【背景】甲烷厌氧氧化(anaerobic oxidation of methane,AOM)包含反硝化型甲烷厌氧氧化和硫酸盐还原型甲烷厌氧氧化。目前,人们向水体中排放过量的含氮及含硫污染物,引起了严重的环境污染和生态破坏。【目的】利用甲烷厌氧氧化微生物燃...【背景】甲烷厌氧氧化(anaerobic oxidation of methane,AOM)包含反硝化型甲烷厌氧氧化和硫酸盐还原型甲烷厌氧氧化。目前,人们向水体中排放过量的含氮及含硫污染物,引起了严重的环境污染和生态破坏。【目的】利用甲烷厌氧氧化微生物燃料电池(microbial fuel cell,MFC)研究同步脱氮除硫耦合反应机理及反应过程中微生物的多样性信息。【方法】构建了3个微生物燃料电池(N-S-MFC、N-MFC、S-MFC),以甲烷作为唯一碳源,探究其同步脱氮除硫性能,并采用16S rRNA基因高通量测序技术对微生物群落结构进行分析。【结果】N-S-MFC中硝酸盐和硫酸盐的去除率分别为90.91%和18.46%。阳极室中微生物的相对丰度提高,与反硝化及硫酸盐还原菌相关的微生物大量富集,如门水平上拟杆菌门(Bacteroidota)、厚壁菌门(Firmicutes)和脱硫杆菌门(Desulfobacterota),同时属水平上Methylobacterium_Methylorubrum、Methylocaldum、Methylomonas等常见的甲烷氧化菌增多。【结论】N-S-MFC促进了硝酸盐还原,而对硫酸盐还原几乎无影响,本研究为甲烷MFC在污水中同步脱氮除硫的应用提供理论依据。展开更多
With focus on investigating the effect of combustor scale on the conversion of fuel-N to NOx and N20, experiments are carried out in three combustors, including single coal particle combustion test rig, laboratory sca...With focus on investigating the effect of combustor scale on the conversion of fuel-N to NOx and N20, experiments are carried out in three combustors, including single coal particle combustion test rig, laboratory scale circulating fluidized-bed boiler （CFB） and full scale CFB in this work. For single coal particle combustion, the majority of f-uel-N （65%-82%） is released as NOx, while only a little （less than 8%） fuel-N yields N20. But in labora- tory scale CFB, the conversion of fuel-N to N20 is increases, but the conversion of fuel-N to NOx is quite less than that of single coal particle combustion. This is because much char in CFB can promote the NOx reduction by in- creasing N20 formation. In full scale CFB, both of the conversion of fuel-N to NOx and the conversion of fuel-N to N20 are smaller than laboratory scale CFB.展开更多
Microbial fuel cells （MFCs） rely on microbial conversion of organic substrates to electricity. The optimal perfor- mance depends on the establishment of a microbial community rich in electrogenic bacteria. Usually t...Microbial fuel cells （MFCs） rely on microbial conversion of organic substrates to electricity. The optimal perfor- mance depends on the establishment of a microbial community rich in electrogenic bacteria. Usually this micro- bial community is established from inoculation of the MFC anode chamber with naturally occurring mixed inocula. In this study, the electrochemical performance of MFCs and microbial community evolution were eval- uated for three inocula including domestic wastewater （DW）, lake sediment （LS） and biogas sludge （BS） with varying substrate loading （Lsub） and external resistance （Rext） on the MFC. The electrogenic bacterium Geobacter sulfurreducens was identified in all inocula and its abundance during MFC operation was positively linked to the MFC performance. The IS inoculated MFCs showed highest abundance （18% ± 1%） of G. sulfurreducens, maximum current density [Imax = （690 ± 30） mA.m 2] and coulombic efficiency （CE = 29% ±1%） with acetate as the substrate./max and CE increased to （1780 ± 30） mA.m-2 and 58%± 1%, respectively, after decreasing the Rext from 1000 Ωto 200 Ω, which also correlated to a higher abundance ofG. sulfurreducens （21% ±0.7%） on the MFC anodic biofilm. The data obtained contribute to understanding the microbial community response to Lsub and Roy, for of timizing electricity eneration in MFCs.展开更多
This paper presents results on the combustion of syngas fuel in re-circulating vortex combustor. The combustion stability is achieved through the use of cavities in which recirculation zones of hot products generated ...This paper presents results on the combustion of syngas fuel in re-circulating vortex combustor. The combustion stability is achieved through the use of cavities in which recirculation zones of hot products generated by the direct injection of fuel and air are created and acting as a continuous source of ignition for the incoming main fuel-air stream. CFD （computational fluid dynamics） analysis was performed in this study to test the combustion performance and emissions from the vortex trapped combustor using synthetic gas or syngas fuel produced from the gasification process. The flame temperature, the flow field and species concentrations inside the vortex trapped combustor were obtained. Several syngas fuels with different fuel compositions （H2, CO, CH4, CO2, N2 and H20） and lower heating values were tested in this study. The changes on the flame temperature and species concentrations inside the combustor, the emissions of NOx, CO, CO2 at the exit of the combustor, the combustor efficiency and the total pressure drop for syngas fuels are presented in this paper. The effect of H2/CO ratio and the mass fraction of each constituent of syngas fuels and hydrogen-methane fuel mixtures on the combustion and emissions performances were investigated.展开更多
