Two new coordination polymers,[Ni(Hpdc)(bib)(H_(2)O)]_(n)(1)and{[Ni(bib)_(3)](ClO_(4))_(2)}_(n)(2),were prepared by mixing Ni^(2+),3,5⁃pyrazoledicarboxylic acid(H3pdc)/p⁃nitrobenzoic acid and 1,4⁃bis(imidazol⁃1⁃ylmeth...Two new coordination polymers,[Ni(Hpdc)(bib)(H_(2)O)]_(n)(1)and{[Ni(bib)_(3)](ClO_(4))_(2)}_(n)(2),were prepared by mixing Ni^(2+),3,5⁃pyrazoledicarboxylic acid(H3pdc)/p⁃nitrobenzoic acid and 1,4⁃bis(imidazol⁃1⁃ylmethyl)butane(bib)by a hydrothermal method,respectively.X⁃ray crystallography reveals a 2D network constructed by six⁃coordinated Ni(Ⅱ)centers,bib,and Hpdc2-ligands in complex 1,while a 2D network is built by Ni(Ⅱ)and bib ligands in 2.Furthermore,the quantum⁃chemical calculations have been performed on‘molecular fragments’extracted from the crystal structure of 1 using the PBE0/LANL2DZ method in Gaussian 16 and the VASP program.CCDC:2343794,1;2343798,2.展开更多
In recent years, China's energy demand and Greenhouse gas (GHG) emissions have grown very fast, quite an amount of which was exported as energy embodied in goods in international trade rather than consumed domesti...In recent years, China's energy demand and Greenhouse gas (GHG) emissions have grown very fast, quite an amount of which was exported as energy embodied in goods in international trade rather than consumed domestically. Starting from the concept of embodied energy, based on input-output energy analysis approach, in this paper the energy embodied in goods in international trade of China during the period from 2001 to 2006 is calculated. The results show that although China has become a net importer of petroleum since 1993, China is a net exporter of embodied energy due to international trade in goods. In 2002, the total amount of energy embodied in exported goods was about 410 million tce (ton of coal equivalent, hereinafter referred to as "tce"). Eliminating the amount of energy embodied in imported goods of about 170 million tce, the net export of embodied energy was about 240 million tce, accounting for 16% of the aggregate primary energy consumption of that very year in China, and the net export of embodied emissions was about 150 million tons of carbon. With the rapid growth of China's international trade, assuming no structural input-output changes of among sectors, in 2006 the net export of embodied energy went up to about 630 million tce, an increase of 162 % over 2002. In addition, this paper also analyzes the possible sources of error in calculation, and also discusses the policy implications according to the result of the calculation.展开更多
Equilibrium photoproduct of 7r-cyclopentadienyliron dicarbonyl dimer [CpFe(CO)2]2 in non- polar solvent carbon tetrachloride (CC14) is investigated using time-resolved 2D IR spec- troscopy. One of the several poss...Equilibrium photoproduct of 7r-cyclopentadienyliron dicarbonyl dimer [CpFe(CO)2]2 in non- polar solvent carbon tetrachloride (CC14) is investigated using time-resolved 2D IR spec- troscopy. One of the several possible visible-light-driven photoreaction pathways is confirmed and the product is found to contain a di-carbonyl group that exhibits quantum beating be- tween two equivalent transitions in time-resolved 2D IR spectra, which turns out to be the anti-symmetric and symmetric stretching of the terminal carbonyl stretching modes of CpFe(CO)2C1. This is the main product and its reaction pathway involves radical formation, followed by chloride addition. Quantum-chemistry computations support these experimental results. Our results indicate that 2D IR method can be used to identify in situ structures and dynamics of chemical species involved in condensed-phase chemical reactions.展开更多
Nowadays, lighting design is the modern attractive field of professional activity. Although its theoretical and methodological bases are in the initial stage of formulation. Though there are standards for regulating i...Nowadays, lighting design is the modern attractive field of professional activity. Although its theoretical and methodological bases are in the initial stage of formulation. Though there are standards for regulating illumination quantitatively, the science has never created a bridge to transfer illumination quantity into illumination quality. How to keep a day image of architectural object without imitating natural lighting? How unrecognizably to change the image, to make it extraordinary and catchy? This paper offers a solution in the form of external illumination designing principles. This paper proposes two conceptual ways of creating artificial lighting of buildings and constructions that pursue different goals: the principle of "tectonic" illumination and the principle of "decorative" illumination. These principles were developed based on the analysis of the state of the art experience of lighting architectural objects and author's empirical study. The latter contained measuring luminosity with luminance meter, processing the data, statistical survey (180 respondents) and lighting modeling in the laboratory of Moscow Architectural Institute.展开更多
This paper presents the methodology and results of modelling of Earth magnetic field disturbances induced by ferromagnetic objects. The modeling was carried out using the finite elements calculations, and the results ...This paper presents the methodology and results of modelling of Earth magnetic field disturbances induced by ferromagnetic objects. The modeling was carried out using the finite elements calculations, and the results were compared with the measurements. The special test stand, consisting of magnetovision scanner and Helmholtz coils, has been used. The measurement system is able to measure the distribution of planar magnetic induction vectors, and to differentiate the sources of measured disturbances.展开更多
