Combustible gases in coal mines are composed of methane, hydrogen, some multi-carbon alkane gases and other gases. Based on a numerical calculation, the explosion limits of combustible gases were studied, showing that...Combustible gases in coal mines are composed of methane, hydrogen, some multi-carbon alkane gases and other gases. Based on a numerical calculation, the explosion limits of combustible gases were studied, showing that these limits are related to the concentrations of different components in the mixture. With an increase of C4H10 and C6H14, the Lower ExplosionLimit (LEL) and Upper Explosion-Limit (UEL) of a combustible gas mixture will decrease clearly. For every 0.1% increase in C4H10 and C6H14, the LEL decreases by about 0.19% and the UEL by about 0.3%. The results also prove that, by increasing the amount of H2, the UEL of a combustible gas mixture will increase considerably. If the level of HE increases by 0.1%, the UEL will increase by about 0.3%. However, H2 has only a small effect on the LEL of the combustible gas mixture. Our study provides a theoretical foundation for judging the explosion risk of an explosive gas mixture in mines.展开更多
A two-dimensional multi-material code was indigenously developed to investigate the effects of duct boundary conditions and ignition positions on the propagation law of explosion wave for hydrogen and methane-based co...A two-dimensional multi-material code was indigenously developed to investigate the effects of duct boundary conditions and ignition positions on the propagation law of explosion wave for hydrogen and methane-based combustible mixture gas. In the code,Young's technique was employed to track the interface between the explosion products and air,and combustible function model was adopted to simulate ignition process. The code was employed to study explosion flow field inside and outside the duct and to obtain peak pressures in different boundary conditions and ignition positions. Numerical results suggest that during the propagation in a duct,for point initiation,the curvature of spherical wave front gradually decreases and evolves into plane wave. Due to the multiple reflections on the duct wall,multi-peak values appear on pressure-time curve,and peak pressure strongly relies on the duct boundary conditions and ignition position. When explosive wave reaches the exit of the duct,explosion products expand outward and forms shock wave in air. Multiple rarefaction waves also occur and propagate upstream along the duct to decrease the pressure in the duct. The results are in agreement with one-dimensional isentropic gas flow theory of the explosion products,and indicate that the ignition model and multi-material interface treatment method are feasible.展开更多
In order to investigate the damage and deformation mechanism of large scale steel fixed-roof oil-storage tanks under the combustible gas explosion, a series of explosion experiments of scaled models are conducted. Th...In order to investigate the damage and deformation mechanism of large scale steel fixed-roof oil-storage tanks under the combustible gas explosion, a series of explosion experiments of scaled models are conducted. The l: 25 scaled numerical models of oil-storage tanks with a capacity of 5 000 m3 are also set up by ANSYS/LS-DYNA software, and their damage processes under the blast impact are numerically simulated. Both the experimental results and the numerical simulations show that the blast loading curve displays a pressure jump instantaneously at the moment of contact with the experimental models, and the overpressure peaks at the stagnation area of the outer surface on the blast side. The yield range first appears at the stagnation area and then propagates to the neighboring parts, and the irregular plastic hinge circle obviously appears around the deformation area, which results in the concaved buckling of the tank inner surface. During the whole process, the inner liquid not only impacts on the structures, but also absorbs and consumes part of the blast energy.展开更多
This paper is aimed at the actual conditions of disaster caused by gas in small and medium-sized coal mines. A new gas concentration monitoring system for coal mines is developed on the basis of gas-sensing detection ...This paper is aimed at the actual conditions of disaster caused by gas in small and medium-sized coal mines. A new gas concentration monitoring system for coal mines is developed on the basis of gas-sensing detection and single-chip control. The monitoring system uses the tin oxide as the main material of N-type semiconductor gas sensors, be- cause it has good sensitive characteristics for the flammable and explosive gas ( such as methane, carbon monoxide). The QM-N5-semiconductor gas sensor is adopted to detect the output values of the resistance under the different gas con- centrations. The system, designedly, takes the AT89C51 digital chip as the core of the circuit processing hardware structure to analyze and judge the input values of the resistance, and then achieve the control and alarm for going beyond the limit of gas concentration. The gas concentration monitoring system has man), advantages including simple in struc- ture, fast response time, stable performance and low cost. Thus, it can be widely used to monitor gas concentration and provide early wamings in small and medium-sized coal mines.展开更多
