In areas with a high geological background of heavy metals,some edible plants could pose a serious threat to human health.In order to find effective methods to remove heavy metals or reduce their harm,this study inves...In areas with a high geological background of heavy metals,some edible plants could pose a serious threat to human health.In order to find effective methods to remove heavy metals or reduce their harm,this study investigated the enrichment conditions of five soil heavy metals,Cd,Pb,Cu,Zn and Cr,in four edible plants in a mining area,Baoshantao,in eastern China that has a high geological background of metals,and two groups of experiments were designed to investigate the effects of passivators on their enrichment.The results showed that the soil heavy metal content in the study area has a certain degree of spatial variability.The five heavy metal element contaminants in the soil are in the order of Cd>Cu>Zn>Pb>Cr.The enrichment coefficients and the transfer coefficients of different edible plants were different for the different heavy metals.The two groups of passivators showed better passivating effects with an increase in passivating agent dosage.The smaller the enrichment coefficient of water spinach,the lower the bioavailability.The results of this study can provide a scientific basis for the restoration of soil heavy metal pollution and the safe use of land in areas with a high geological background of heavy metals.展开更多
Though several theoretical models have been proposed to design electronic flat-bands, the definite experimental realization in two-dimensional atomic crystal is still lacking. Here we propose a novel and realistic fla...Though several theoretical models have been proposed to design electronic flat-bands, the definite experimental realization in two-dimensional atomic crystal is still lacking. Here we propose a novel and realistic flat-band model based on threefold degenerate p-orbitals in two-dimensional ionic materials. Our theoretical analysis and first-principles calculations show that the proposed flat-band can be realized in 1 T layered materials of alkali-metal chalogenides and metal-carbon group compounds. Some of the former are theoretically predicted to be stable as layered materials(e.g., K2 S), and some of the latter have been experimentally fabricated in previous works(e.g., Gd2 CCl2). More interestingly, the flat-band is partially filled in the heterostructure of a K2 S monolayer and graphene layers. The spin polarized nearly flatband can be realized in the ferromagnetic state of a Gd2 CCl2 monolayer, which has been fabricated in experiments. Our theoretical model together with the material predictions provide a realistic platform for the study of flat-bands and related exotic quantum phases.展开更多
基金The National Natural Science Foundation of China(42371185)The Anhui Normal University College Students Innovation and EntrepreneurshipTraining Program(2022056511).
文摘In areas with a high geological background of heavy metals,some edible plants could pose a serious threat to human health.In order to find effective methods to remove heavy metals or reduce their harm,this study investigated the enrichment conditions of five soil heavy metals,Cd,Pb,Cu,Zn and Cr,in four edible plants in a mining area,Baoshantao,in eastern China that has a high geological background of metals,and two groups of experiments were designed to investigate the effects of passivators on their enrichment.The results showed that the soil heavy metal content in the study area has a certain degree of spatial variability.The five heavy metal element contaminants in the soil are in the order of Cd>Cu>Zn>Pb>Cr.The enrichment coefficients and the transfer coefficients of different edible plants were different for the different heavy metals.The two groups of passivators showed better passivating effects with an increase in passivating agent dosage.The smaller the enrichment coefficient of water spinach,the lower the bioavailability.The results of this study can provide a scientific basis for the restoration of soil heavy metal pollution and the safe use of land in areas with a high geological background of heavy metals.
基金supported by the National Basic Research Program of China(2015CB921102 and 2019YFA0308403)the National Natural Science Foundation of China(11674028 and11822407)+1 种基金the Strategic Priority Research Program of Chinese Academy of Sciences(XDB28000000)China Postdoctoral Science Foundation(2020M670011)。
文摘Though several theoretical models have been proposed to design electronic flat-bands, the definite experimental realization in two-dimensional atomic crystal is still lacking. Here we propose a novel and realistic flat-band model based on threefold degenerate p-orbitals in two-dimensional ionic materials. Our theoretical analysis and first-principles calculations show that the proposed flat-band can be realized in 1 T layered materials of alkali-metal chalogenides and metal-carbon group compounds. Some of the former are theoretically predicted to be stable as layered materials(e.g., K2 S), and some of the latter have been experimentally fabricated in previous works(e.g., Gd2 CCl2). More interestingly, the flat-band is partially filled in the heterostructure of a K2 S monolayer and graphene layers. The spin polarized nearly flatband can be realized in the ferromagnetic state of a Gd2 CCl2 monolayer, which has been fabricated in experiments. Our theoretical model together with the material predictions provide a realistic platform for the study of flat-bands and related exotic quantum phases.