Extraction of moving objects is an important and fundamental research topic for many video applications. This paper addresses an unsupervised spatio-temporal segmentation scheme to extract moving objects from video se...Extraction of moving objects is an important and fundamental research topic for many video applications. This paper addresses an unsupervised spatio-temporal segmentation scheme to extract moving objects from video sequences.The temporal segmentation localizes moving objects by comparing the motion vector of each block in each frame with the corresponding global motion vector estimated by an outlier rejection(OR) based method.Furthermore,the temporal compensation utilizing the temporal coherence of moving objects is considered in the temporal segmentation to solve the temporarily stopping problem.The detected moving regions usually have discontinuous boundaries and some holes.These regions are then compensated in the spatial domain. In the spatial segmentation,the watershed algorithm considering the global information improves the accuracy of segmentation in the spatial domain.The modified mean filter is presented to suppress some minima.By using a fusion module,moving objects are extracted.Experiments on various sequences have successfully demonstrated the validity of the proposed scheme.展开更多
A novel method applying simple, rapid, effective and inexpensive excitation-emission matrix (EEM) fluorescence spectroscopy coupled with second-order calibration method for simultaneous determination of ethoxyquin ...A novel method applying simple, rapid, effective and inexpensive excitation-emission matrix (EEM) fluorescence spectroscopy coupled with second-order calibration method for simultaneous determination of ethoxyquin (EQ) and tert-butylhydroquinone (TBHQ) contents in biological fluid samples was developed. After a simple data preprocessing that was to insert zeros below the first-order Rayleigh scattering, the second-order calibration method based on the alternating normalization-weighed error (ANWE) algorithm was used to deal with EEM data. Via the introduced "second-order advantage", the individual con- centrations of the analytes of interest could be obtained even in the presence of uncalibrated interferences. The experimental concentration ranges for the analytes were as follows: EQ, from 4.58 to 20.6 p.g mL-1 in plasma and from 6.87 to 20.6 gg mL-1 in urine; TBHQ, from 4.49 to 20.2 ~tg mL-1 in plasma and from 6.73 to 22.4 I.tg mL-l in urine. The recoveries from spiked bi- ological fluid samples were in the ranges of 92.8%-106.2% for EQ and 94.6%-107.2% for TBHQ. These results demonstrate that the three-dimensional EEM fluorescence with second-order calibration method is a powerful tool for obtaining both EQ and TBHQ quantitative results in plasma and urine samples, and could be applied to more complex matrices.展开更多
文摘Two new coordination polymers,[Ni(Hpdc)(bib)(H_(2)O)]_(n)(1)and{[Ni(bib)_(3)](ClO_(4))_(2)}_(n)(2),were prepared by mixing Ni^(2+),3,5⁃pyrazoledicarboxylic acid(H3pdc)/p⁃nitrobenzoic acid and 1,4⁃bis(imidazol⁃1⁃ylmethyl)butane(bib)by a hydrothermal method,respectively.X⁃ray crystallography reveals a 2D network constructed by six⁃coordinated Ni(Ⅱ)centers,bib,and Hpdc2-ligands in complex 1,while a 2D network is built by Ni(Ⅱ)and bib ligands in 2.Furthermore,the quantum⁃chemical calculations have been performed on‘molecular fragments’extracted from the crystal structure of 1 using the PBE0/LANL2DZ method in Gaussian 16 and the VASP program.CCDC:2343794,1;2343798,2.
基金sponsored by China Office of World Wide Fund for Nature(WWF)(No.:CN01010123514)
文摘In recent years, China's energy demand and Greenhouse gas (GHG) emissions have grown very fast, quite an amount of which was exported as energy embodied in goods in international trade rather than consumed domestically. Starting from the concept of embodied energy, based on input-output energy analysis approach, in this paper the energy embodied in goods in international trade of China during the period from 2001 to 2006 is calculated. The results show that although China has become a net importer of petroleum since 1993, China is a net exporter of embodied energy due to international trade in goods. In 2002, the total amount of energy embodied in exported goods was about 410 million tce (ton of coal equivalent, hereinafter referred to as "tce"). Eliminating the amount of energy embodied in imported goods of about 170 million tce, the net export of embodied energy was about 240 million tce, accounting for 16% of the aggregate primary energy consumption of that very year in China, and the net export of embodied emissions was about 150 million tons of carbon. With the rapid growth of China's international trade, assuming no structural input-output changes of among sectors, in 2006 the net export of embodied energy went up to about 630 million tce, an increase of 162 % over 2002. In addition, this paper also analyzes the possible sources of error in calculation, and also discusses the policy implications according to the result of the calculation.
