We present a comparison for the effect of condensation on the morphology and magnetic prop erties of oleic acid modified BaFe_(12)O_(19) nanoparticles.Two different samples of BaFe_(12)O_(19) nanoparticles were synthe...We present a comparison for the effect of condensation on the morphology and magnetic prop erties of oleic acid modified BaFe_(12)O_(19) nanoparticles.Two different samples of BaFe_(12)O_(19) nanoparticles were synthesized by dehydration(Z1) and rotary evaporation(Z2) method,respectively.Oleic acid was used as the surface modification agent to observe the morphological and magnetic changes.The nanoparticles were analyzed by XRD,FTIR,TGA,SEM,and VSM techniques for structural and physicochemical characteris tics.Crystallographic analysis reveals the phase as hexaferrite and the average crystallite size of Z1 and Z2 is 21±3 nm and 17±2 nm,respectively.Rotary evaporator accelerates the condensation process in viscous gel(Z2).Due to the use of rotary evaporator,the coating with oleic acid for Z2 product has been accomplished very well,as compared with Z1.As a result,saturation magnetization of Z2 sample is much lower than that of Z1 sample.展开更多
Multiferroic composites with a large magnetoelectric response are gaining attractive interests for the design of magnetoelectric(ME)functional devices.In this work,the particulate ME composites(Ba_(0.85)Ca_(0.15))(Zr_...Multiferroic composites with a large magnetoelectric response are gaining attractive interests for the design of magnetoelectric(ME)functional devices.In this work,the particulate ME composites(Ba_(0.85)Ca_(0.15))(Zr_(0.1)Ti_(0.9))O_(3)-xBaFe_(12)O_(19)(x=0,0.1,0.2,0.3,0.4 and 1)were prepared,and their structural,dielectric,magnetic,ferroelectric,piezoelectric properties and magnetoelectric coupling were systematically investigated.The composites consisted of only two chemically separated phases with well-bonded interface.Dielectric and impedance analyses indicated the co-contribution of grain and grain boundary to polarization.Well-saturated ferroelectric and magnetic hysteresis loops demonstrated multiferroic nature.ME response was investigated elaborately by employing magnetically induced polarization,together with measuring ME voltage coefficient and magnetodielectric value.Specifically,a large ME coefficient of 26.78 mV/cm·Oe was achieved for x=0.3,which is higher than that in single-phase BaFe_(12)O_(19)and its coupled composites.展开更多
基金the Fatih University,Research Pro ject Foundation (Contract No:P50020902-2)Turkish Ministry of Industry and TUBITAK (Contract No:110T487) for financial support of this study
文摘We present a comparison for the effect of condensation on the morphology and magnetic prop erties of oleic acid modified BaFe_(12)O_(19) nanoparticles.Two different samples of BaFe_(12)O_(19) nanoparticles were synthesized by dehydration(Z1) and rotary evaporation(Z2) method,respectively.Oleic acid was used as the surface modification agent to observe the morphological and magnetic changes.The nanoparticles were analyzed by XRD,FTIR,TGA,SEM,and VSM techniques for structural and physicochemical characteris tics.Crystallographic analysis reveals the phase as hexaferrite and the average crystallite size of Z1 and Z2 is 21±3 nm and 17±2 nm,respectively.Rotary evaporator accelerates the condensation process in viscous gel(Z2).Due to the use of rotary evaporator,the coating with oleic acid for Z2 product has been accomplished very well,as compared with Z1.As a result,saturation magnetization of Z2 sample is much lower than that of Z1 sample.
基金financially supported by the National Key Research and Development Program of China(2017YFA0204600)the National Natural Science Foundation of China(51902104).
文摘Multiferroic composites with a large magnetoelectric response are gaining attractive interests for the design of magnetoelectric(ME)functional devices.In this work,the particulate ME composites(Ba_(0.85)Ca_(0.15))(Zr_(0.1)Ti_(0.9))O_(3)-xBaFe_(12)O_(19)(x=0,0.1,0.2,0.3,0.4 and 1)were prepared,and their structural,dielectric,magnetic,ferroelectric,piezoelectric properties and magnetoelectric coupling were systematically investigated.The composites consisted of only two chemically separated phases with well-bonded interface.Dielectric and impedance analyses indicated the co-contribution of grain and grain boundary to polarization.Well-saturated ferroelectric and magnetic hysteresis loops demonstrated multiferroic nature.ME response was investigated elaborately by employing magnetically induced polarization,together with measuring ME voltage coefficient and magnetodielectric value.Specifically,a large ME coefficient of 26.78 mV/cm·Oe was achieved for x=0.3,which is higher than that in single-phase BaFe_(12)O_(19)and its coupled composites.
