水泥土搅拌法加固冲填土软土地基的微观试验

针对某工程冲填土软土地基水泥土搅拌法处理过程中的冲填土与自然软土加固效果差异问题,从化学成分与物理结构等微观角度出发,分别对冲填土和自然软土的原状样、加固样进行了X射线衍射试验和扫描电镜试验两种微结构试验,对比分析了导致这种加固效果差异的微观机理及其形成原因.研究发现,物理微结构对冲填土软土地基的水泥土搅拌法加固效果存在重要的影响.虽然水泥土搅拌法加固冲填土与自然软土的化学反应是类似的,但加固后的土体在物理微结构特征上却差异显著,并导致加固土体宏观强度表现上的不同.因此,应采取相应的施工措施,改良冲填土的微观结构特征,优化地基加固效果.

南京大学微结构物理研究创新群体情况简介

1.基本情况 南京大学微结构物理研究创新群体主要依托于南京大学固体微结构物理国家重点实验室。该实验室是1984年首批建设的重点实验室之一,主要从事固体微结构研究,历经几代人的艰苦努力,取得了可喜的成果,在国内外有重要影响。在该实验室发展的过程中,逐渐形成了一个以年轻人为群体的新一代研究核心组。主要学术带头人有王牧教授、王伟教授和王惠田教授等。他们都曾在国内外取得相关的专业博士学位,其中3位是教育部长江学者计划特聘教授,5位获得杰出青年基金,35岁以下研究人员9位。

Effect of heat treatment on microstructure and tensile strength of NiCoCrAl alloy sheet fabricated by EB-PVD

The NiCoCrAl alloy sheet was fabricated by electron beam physical vapor deposition technique and the effects of the heat treatment on the microstructure and tensile strength of the NiCoCrAl alloy sheet were investigated. The heat treatment at 1050 °C is favorable to improve the interface bonding between the columnar structures due to the disappearance of the intergranular gaps. Comparing with the thin NiCoCrAl alloy sheet before heat treatment, the Ni3Al phase appears in the NiCoCrAl alloy sheet after heat treatment, which is favorable to improve the interface bonding between the columnar structures. The increase in the tensile strength and elongation is attributed to the improvement of the interface bonding between the columnar structures. The residual stress in the NiCoCrAl alloy sheet after heat treatment is reduced significantly, which also confirms that the interface bonding is improved by the heat treatment.

Impacts of Secondary Aerosols on a Persistent Fog Event in Northern China

The chemistry version of the Weather Re- search and Forecasting model （WRF/Chem） was coupled with the anthropogenic emission inventory of David Streets to investigate the impacts of secondary aerosols on a persistent fog event from 25 to 26 October 2007, in Northem China. The spatial distribution of the simulated fog is consistent with satellite observations, and the time-height distributions of the simulated boundary layer where the fog formed are also in good agreement with these observations. The sensitivity studies show that the secondary aerosols of SO4, NO3, and NH4 formed from gaseous precursors of SO2, NOx, and NH3 had substantial impacts on the formation processes and microphysical structure of the fog event. The decrease of the secondary aerosols obviously reduced the liquid water path and column droplet number concentration of the fog below the 1-km layer, and the corresponding area-averaged liquid water path and droplet number concentration of the fog decreased by 43% and 79%, respectively. The concentra- tions of NOx and NO3 were found to be extremely high in this case. The concentration of interstitial aerosol NO3 was much higher than the SO4 and NH4, but the concentration of SO4 was highest in the cloud-borne aerosols. The average activation ratios for SO4, NO3, and NH4 were 34%, 31%, and 30%, respectively, and the maximum ra- tios reached 62%, 86%, and 55% during the fog episode.