In this article, the authors propose the production of ethanol from cellulose as an alternative to oil. Cellulosic-ethanol will reduce greenhouse gas emissions, and provide a means to prevent forest fires. This liquid...In this article, the authors propose the production of ethanol from cellulose as an alternative to oil. Cellulosic-ethanol will reduce greenhouse gas emissions, and provide a means to prevent forest fires. This liquid dense fuel was selected because it： （1） easily transported and dispensed as a fuel; （2） can be handled by the existing fuel distribution infrastructure; and （3） unlike its commercial competitor, Me-OH （Methanol）, Et-OH （Ethanol）, is edible, thus being biodegradable and nontoxic. Forest residue ethanol is cheaper to produce and more environmentally friendly than other forms of ethanol fuel. Furthermore, forests would have less available ground fuel for fires. The potential decline of forest fires would then reduce the carbon footprint attributed directly to forest fires. In combination with ethanol fuel combustion, carbon emissions can be reduced by more than 70% compared to gasoline combustion. We used GREET （Greenhouse gases, Regulated Emissions, and Energy use in Transportation） software to assess the life cycles of different fuel pathways. In conclusion, cellulosic ethanol fuel is clearly an answer to decrease dependency on current oil imports and prevent forest fires.展开更多
Increase in greenhouse gases, has made scientists to substitute alternative fuels for fossil fuels. Nowadays, converting biomass into liquid by Fischer-Tropsch synthesis is a major concern for alternative fuels （gaso...Increase in greenhouse gases, has made scientists to substitute alternative fuels for fossil fuels. Nowadays, converting biomass into liquid by Fischer-Tropsch synthesis is a major concern for alternative fuels （gasoline, diesel etc.）. Selectivity of Fischer-Tropsch hydrocarbon product （green fuel） is an important issue. In this study, the experimental data has been obtained from three factors; temperature, H2/CO ratio and pressure in the fixed bed micro reactor. T = 543-618 （K）, P = 3-10 （bar）, H2/CO = 1-2 and space velocity = 4500 （l/h） were the reactor conditions. The results of product modeling for methane （CH4）, ethane （C2H6）, ethylene （C2H4） and CO conversion with experimental data were compared. The effective parameters and the interaction between them were investigated in the model. H2/CO ratio and pressure and interaction between pressure and H2/CO in ethane selectivity model and CO conversion and interaction between temperature and H2/CO ratio in methane selectivity model and ethylene gave the best results. To determine the optimal conditions for light hydrocarbons, ANOVA and RSM were employed. Finally, products optimization was done and results were concluded.展开更多
This work deals with the examination of farm tractor with diesel engine from the viewpoint of power and gas emissions, using as fuel diesel-ethanol mixtures. A series of laboratory instruments was used for the realiza...This work deals with the examination of farm tractor with diesel engine from the viewpoint of power and gas emissions, using as fuel diesel-ethanol mixtures. A series of laboratory instruments was used for the realization of the experiments. The tractor engine is functioning under full load conditions. The experimental results have shown small reduction of power engine with simultaneously remarkable reduction of CO and HC emissions.展开更多
In the near future, the use of FCVs （fuel cell vehicles） is expected to help mitigate environmental problems such as exhaustion of fossil fuels and greenhouse gas emissions. Manufacturers publish an FCV＇s specific ...In the near future, the use of FCVs （fuel cell vehicles） is expected to help mitigate environmental problems such as exhaustion of fossil fuels and greenhouse gas emissions. Manufacturers publish an FCV＇s specific fuel consumption, but not its dynamic characteristics such as fuel consumption ratio and motor power ratio. Thus, it is difficult to reflect the dynamic characteristics of FCVs in lifecycle system evaluation. To solve this problem, we propose a fuel-consumption simulation method for FCVs using a 1.2 kW stationary PEMFC （proton exchange membrane fuel cell）. In this study, the specific fuel consumption under driving cycles such as the Japanese 10-15 and the JC08 modes are determined and compared with the FCV simulation results obtained using fuel consumption ratios derived from the stationary PEMFC. In the simulation, the specific fuel consumption was found to be 1.16 kg-H2/100-km for the base case under the Japanese 10-15 driving cycle.展开更多
