Thermogravimetric study of rubber compositions （operating glove and catheter） in medical waste was carried out using the thermogravimetric analyser （TGA）,at the heating rate of 20 ℃/min in a stream of N2.The resu...Thermogravimetric study of rubber compositions （operating glove and catheter） in medical waste was carried out using the thermogravimetric analyser （TGA）,at the heating rate of 20 ℃/min in a stream of N2.The results indicate that the decomposition process of operating glove appears an obvious mass loss stage at 250-485 ℃,while catheter has two obvious stages at 240-510 ℃ and 655-800 ℃,respectively; both samples present endothermic pyrolysis reaction; the decomposition of operating glove and the first mass loss stage of catheter are in agreement with natural rubber pyrolysis; the second mass loss stage of catheter corresponds to CaCO3 decomposition.Based on the experimental results,a novel two-step four-reaction model was established to simulate the whole continuous processes,which could more satisfactorily describe and predict the pyrolysis processes of rubber compositions,being more mechanistic and conveniently serving for the engineering.展开更多
The analysis on the traditional asymmetric Mach-Zehnder interferometer (AMZI) optical filter based on two 3 dB directional couplers (DCs) shows that by adding an additional nonlinear phase generated by phase-generatin...The analysis on the traditional asymmetric Mach-Zehnder interferometer (AMZI) optical filter based on two 3 dB directional couplers (DCs) shows that by adding an additional nonlinear phase generated by phase-generating coupler (PGC) to the original phase difference of the AMZI, its non-periodic frequency response can be modified, and a strictly periodic spectrum can be obtained. A novel structure of the AMZI filter using two PGCs before and after the AMZI region is proposed. With the needed free spectrum range (FSR) of 20 nm, the design and optimization of the device are performed using polymer SU-8 as the core and PMMA-GMA as the buffer. Though the insertion loss (IL) gets larger than that of the traditional AMZI filter, the FSR is nearly uniform as the expected period of 20 nm.展开更多
基金Project(50378062)supported by the National Natural Science Foundation of ChinaProject(09JCYBJC08100)supported by the Natural Science Foundation of Tianjin Municipality,ChinaProject supported by Key Laboratory Program of the Ministry of Education,China
文摘Thermogravimetric study of rubber compositions （operating glove and catheter） in medical waste was carried out using the thermogravimetric analyser （TGA）,at the heating rate of 20 ℃/min in a stream of N2.The results indicate that the decomposition process of operating glove appears an obvious mass loss stage at 250-485 ℃,while catheter has two obvious stages at 240-510 ℃ and 655-800 ℃,respectively; both samples present endothermic pyrolysis reaction; the decomposition of operating glove and the first mass loss stage of catheter are in agreement with natural rubber pyrolysis; the second mass loss stage of catheter corresponds to CaCO3 decomposition.Based on the experimental results,a novel two-step four-reaction model was established to simulate the whole continuous processes,which could more satisfactorily describe and predict the pyrolysis processes of rubber compositions,being more mechanistic and conveniently serving for the engineering.
基金supported by the National Natural Science Foundation of China (Nos.61107021, 61177027, 61077041 and 60807029)the Ministry of Education of China (Nos.20110061120052 and 20090061110041)+1 种基金the China Postdoctoral Science Foundation Funded Project (No.20110491299)the Special Funds of Basic Science and Technology of Jilin University (Nos.201103076 and 200905005)
文摘The analysis on the traditional asymmetric Mach-Zehnder interferometer (AMZI) optical filter based on two 3 dB directional couplers (DCs) shows that by adding an additional nonlinear phase generated by phase-generating coupler (PGC) to the original phase difference of the AMZI, its non-periodic frequency response can be modified, and a strictly periodic spectrum can be obtained. A novel structure of the AMZI filter using two PGCs before and after the AMZI region is proposed. With the needed free spectrum range (FSR) of 20 nm, the design and optimization of the device are performed using polymer SU-8 as the core and PMMA-GMA as the buffer. Though the insertion loss (IL) gets larger than that of the traditional AMZI filter, the FSR is nearly uniform as the expected period of 20 nm.
