Naphtha is an important raw material for manufacture of clean fuels and ethylene products. However, China is experiencing a serious imbalance between supply and demand of naphtha, due to its rapidly increasing car pop...Naphtha is an important raw material for manufacture of clean fuels and ethylene products. However, China is experiencing a serious imbalance between supply and demand of naphtha, due to its rapidly increasing car population and booming ethylene industry, the demand of which cannot be met by the domestic depleting crude oil resources. Focusing on alleviating the above-mentioned naphtha deficit, this paper puts forward an idea suggesting that China＇s limited naphtha resource should be used reasonably. Naphtha feedstocks with more potential aromatic content should be used in catalytic reforming process to produce clean fuel products, and those feedstocks with more paraffinic content should be used in ethylene production. Meanwhile, industry tests show that the low-valued naphtha byproduct from ethylene plants and the products of secondary processing units at refineries can also be applied so as to extend the naphtha supply for manufacture of cleaner fuels and ethylene derivatives.展开更多
As one of promising clean coal technologies used to reduce pollutant emission and CO2 discharge, co gasification has been extensively investigated. In this paper, a new co-gasification technology using coal and natura...As one of promising clean coal technologies used to reduce pollutant emission and CO2 discharge, co gasification has been extensively investigated. In this paper, a new co-gasification technology using coal and natural gas was developed. The distinct advantages of this technology are the excellent fuel flexibility and the availability to establish the gasifier by reconstructing the blast furnace or similar shaft furnace. Based on the concept of the new co-gasification technology, lab-scale experiments and modeling study were carried out. The obtained results indicate that gasification is undertaken at ideal thermodynamic environment where quasi-equilibrium could be reached without catalysts. The modeling results are in agreement with experimental data, demonstrating the validity of the model and that Aspen Plus is a useful tool for the analysis of the co-gasification process. Furthermore, the effect of major operation parameters, including oxygen flow rate and steam flow rate, on co-gasification process was investigated using the developed model.展开更多
文摘Naphtha is an important raw material for manufacture of clean fuels and ethylene products. However, China is experiencing a serious imbalance between supply and demand of naphtha, due to its rapidly increasing car population and booming ethylene industry, the demand of which cannot be met by the domestic depleting crude oil resources. Focusing on alleviating the above-mentioned naphtha deficit, this paper puts forward an idea suggesting that China＇s limited naphtha resource should be used reasonably. Naphtha feedstocks with more potential aromatic content should be used in catalytic reforming process to produce clean fuel products, and those feedstocks with more paraffinic content should be used in ethylene production. Meanwhile, industry tests show that the low-valued naphtha byproduct from ethylene plants and the products of secondary processing units at refineries can also be applied so as to extend the naphtha supply for manufacture of cleaner fuels and ethylene derivatives.
文摘As one of promising clean coal technologies used to reduce pollutant emission and CO2 discharge, co gasification has been extensively investigated. In this paper, a new co-gasification technology using coal and natural gas was developed. The distinct advantages of this technology are the excellent fuel flexibility and the availability to establish the gasifier by reconstructing the blast furnace or similar shaft furnace. Based on the concept of the new co-gasification technology, lab-scale experiments and modeling study were carried out. The obtained results indicate that gasification is undertaken at ideal thermodynamic environment where quasi-equilibrium could be reached without catalysts. The modeling results are in agreement with experimental data, demonstrating the validity of the model and that Aspen Plus is a useful tool for the analysis of the co-gasification process. Furthermore, the effect of major operation parameters, including oxygen flow rate and steam flow rate, on co-gasification process was investigated using the developed model.