Abstract: In order to study the flammability and explosion property of gases during the propane oxidation to acrylic acid process, the explosion limits and the safety oxygen content of gases at the recycle gas compre...Abstract: In order to study the flammability and explosion property of gases during the propane oxidation to acrylic acid process, the explosion limits and the safety oxygen content of gases at the recycle gas compressor outlet, the reactor inlet, and the reactor outlet were theoretically calculated and experimentally tested. Finally, the inert limit was also determined. It showed that gases at the recycle gas compressor outlet and the reactor outlet were nonflammable based on three indicators: the explosion limits, the safety oxygen content and the inert limit. The C3H6 and O2 contents were higher at the reactor inlet, which made the mixed gases easily ignitable. However, the large amount of inert gases suppressed the possibility of explo- sion effectively. As a consequence, no explosion phenomenon would happen in all three locations. But gases at the reactor inlet are most dangerous, where more supervision on the concentration of gases and more strict control on the temperature and pressure should be implemented. Besides this, open flame, hot surfaces and other sources of ignition are prohibited in working spaces. The experimental results can be applied to similar process for oxidation of propane.展开更多
The transition from a deflagration to a detonation (DDT) in gas dynamics is investigated through the process of a deflagration with a imite width flame overtaken by a shock. The problem is formulated as a free boundar...The transition from a deflagration to a detonation (DDT) in gas dynamics is investigated through the process of a deflagration with a imite width flame overtaken by a shock. The problem is formulated as a free boundary value problem in an angular domain with a strong detonation and a reflected shock as boundaries. The main difficulty lies in the fact that the strength of reflected shock is zero at the vertex where the shock speed degenerates to be the same as the characteristic speed. The conclusion is that a strong detonation and a retonation (a reflected shock) form locally. Also the entropy satisfaction of this solution is presented.展开更多
基金Projects 706029 supported by the Cultivation Fund of the Key Scientific and Technical Innovation Project of Ministry of Education of China2007AA04Z332 by the National High Technology Research and Development Program of China
文摘Combustible gases in coal mines are composed of methane, hydrogen, some multi-carbon alkane gases and other gases. Based on a numerical calculation, the explosion limits of combustible gases were studied, showing that these limits are related to the concentrations of different components in the mixture. With an increase of C4H10 and C6H14, the Lower ExplosionLimit (LEL) and Upper Explosion-Limit (UEL) of a combustible gas mixture will decrease clearly. For every 0.1% increase in C4H10 and C6H14, the LEL decreases by about 0.19% and the UEL by about 0.3%. The results also prove that, by increasing the amount of H2, the UEL of a combustible gas mixture will increase considerably. If the level of HE increases by 0.1%, the UEL will increase by about 0.3%. However, H2 has only a small effect on the LEL of the combustible gas mixture. Our study provides a theoretical foundation for judging the explosion risk of an explosive gas mixture in mines.
基金Project(10572026) supported by the National Natural Science Foundation of China
文摘A two-dimensional multi-material code was indigenously developed to investigate the effects of duct boundary conditions and ignition positions on the propagation law of explosion wave for hydrogen and methane-based combustible mixture gas. In the code,Young's technique was employed to track the interface between the explosion products and air,and combustible function model was adopted to simulate ignition process. The code was employed to study explosion flow field inside and outside the duct and to obtain peak pressures in different boundary conditions and ignition positions. Numerical results suggest that during the propagation in a duct,for point initiation,the curvature of spherical wave front gradually decreases and evolves into plane wave. Due to the multiple reflections on the duct wall,multi-peak values appear on pressure-time curve,and peak pressure strongly relies on the duct boundary conditions and ignition position. When explosive wave reaches the exit of the duct,explosion products expand outward and forms shock wave in air. Multiple rarefaction waves also occur and propagate upstream along the duct to decrease the pressure in the duct. The results are in agreement with one-dimensional isentropic gas flow theory of the explosion products,and indicate that the ignition model and multi-material interface treatment method are feasible.
