Directional solidification experiments were conducted for Ti-46Al-8Nb alloy at the growth rates ranging from 3 to 70 pards. The microstructure evolution and microsegregation pattern were investigated. In the range of ...Directional solidification experiments were conducted for Ti-46Al-8Nb alloy at the growth rates ranging from 3 to 70 pards. The microstructure evolution and microsegregation pattern were investigated. In the range of growth rate, a regular dendritic structure appears and the primary dendrite spacing decreases with increasing growth rate. The peritectic reaction is observed during the solidification and the final microstructure is composed of α2/γ lamellar structure and retained β（B2） after directional solidification The lamellar orientation is found to be parallel and 45° to the primary growth direction ofβ dendrite. Peritectic reaction leads to significant chemical inhomogeneity, in which aluminum is rich in interdendritic liquid and niobium is rich in the core ofβ dendrite during the solidification. With the nucleation and growth of a phase, the segregation amplitude of niobium increases, which promotes the formation of B2 phase, while aluminum rich in the interdendritic becomes homogeneous gradually.展开更多
通过中间相沥青熔融纺丝、预氧化、炭化及石墨化处理制得了带状中间相沥青基石墨纤维。研究了喷丝孔尺寸和纺丝速率对带状石墨纤维横截面碳层片取向和晶体结构的影响,对用作锂离子电池负极材料的带状石墨纤维的电化学性能进行了测试。...通过中间相沥青熔融纺丝、预氧化、炭化及石墨化处理制得了带状中间相沥青基石墨纤维。研究了喷丝孔尺寸和纺丝速率对带状石墨纤维横截面碳层片取向和晶体结构的影响,对用作锂离子电池负极材料的带状石墨纤维的电化学性能进行了测试。结果表明:喷丝孔尺寸和纺丝速率对石墨纤维碳层片取向具有显著影响。采用低长宽比的喷丝孔在低纺丝速率下制备的石墨纤维其碳层片取向呈类辐射状,此石墨纤维负极材料的倍率性能较好,在0.1C和1C倍率下其放电比容量分别为336和300 m Ah?g^(-1),但其循环稳定性较差,在0.1C倍率下循环100次后容量保持率为89.1%;采用高长宽比的喷丝孔在低纺丝速率下制备的石墨纤维其碳层片呈波浪褶皱状且沿平行纤维主平面取向度高,此石墨纤维负极材料的倍率性能相对较差,但其循环稳定性较好,在0.1C倍率下循环100次后容量保持率为98.8%。随纺丝速率的增加,石墨纤维碳层片整体有序度降低,平行纤维主平面取向的碳层片含量减小,由此导致纤维负极材料的可逆比容量下降。展开更多
基金Projects (50801019,51071062) supported by the National Natural Science Foundation of ChinaProject (2011CB605504) supported by the National Basic Research Program of China
文摘Directional solidification experiments were conducted for Ti-46Al-8Nb alloy at the growth rates ranging from 3 to 70 pards. The microstructure evolution and microsegregation pattern were investigated. In the range of growth rate, a regular dendritic structure appears and the primary dendrite spacing decreases with increasing growth rate. The peritectic reaction is observed during the solidification and the final microstructure is composed of α2/γ lamellar structure and retained β（B2） after directional solidification The lamellar orientation is found to be parallel and 45° to the primary growth direction ofβ dendrite. Peritectic reaction leads to significant chemical inhomogeneity, in which aluminum is rich in interdendritic liquid and niobium is rich in the core ofβ dendrite during the solidification. With the nucleation and growth of a phase, the segregation amplitude of niobium increases, which promotes the formation of B2 phase, while aluminum rich in the interdendritic becomes homogeneous gradually.
文摘通过中间相沥青熔融纺丝、预氧化、炭化及石墨化处理制得了带状中间相沥青基石墨纤维。研究了喷丝孔尺寸和纺丝速率对带状石墨纤维横截面碳层片取向和晶体结构的影响,对用作锂离子电池负极材料的带状石墨纤维的电化学性能进行了测试。结果表明:喷丝孔尺寸和纺丝速率对石墨纤维碳层片取向具有显著影响。采用低长宽比的喷丝孔在低纺丝速率下制备的石墨纤维其碳层片取向呈类辐射状,此石墨纤维负极材料的倍率性能较好,在0.1C和1C倍率下其放电比容量分别为336和300 m Ah?g^(-1),但其循环稳定性较差,在0.1C倍率下循环100次后容量保持率为89.1%;采用高长宽比的喷丝孔在低纺丝速率下制备的石墨纤维其碳层片呈波浪褶皱状且沿平行纤维主平面取向度高,此石墨纤维负极材料的倍率性能相对较差,但其循环稳定性较好,在0.1C倍率下循环100次后容量保持率为98.8%。随纺丝速率的增加,石墨纤维碳层片整体有序度降低,平行纤维主平面取向的碳层片含量减小,由此导致纤维负极材料的可逆比容量下降。