Three types of low-carbon vehicle technologies in China are reviewed. Potential effects are listed for those integrated energy-saving technologies for conventional vehicles. Low carbon transitions, including alternati...Three types of low-carbon vehicle technologies in China are reviewed. Potential effects are listed for those integrated energy-saving technologies for conventional vehicles. Low carbon transitions, including alternative vehicle power train systems and fuels, are discussed on their development status and trends, including life cycle primary fossil energy use and greenhouse gas emissions of each pathway. To further support the low-carbon vehicle technologies development, integrated policies should seek to： （1） employ those integrated energy-saving technologies, （2） apply hybrid electric technology, （3） commercialize electric vehicles through battery technology innovation, （4） support fuel cell vehicles and hydrogen technology R＆D for future potential applications, （5） boost the R＆D of second generation biofuel technology, and （6） conduct further research on applying low-carbon technologies including CO2 capture and storage technology to coal-based transportation solutions.展开更多
基金Supported by the National Basic Research Program of China(2009CB219802)
文摘With focus on investigating the effect of combustor scale on the conversion of fuel-N to NOx and N20, experiments are carried out in three combustors, including single coal particle combustion test rig, laboratory scale circulating fluidized-bed boiler （CFB） and full scale CFB in this work. For single coal particle combustion, the majority of f-uel-N （65%-82%） is released as NOx, while only a little （less than 8%） fuel-N yields N20. But in labora- tory scale CFB, the conversion of fuel-N to N20 is increases, but the conversion of fuel-N to NOx is quite less than that of single coal particle combustion. This is because much char in CFB can promote the NOx reduction by in- creasing N20 formation. In full scale CFB, both of the conversion of fuel-N to NOx and the conversion of fuel-N to N20 are smaller than laboratory scale CFB.
基金grateful to Danida Fellowship Centre for supporting the research project (Biobased electricity in developing countries,DFC No.11-091 Ris?)The financial support from China Scholarship Council (CSC No.2011635051) for Guotao Sun is gratefully acknowledged.Annette E.Jensen,DTU is thanked for technical support
文摘Microbial fuel cells （MFCs） rely on microbial conversion of organic substrates to electricity. The optimal perfor- mance depends on the establishment of a microbial community rich in electrogenic bacteria. Usually this micro- bial community is established from inoculation of the MFC anode chamber with naturally occurring mixed inocula. In this study, the electrochemical performance of MFCs and microbial community evolution were eval- uated for three inocula including domestic wastewater （DW）, lake sediment （LS） and biogas sludge （BS） with varying substrate loading （Lsub） and external resistance （Rext） on the MFC. The electrogenic bacterium Geobacter sulfurreducens was identified in all inocula and its abundance during MFC operation was positively linked to the MFC performance. The IS inoculated MFCs showed highest abundance （18% ± 1%） of G. sulfurreducens, maximum current density [Imax = （690 ± 30） mA.m 2] and coulombic efficiency （CE = 29% ±1%） with acetate as the substrate./max and CE increased to （1780 ± 30） mA.m-2 and 58%± 1%, respectively, after decreasing the Rext from 1000 Ωto 200 Ω, which also correlated to a higher abundance ofG. sulfurreducens （21% ±0.7%） on the MFC anodic biofilm. The data obtained contribute to understanding the microbial community response to Lsub and Roy, for of timizing electricity eneration in MFCs.
文摘This paper presents results on the combustion of syngas fuel in re-circulating vortex combustor. The combustion stability is achieved through the use of cavities in which recirculation zones of hot products generated by the direct injection of fuel and air are created and acting as a continuous source of ignition for the incoming main fuel-air stream. CFD （computational fluid dynamics） analysis was performed in this study to test the combustion performance and emissions from the vortex trapped combustor using synthetic gas or syngas fuel produced from the gasification process. The flame temperature, the flow field and species concentrations inside the vortex trapped combustor were obtained. Several syngas fuels with different fuel compositions （H2, CO, CH4, CO2, N2 and H20） and lower heating values were tested in this study. The changes on the flame temperature and species concentrations inside the combustor, the emissions of NOx, CO, CO2 at the exit of the combustor, the combustor efficiency and the total pressure drop for syngas fuels are presented in this paper. The effect of H2/CO ratio and the mass fraction of each constituent of syngas fuels and hydrogen-methane fuel mixtures on the combustion and emissions performances were investigated.
