Silicone rubber gaskets are employed to keep fuel gases and oxidation in their own zones. Due to the viscosity and elasticity, the assembly force could relax when the silicone rubber is compressed in a proton exchange...Silicone rubber gaskets are employed to keep fuel gases and oxidation in their own zones. Due to the viscosity and elasticity, the assembly force could relax when the silicone rubber is compressed in a proton exchange membrane fuel cell. In this work, the stress relaxation behavior of silicone rubber samples is studied under different temperatures and simulated operating conditions. The results show that the stress relaxes exponentially with time at 25% strain level, especially at higher temperature or with higher acid concentration solution. The three-term Prony series can simulate the viscoelastic behavior well, and the Master curves are established by applying a time–temperature superposition method to estimate the life of the samples. It can save approximately 50% and 78% of the test time when an operating temperature and acid solution are chosen appropriately.展开更多
基金Projects(51505212,51505211,11302097)supported by the National Natural Science Foundation of ChinaProject(XTCX201609)supported by the Open Research Fund of Jiangsu Collaborative Innovation Center for Smart Distribution Network,Nanjing Institute of Technology,China+3 种基金Project(1301060B)supported by the Postdoctoral Science Foundation of Jiangsu Province,ChinaProject(11KJD130001)supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions,ChinaProject(ZKJ201401)supported by the on-job Doctorate Foundation of Nanjing Institute of Technology,ChinaProject(JXKJ201511)supported by the Open Projects about Key Discipline in 2015,School of Mechanical Engineering,Nanjing Institute of Technology,China
文摘Silicone rubber gaskets are employed to keep fuel gases and oxidation in their own zones. Due to the viscosity and elasticity, the assembly force could relax when the silicone rubber is compressed in a proton exchange membrane fuel cell. In this work, the stress relaxation behavior of silicone rubber samples is studied under different temperatures and simulated operating conditions. The results show that the stress relaxes exponentially with time at 25% strain level, especially at higher temperature or with higher acid concentration solution. The three-term Prony series can simulate the viscoelastic behavior well, and the Master curves are established by applying a time–temperature superposition method to estimate the life of the samples. It can save approximately 50% and 78% of the test time when an operating temperature and acid solution are chosen appropriately.