基金The National Natural Science Foundation of China(No. 51078115)
文摘In order to investigate the damage and deformation mechanism of large scale steel fixed-roof oil-storage tanks under the combustible gas explosion, a series of explosion experiments of scaled models are conducted. The l: 25 scaled numerical models of oil-storage tanks with a capacity of 5 000 m3 are also set up by ANSYS/LS-DYNA software, and their damage processes under the blast impact are numerically simulated. Both the experimental results and the numerical simulations show that the blast loading curve displays a pressure jump instantaneously at the moment of contact with the experimental models, and the overpressure peaks at the stagnation area of the outer surface on the blast side. The yield range first appears at the stagnation area and then propagates to the neighboring parts, and the irregular plastic hinge circle obviously appears around the deformation area, which results in the concaved buckling of the tank inner surface. During the whole process, the inner liquid not only impacts on the structures, but also absorbs and consumes part of the blast energy.
基金supported by the program of Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Provincethe Hunan Province and Xiangtan City Natural Science Joint Foundation(No.09JJ8005)+1 种基金the Industrial Cultivation Program of Scientific and Technological Achievements in Higher Educational Institutions of Hunan Province(No.10CY008)the Technologies R & D of Hunan Province (No.2010CK3031)
文摘This paper is aimed at the actual conditions of disaster caused by gas in small and medium-sized coal mines. A new gas concentration monitoring system for coal mines is developed on the basis of gas-sensing detection and single-chip control. The monitoring system uses the tin oxide as the main material of N-type semiconductor gas sensors, be- cause it has good sensitive characteristics for the flammable and explosive gas ( such as methane, carbon monoxide). The QM-N5-semiconductor gas sensor is adopted to detect the output values of the resistance under the different gas con- centrations. The system, designedly, takes the AT89C51 digital chip as the core of the circuit processing hardware structure to analyze and judge the input values of the resistance, and then achieve the control and alarm for going beyond the limit of gas concentration. The gas concentration monitoring system has man), advantages including simple in struc- ture, fast response time, stable performance and low cost. Thus, it can be widely used to monitor gas concentration and provide early wamings in small and medium-sized coal mines.
基金financially supported by the National Science and Technology Support Program of China(2012BAK13B01)
文摘Abstract: In order to study the flammability and explosion property of gases during the propane oxidation to acrylic acid process, the explosion limits and the safety oxygen content of gases at the recycle gas compressor outlet, the reactor inlet, and the reactor outlet were theoretically calculated and experimentally tested. Finally, the inert limit was also determined. It showed that gases at the recycle gas compressor outlet and the reactor outlet were nonflammable based on three indicators: the explosion limits, the safety oxygen content and the inert limit. The C3H6 and O2 contents were higher at the reactor inlet, which made the mixed gases easily ignitable. However, the large amount of inert gases suppressed the possibility of explo- sion effectively. As a consequence, no explosion phenomenon would happen in all three locations. But gases at the reactor inlet are most dangerous, where more supervision on the concentration of gases and more strict control on the temperature and pressure should be implemented. Besides this, open flame, hot surfaces and other sources of ignition are prohibited in working spaces. The experimental results can be applied to similar process for oxidation of propane.
基金the Program of Key Laboratory of Military Defenses(No.00JS75.1.1.QT1901).
文摘The transition from a deflagration to a detonation (DDT) in gas dynamics is investigated through the process of a deflagration with a imite width flame overtaken by a shock. The problem is formulated as a free boundary value problem in an angular domain with a strong detonation and a reflected shock as boundaries. The main difficulty lies in the fact that the strength of reflected shock is zero at the vertex where the shock speed degenerates to be the same as the characteristic speed. The conclusion is that a strong detonation and a retonation (a reflected shock) form locally. Also the entropy satisfaction of this solution is presented.