8Y0.2O2.9-Ce0.85Sm0.15O1.925 composite electrolytes were prepared with Ba Ce0.8Y0.2O2.9(BCY) and Ce0.85Sm0.15O1.925(SDC). The SDC and BCY powders were mixed in the weight ratio of 95:5, 85:15, and 75:25, re...The Ba Ce0.8Y0.2O2.9-Ce0.85Sm0.15O1.925 composite electrolytes were prepared with Ba Ce0.8Y0.2O2.9(BCY) and Ce0.85Sm0.15O1.925(SDC). The SDC and BCY powders were mixed in the weight ratio of 95:5, 85:15, and 75:25, respectively(named as BS95, BS85, and BS75). Because of the composite effect between the SDC and BCY phases, the BS95 and BS85 exhibit improved conductivity compared with the pure SDC and BCY. The conductivity of BS95 is higher than that of BS85, indicating that the composite effect of BS95 is greater than that of BS85. Nevertheless, the composite effect in BS75 does not exist. Hence, we conclude that the composite effect in the BCY-SDC composites will decrease with the increase of the amount of BCY and even disappear when the amount of BCY exceeds a certain value. In our case, the optimum composition of the composite electrolyte is 95 wt% SDC and 5 wt% BCY. The BS95 has the highest conductivity(σ1t=0.07808 S cm-1, at 800 °C) and the fuel cell based on the BS95 shows the best performance(the maximum power density reaches as high as 526 mw cm-2 at 750 °C). The encouraging results suggest that the BCY-SDC composites are the very promising electrolyte materials for IT-SOFCs.展开更多
文摘A polystyrene-based ion-exchange resin was employed as the precursor for preparation of resin-derived carbon spheres （RCSs） through KOH activation with various impregnation ratios. Pore structure, yield and hardness, surface functional groups of the samples and their adsorption performance towards dibenzothiophene （DBT） were investigated. The RCSs with large surface areas （up to 2696 m2/g） and total pore volumes （up to 1.46 cm3/g） exhibited larger adsorption capacities than a commercial ac- tivated carbon, F400. Polanyi-Dubinin-Mane （PDM） model was applied to fit the adsorption data, which proved that micropore filling was involved during the adsorption process. Moreover, a good linear relationship was observed between the ex- tra-micropore volume and adsorption capacity. Intra-particle diffusion （IPD） model was used to describe the kinetic data of DBT onto the adsorbents. The adsorption processes were divided into three stages according to the different diffusion parame- ter. The selective adsorption towards DBT in the presence of competing compounds was also investigated and the high selec- tivity of the RSCs towards DBT may be attributed to the large quantity of acidic oxygen-containing groups.
基金supported by the Natural Science Foundation of Liaoning Province(2013020010)
文摘The Ba Ce0.8Y0.2O2.9-Ce0.85Sm0.15O1.925 composite electrolytes were prepared with Ba Ce0.8Y0.2O2.9(BCY) and Ce0.85Sm0.15O1.925(SDC). The SDC and BCY powders were mixed in the weight ratio of 95:5, 85:15, and 75:25, respectively(named as BS95, BS85, and BS75). Because of the composite effect between the SDC and BCY phases, the BS95 and BS85 exhibit improved conductivity compared with the pure SDC and BCY. The conductivity of BS95 is higher than that of BS85, indicating that the composite effect of BS95 is greater than that of BS85. Nevertheless, the composite effect in BS75 does not exist. Hence, we conclude that the composite effect in the BCY-SDC composites will decrease with the increase of the amount of BCY and even disappear when the amount of BCY exceeds a certain value. In our case, the optimum composition of the composite electrolyte is 95 wt% SDC and 5 wt% BCY. The BS95 has the highest conductivity(σ1t=0.07808 S cm-1, at 800 °C) and the fuel cell based on the BS95 shows the best performance(the maximum power density reaches as high as 526 mw cm-2 at 750 °C). The encouraging results suggest that the BCY-SDC composites are the very promising electrolyte materials for IT-SOFCs.