文摘In this article, the authors propose the production of ethanol from cellulose as an alternative to oil. Cellulosic-ethanol will reduce greenhouse gas emissions, and provide a means to prevent forest fires. This liquid dense fuel was selected because it： （1） easily transported and dispensed as a fuel; （2） can be handled by the existing fuel distribution infrastructure; and （3） unlike its commercial competitor, Me-OH （Methanol）, Et-OH （Ethanol）, is edible, thus being biodegradable and nontoxic. Forest residue ethanol is cheaper to produce and more environmentally friendly than other forms of ethanol fuel. Furthermore, forests would have less available ground fuel for fires. The potential decline of forest fires would then reduce the carbon footprint attributed directly to forest fires. In combination with ethanol fuel combustion, carbon emissions can be reduced by more than 70% compared to gasoline combustion. We used GREET （Greenhouse gases, Regulated Emissions, and Energy use in Transportation） software to assess the life cycles of different fuel pathways. In conclusion, cellulosic ethanol fuel is clearly an answer to decrease dependency on current oil imports and prevent forest fires.
文摘Increase in greenhouse gases, has made scientists to substitute alternative fuels for fossil fuels. Nowadays, converting biomass into liquid by Fischer-Tropsch synthesis is a major concern for alternative fuels （gasoline, diesel etc.）. Selectivity of Fischer-Tropsch hydrocarbon product （green fuel） is an important issue. In this study, the experimental data has been obtained from three factors; temperature, H2/CO ratio and pressure in the fixed bed micro reactor. T = 543-618 （K）, P = 3-10 （bar）, H2/CO = 1-2 and space velocity = 4500 （l/h） were the reactor conditions. The results of product modeling for methane （CH4）, ethane （C2H6）, ethylene （C2H4） and CO conversion with experimental data were compared. The effective parameters and the interaction between them were investigated in the model. H2/CO ratio and pressure and interaction between pressure and H2/CO in ethane selectivity model and CO conversion and interaction between temperature and H2/CO ratio in methane selectivity model and ethylene gave the best results. To determine the optimal conditions for light hydrocarbons, ANOVA and RSM were employed. Finally, products optimization was done and results were concluded.
文摘This work deals with the examination of farm tractor with diesel engine from the viewpoint of power and gas emissions, using as fuel diesel-ethanol mixtures. A series of laboratory instruments was used for the realization of the experiments. The tractor engine is functioning under full load conditions. The experimental results have shown small reduction of power engine with simultaneously remarkable reduction of CO and HC emissions.
文摘In the near future, the use of FCVs （fuel cell vehicles） is expected to help mitigate environmental problems such as exhaustion of fossil fuels and greenhouse gas emissions. Manufacturers publish an FCV＇s specific fuel consumption, but not its dynamic characteristics such as fuel consumption ratio and motor power ratio. Thus, it is difficult to reflect the dynamic characteristics of FCVs in lifecycle system evaluation. To solve this problem, we propose a fuel-consumption simulation method for FCVs using a 1.2 kW stationary PEMFC （proton exchange membrane fuel cell）. In this study, the specific fuel consumption under driving cycles such as the Japanese 10-15 and the JC08 modes are determined and compared with the FCV simulation results obtained using fuel consumption ratios derived from the stationary PEMFC. In the simulation, the specific fuel consumption was found to be 1.16 kg-H2/100-km for the base case under the Japanese 10-15 driving cycle.
基金co-supported by the China National Social Science Foundation(09&ZD029)MOE Project of Key Research Institute of Humanities and Social Sciences at Universities in China (2009JJD790029)+1 种基金Doctoral Thesis Fund of Beijing Municipal Science and Technology Commission (zz200923)the CAERC program(Tsinghua/ GM/SAIC-China)
文摘Three types of low-carbon vehicle technologies in China are reviewed. Potential effects are listed for those integrated energy-saving technologies for conventional vehicles. Low carbon transitions, including alternative vehicle power train systems and fuels, are discussed on their development status and trends, including life cycle primary fossil energy use and greenhouse gas emissions of each pathway. To further support the low-carbon vehicle technologies development, integrated policies should seek to： （1） employ those integrated energy-saving technologies, （2） apply hybrid electric technology, （3） commercialize electric vehicles through battery technology innovation, （4） support fuel cell vehicles and hydrogen technology R＆D for future potential applications, （5） boost the R＆D of second generation biofuel technology, and （6） conduct further research on applying low-carbon technologies including CO2 capture and storage technology to coal-based transportation solutions.
