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东营凹陷古近系升藿烷生物标志物参数分布及演变规律 被引量:10
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作者 陈中红 查明 +1 位作者 金强 任拥军 《沉积学报》 CAS CSCD 北大核心 2011年第1期173-183,共11页
为研究实际地质体或地质剖面中的C31到C3517α(H),21β(H)升藿烷生物标志物构型转化参数22S/(22S+22R)及升藿烷指数C35/∑(C31—C35)等的分布、演化特征,对东营凹陷主要烃源岩层系古近系沙河街组三段(淡水—微咸水层系)和沙河街组四段(... 为研究实际地质体或地质剖面中的C31到C3517α(H),21β(H)升藿烷生物标志物构型转化参数22S/(22S+22R)及升藿烷指数C35/∑(C31—C35)等的分布、演化特征,对东营凹陷主要烃源岩层系古近系沙河街组三段(淡水—微咸水层系)和沙河街组四段(咸水层系)的系列样品进行了研究,分析样品来源于1 300~4 000的暗色泥岩,其中2 800~4 000 m的样品对应于东营凹陷古近系烃源岩的生油初期到生油晚期。研究结果表明,C31、C32、C33、C34、C35升藿烷(17α(H),21β(H))构型转化参数的分布除与异构体之间的手性碳立体构型转化作用有关外,不同异构体之间降解或裂解速率和新生成速率的差异也是其主要控制因素,沉积环境(如高盐环境)也在一定程度上影响了其分布;从未熟—低熟状态到成熟状态,相关升藿烷构型转化参数22S/(22S+22R)总体均表现出随埋藏深度增大而加大的特点,并从离散状态聚集到热演化的平衡状态附近;在到达成熟状态后,相关升藿烷的构型转化参数22S/(22S+22R)从缓慢增大过渡到一个持续的热演化平衡状态,并且该构型转化参数的热演化平衡状态对应于生油门限附近;在高盐环境中除C33升藿烷保持不变的热演化平衡状态外,其它升藿烷均呈现不同幅度的逆转特征,表明高含量的盐类矿物对升藿烷成熟度参数亦具有抑制作用或迟缓效应;C31、C32、C33、C34、C3517α升藿烷之间的22S/(22S+22R)分布型式复杂多变,其中对于成熟源岩样品,C35升藿烷22S/(22S+22R)值变化强烈,表现出"翘尾"状的上升型特征和"坠尾"状的下降型特征,而对于低熟—未熟样品,C32升藿烷的22S/(22S+22R)显示相对高值,并且多数样品显示为C31<C32>C33<C34>C35的偶数碳优势的特征;研究显示C31到C33升藿烷的构型转化参数S/(S+R)热演化平衡值均为0.6,而C34S/(S+R)及C35S/(S+R)热演化平衡值相对较高,沙三段、沙四段的C34 S/(S+R)及沙四段的C35 S/(S+R)分别达到0.63、0.62、0.65;升藿烷指数C35/∑(C31—C35)受热演化影响也比较明显,在生油期间随着埋藏深度增加而减小,在高盐环境中表现出相对高值,研究表明该指数的变化与其22R异构体演化有关,并且参数C31/∑(C31—C35)、C32/∑(C31—C35)、C33/∑(C31—C35)、C34/∑(C31—C35)、C35/∑(C31—C35)演化特征截然不同。 展开更多
关键词 升藿烷 构型转化参数 标志 物湖相源岩 东营凹陷
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Geobiological processes of the formation of lacustrine source rock in Paleogene 被引量:12
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作者 LI GuoShan WANG YongBiao +4 位作者 LU ZongSheng LIAO Wei SONG GuoQi WANG XueJun XU XingYou 《Science China Earth Sciences》 SCIE EI CAS 2014年第5期976-987,共12页
Gypsum-salt rocks and coccolith calcareous shale are widely deposited in the lower part of the Paleogene Shahejie Formation in the Dongying Sag, Sbandong Province. The gypsum-salt rock is believed to be formed during ... Gypsum-salt rocks and coccolith calcareous shale are widely deposited in the lower part of the Paleogene Shahejie Formation in the Dongying Sag, Sbandong Province. The gypsum-salt rock is believed to be formed during the earlier deposition in salt lake, while the overlying coccolith shale in saline lake with relatively low salinity. By comparing the lake environment and la- custrine microbial communities between ancient and recent lakes, cyanobacteria are regarded as the main representative of productivity during the formation of gypsum-salt strata series, with the annual productivity of 1500-2000 gC m-2 yr1. Based on the research of ultramicrofossils in the calcareous shale, coccolith is considered as the main contributor to the productivity during the formation of calcareous shale. On the basis of statistic data of sedimentary rates, shale laminations, and coccolith fossils in each lamination, the quantitative value of productivity is calculated, with the annual productivity of 2250 3810 gC m 2 yr-1 (averagely 3120 gC m-2 yr-1). Statistic data of large amount of pyrite framboids indicate that the lower water col- umn was persistently in sulfidic or anoxic conditions during the deposition of gypsum-salt strata series, but it changed to be dysoxic when the coccolith calcareous shale was deposited. Both of these water conditions are favorable for the preservation of organic matter. It is estimated that the organic carbon burial efficiency of the Lower Paleogene salt lakes and saline lakes of Dongying Depression is about 10%-15%, which is calculated and analyzed using the multi-parameter geobiological model. 展开更多
关键词 source rock GEOBIOLOGY paleo-oxygenation facies PALEOGENE Dongying Sag
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