In order to prevent spontaneous coal combustion occurring at a fully mechanized caving face with large obliquity in deep mines in China, we have analyzed the characteristics of spontaneous coal combustion and explain ...In order to prevent spontaneous coal combustion occurring at a fully mechanized caving face with large obliquity in deep mines in China, we have analyzed the characteristics of spontaneous coal combustion and explain theoretically the factors affecting spontaneous coal combustion, such as rock bursts, high temperatures, high ventilation resistance, slow advancing speed and large obliquity mining. Key technologies to prevent spontaneous combustion occurring in sharply inclined seams in deep mines are pro- posed; these include pouring water, stopping leakage in upper and lower comers of the working face, choking off the goaf and cov- eting the coal. CO concentrations were controlled within two years to less than 15×10^-6 at the upper comer by applying these tech- nologies at the 1410 working face of the Huafeng coal mine. Our method has significant theoretical value and is of practical impor- tance in controlling spontaneous coal combustion occurring at a fully mechanized caving face with large obliquity in deep mines.展开更多
The bromine (Br) and iodine (I) in raw coal, bottom ash (BA) and fly ash (FA) from seven thermal power plants (TPP) digested with pyrohydrolysis were determined by using inductively coupled plasma mass spect...The bromine (Br) and iodine (I) in raw coal, bottom ash (BA) and fly ash (FA) from seven thermal power plants (TPP) digested with pyrohydrolysis were determined by using inductively coupled plasma mass spectrometry (ICP-MS). The distribution behavior of Br and I during coal combustion were researched and the environmental effects of Br and I in BA, FA and gas phase were analyzed. The results show that both elements Br and I in combustion products from TPP are usually pre- sent in decreasing order of the distribution rate as gas phase, FA and BA. In FA and BA, the distribution rate of Br (8.11% and 1.68%, respectively) are generally lower than that of I (9.26% and 4.67%, respectively); on the contrary, in gas phase, the former (90.2%) is higher than the latter (86.9%). In addition, for gas phase, the percentage of Br: (2.0%-75%) in total Br is generally larger than that of I2 (1.0%-10%) in total I. The environmental effects for Br and I emitted into atmosphere from TPP may be larger than those remained and captured by both FA and BA.展开更多
In order to provide experimental guide to commercial use of fluorine pollution control during coal combustion, with fluorine pollution control during coal combustion in mind, this paper proposed the theory of combusti...In order to provide experimental guide to commercial use of fluorine pollution control during coal combustion, with fluorine pollution control during coal combustion in mind, this paper proposed the theory of combustion fluorine retention technology. Feasibility of fluorine retention reaction with calcium-based fluorine retention agent was analyzed through thermo-dynamic calculation during coal combustion. By simulating the restraining and retention effects and influential factors of calcium-based sorbets on vaporized fluoride during experimental combustion using fixed bed tube furnace, the paper systematically explored the influential law of such factors as combustion temperature, retention time, and added quantities of calcium-based sorbets on effects of fluorine retention. The research result shows that adding calcium-based fluorine retention agent in coal combustion has double effects of fluorine retention and sulfur retention, it lays an experimental foundation for commercial test of combustion fluorine retention.展开更多
This paper theoretically analyzes major factors influencing spontaneous combustion of coal, such as molecule structure of coal, porosity, temperature, concentration of oxygen, coal thickness, velocity of face advance,...This paper theoretically analyzes major factors influencing spontaneous combustion of coal, such as molecule structure of coal, porosity, temperature, concentration of oxygen, coal thickness, velocity of face advance, and so on; and probes into how they affect the process of spontaneous combustion of coal, which is of momentous significance to predict or control self ignition of coal.展开更多
The exact shape and size of the gasification channel during underground coal gasification(UGC) are of vital importance for the safety and stability of the upper parts of the geological formation.In practice existing g...The exact shape and size of the gasification channel during underground coal gasification(UGC) are of vital importance for the safety and stability of the upper parts of the geological formation.In practice existing geological measurements are insufficient to obtain such information because the coal seam is typically deeply buried and the geological conditions are often complex.This paper introduces a cylindrical model for the gasification channel.The rock and soil masses are assumed to be homogeneous and isotropic and the effect of seepage on the temperature field was neglected.The theory of heat conduction was used to write the equation predicting the temperature field around the gasification channel.The idea of an excess temperature was introduced to solve the equations.Applying this model to UCG in the field for an influence radius,r,of 70 m gave the model parameters,u1,2,3...,of 2.4,5.5,8.7...By adjusting the radius(2,4,or 6 m) reasonable temperatures of the gasification channel were found for 4 m.The temperature distribution in the vertical direction,and the combustion volume,were also calculated.Comparison to field measurements shows that the results obtained from the proposed model are very close to practice.展开更多
基金Projects 2007B53 supported by the Foundation for National Excellent Doctoral Dissertation of ChinaBK2008123 by the Natural Science Foundation of Jiangsu Province
文摘In order to prevent spontaneous coal combustion occurring at a fully mechanized caving face with large obliquity in deep mines in China, we have analyzed the characteristics of spontaneous coal combustion and explain theoretically the factors affecting spontaneous coal combustion, such as rock bursts, high temperatures, high ventilation resistance, slow advancing speed and large obliquity mining. Key technologies to prevent spontaneous combustion occurring in sharply inclined seams in deep mines are pro- posed; these include pouring water, stopping leakage in upper and lower comers of the working face, choking off the goaf and cov- eting the coal. CO concentrations were controlled within two years to less than 15×10^-6 at the upper comer by applying these tech- nologies at the 1410 working face of the Huafeng coal mine. Our method has significant theoretical value and is of practical impor- tance in controlling spontaneous coal combustion occurring at a fully mechanized caving face with large obliquity in deep mines.