文摘Equilibrium photoproduct of 7r-cyclopentadienyliron dicarbonyl dimer [CpFe(CO)2]2 in non- polar solvent carbon tetrachloride (CC14) is investigated using time-resolved 2D IR spec- troscopy. One of the several possible visible-light-driven photoreaction pathways is confirmed and the product is found to contain a di-carbonyl group that exhibits quantum beating be- tween two equivalent transitions in time-resolved 2D IR spectra, which turns out to be the anti-symmetric and symmetric stretching of the terminal carbonyl stretching modes of CpFe(CO)2C1. This is the main product and its reaction pathway involves radical formation, followed by chloride addition. Quantum-chemistry computations support these experimental results. Our results indicate that 2D IR method can be used to identify in situ structures and dynamics of chemical species involved in condensed-phase chemical reactions.
文摘Nowadays, lighting design is the modern attractive field of professional activity. Although its theoretical and methodological bases are in the initial stage of formulation. Though there are standards for regulating illumination quantitatively, the science has never created a bridge to transfer illumination quantity into illumination quality. How to keep a day image of architectural object without imitating natural lighting? How unrecognizably to change the image, to make it extraordinary and catchy? This paper offers a solution in the form of external illumination designing principles. This paper proposes two conceptual ways of creating artificial lighting of buildings and constructions that pursue different goals: the principle of "tectonic" illumination and the principle of "decorative" illumination. These principles were developed based on the analysis of the state of the art experience of lighting architectural objects and author's empirical study. The latter contained measuring luminosity with luminance meter, processing the data, statistical survey (180 respondents) and lighting modeling in the laboratory of Moscow Architectural Institute.
文摘This paper presents the methodology and results of modelling of Earth magnetic field disturbances induced by ferromagnetic objects. The modeling was carried out using the finite elements calculations, and the results were compared with the measurements. The special test stand, consisting of magnetovision scanner and Helmholtz coils, has been used. The measurement system is able to measure the distribution of planar magnetic induction vectors, and to differentiate the sources of measured disturbances.
基金the National Natural Science Foundationof China(No.60502034)
文摘Extraction of moving objects is an important and fundamental research topic for many video applications. This paper addresses an unsupervised spatio-temporal segmentation scheme to extract moving objects from video sequences.The temporal segmentation localizes moving objects by comparing the motion vector of each block in each frame with the corresponding global motion vector estimated by an outlier rejection(OR) based method.Furthermore,the temporal compensation utilizing the temporal coherence of moving objects is considered in the temporal segmentation to solve the temporarily stopping problem.The detected moving regions usually have discontinuous boundaries and some holes.These regions are then compensated in the spatial domain. In the spatial segmentation,the watershed algorithm considering the global information improves the accuracy of segmentation in the spatial domain.The modified mean filter is presented to suppress some minima.By using a fusion module,moving objects are extracted.Experiments on various sequences have successfully demonstrated the validity of the proposed scheme.
基金the National Natural Science Foundation of China (21175041)the National Basic Research Program(2012CB910602) for financial support
文摘A novel method applying simple, rapid, effective and inexpensive excitation-emission matrix (EEM) fluorescence spectroscopy coupled with second-order calibration method for simultaneous determination of ethoxyquin (EQ) and tert-butylhydroquinone (TBHQ) contents in biological fluid samples was developed. After a simple data preprocessing that was to insert zeros below the first-order Rayleigh scattering, the second-order calibration method based on the alternating normalization-weighed error (ANWE) algorithm was used to deal with EEM data. Via the introduced "second-order advantage", the individual con- centrations of the analytes of interest could be obtained even in the presence of uncalibrated interferences. The experimental concentration ranges for the analytes were as follows: EQ, from 4.58 to 20.6 p.g mL-1 in plasma and from 6.87 to 20.6 gg mL-1 in urine; TBHQ, from 4.49 to 20.2 ~tg mL-1 in plasma and from 6.73 to 22.4 I.tg mL-l in urine. The recoveries from spiked bi- ological fluid samples were in the ranges of 92.8%-106.2% for EQ and 94.6%-107.2% for TBHQ. These results demonstrate that the three-dimensional EEM fluorescence with second-order calibration method is a powerful tool for obtaining both EQ and TBHQ quantitative results in plasma and urine samples, and could be applied to more complex matrices.