基金Supported by the National Natural Science Foundation of China (40133010, 40973080)
文摘The bromine (Br) and iodine (I) in raw coal, bottom ash (BA) and fly ash (FA) from seven thermal power plants (TPP) digested with pyrohydrolysis were determined by using inductively coupled plasma mass spectrometry (ICP-MS). The distribution behavior of Br and I during coal combustion were researched and the environmental effects of Br and I in BA, FA and gas phase were analyzed. The results show that both elements Br and I in combustion products from TPP are usually pre- sent in decreasing order of the distribution rate as gas phase, FA and BA. In FA and BA, the distribution rate of Br (8.11% and 1.68%, respectively) are generally lower than that of I (9.26% and 4.67%, respectively); on the contrary, in gas phase, the former (90.2%) is higher than the latter (86.9%). In addition, for gas phase, the percentage of Br: (2.0%-75%) in total Br is generally larger than that of I2 (1.0%-10%) in total I. The environmental effects for Br and I emitted into atmosphere from TPP may be larger than those remained and captured by both FA and BA.
基金the National Natural Science Foundation of China(50476032)China Postdoctoral Science Foundation(2004035555)New Century of Talents Scheme Projects of Universities in Liaoning Province(RC-04-04)
文摘In order to provide experimental guide to commercial use of fluorine pollution control during coal combustion, with fluorine pollution control during coal combustion in mind, this paper proposed the theory of combustion fluorine retention technology. Feasibility of fluorine retention reaction with calcium-based fluorine retention agent was analyzed through thermo-dynamic calculation during coal combustion. By simulating the restraining and retention effects and influential factors of calcium-based sorbets on vaporized fluoride during experimental combustion using fixed bed tube furnace, the paper systematically explored the influential law of such factors as combustion temperature, retention time, and added quantities of calcium-based sorbets on effects of fluorine retention. The research result shows that adding calcium-based fluorine retention agent in coal combustion has double effects of fluorine retention and sulfur retention, it lays an experimental foundation for commercial test of combustion fluorine retention.
基金ThearticleissupportedfinanciallybyNationalNaturalScienceFoundationofChina (No 59974 0 2 0 )andSpecialFoundationofShanxiEdu cat
文摘This paper theoretically analyzes major factors influencing spontaneous combustion of coal, such as molecule structure of coal, porosity, temperature, concentration of oxygen, coal thickness, velocity of face advance, and so on; and probes into how they affect the process of spontaneous combustion of coal, which is of momentous significance to predict or control self ignition of coal.
基金supported by a grant from the Major State Basic Research and Development Program of China (No. 2007CB714102)sponsored by the Fundamental Research Funds for the Central Universities (No. 2009B00714)
文摘The exact shape and size of the gasification channel during underground coal gasification(UGC) are of vital importance for the safety and stability of the upper parts of the geological formation.In practice existing geological measurements are insufficient to obtain such information because the coal seam is typically deeply buried and the geological conditions are often complex.This paper introduces a cylindrical model for the gasification channel.The rock and soil masses are assumed to be homogeneous and isotropic and the effect of seepage on the temperature field was neglected.The theory of heat conduction was used to write the equation predicting the temperature field around the gasification channel.The idea of an excess temperature was introduced to solve the equations.Applying this model to UCG in the field for an influence radius,r,of 70 m gave the model parameters,u1,2,3...,of 2.4,5.5,8.7...By adjusting the radius(2,4,or 6 m) reasonable temperatures of the gasification channel were found for 4 m.The temperature distribution in the vertical direction,and the combustion volume,were also calculated.Comparison to field measurements shows that the results obtained from the proposed model are very close to practice.