Physical simulation of hot deformation of TiAl based alloy

In order to establish a model between the grain size and the process parameters, the hot deformation behaviors of Ti 49.5Al alloy was investigated by isothermal compressive tests at temperatures ranging from 800 to 1?100 ℃ with strain rates of 10 -3 10 -1 s -1 . Within this range, the deformation behavior obeys the power law relationship, which can be described using the kinetic rate equation. The stress exponent, n , has a value of about 5.0, and the apparent activation energy is about 320 J/mol, which fits well with the value estimated in previous investigations. The results show that, the dependence of flow stress on the recrystallized grain size can be expressed by the equation: σ=K 1d rex -0 56 . The relationship between the deformed microstructure and the process control parameter can be expressed by the formula: lg d rex =-0 281?1gZ +3 908?1.

Cloud vertical structures associated with precipitation magnitudes over the Tibetan Plateau and its neighboring regions

Cloud vertical structures and precipitation over the Tibetan Plateau （TP） are analyzed and compared with its neighboring land and tropical oceans based on CloudSat/CALIPSO satellite measurements and TRMM precipitation data. Results show that the TP generally has a compression effect on cloud systems, as manifested by a shrinking cloud depth and lowering cloud top. Precipitation is weaker over the TP than its neighboring regions and exhibits large seasonal variations. In summer, cloud ice particles over the TP are mostly located at lower altitude （5-10 km）, with a larger variability of sizes and aggregation （particle number concentration） under no-rain conditions compared to other regions. Ice water content becomes abundant and the number concentration tends to be dense at higher altitudes when precipitation is enhanced. However, even for heavy rainstorms, the aggregation is most likely between 100 and 250 L-1, whereas it can reach as high as 500 L-1 over its neighboring land and tropical oceans. Given the same magnitude of precipitation, the spectrum of ice particle sizes is found to be wider over the TP than other regions.

Wastewater treatment performance and microbial community structure in the constructed wetland under double-pressure of low temperature and Ag NPs exposure

To investigate the effects of silver nanoparticles(Ag NPs)and low temperature double-pressure on the wastewater treatment efficacy and the microbial community structure of constructed wetlands,a pilot-scale vertical flow constructed wetland was set up to treat synthetic wastewater under laboratory conditions.By measuring the effluent concentration of ammonia nitrogen(NH_(4)^(+)-N),total nitrogen(TN),total phosphorus(TP),chemical oxygen demand(COD),and the diversity,richness,and community structure of microorganisms of the upper and lower soil layers in the wetland,the nutrient removal effect of the constructed wetland and the changes in the microflora of the soil layer were studied.The results reveal that the correlation coefficients between the removal rates of TN and NH_(4)^(+)-N and the temperature are 0.463 and 0.692,respectively,indicating a significant positive correlation.From the warm to the cold season,both the diversity and richness of microorganisms in the lower soil layer of wetlands are inhibited under the double-pressure of Ag NPs and low temperature,and the abundances of the denitrogenation functional bacteria such as Candidatus nitrososphaera,Sulfuritalea,Anaeromyxobacter,Candidatus solibacter,Nitrospira,and Zoogloea are altered.Low temperature and Ag NPs exposure can thus affect the wastewater treatment performance of constructed wetlands,possibly because of the seasonal changes of the microflora.

CFD Simulation of Film Flow and Gas/Liquid Countercurrent Flow on Structured Packing

A mathematic model of two-phase flow and a physical model of two-dimensional (2D) vertical section for the plate-type structured packing Mellapak 250.Y were set up and verified. The models were used to study the influence of packing’s surface microstructure on the continuity of liquid film and the amount of liquid holdup. Simulation results show that the round corner shape and micro wavy structure are favorable in remaining the continuity of liquid film and increasing the amount of liquid holdup. The appropriate liquid flow rate was determined by investigating different liquid loadings to obtain an unbroken liquid film on the packing surface. The pressure difference between inlet and outlet for gas phase allowed gas and liquid to flow countercurrently in a 2D computational domain. The direction change of gas flow occurred near the phase interface area.

Influence of Heat Treatment on Microstructure and Sliding Wear Behavior of Fe-Al/WC Composite Coatings

An experimental study has been carried out to investigate the influence of heat treatment at 300 ℃,450 ℃,550 ℃,650 ℃ and 800 ℃ on the microstructure and sliding wear behavior of Fe Al/WC intermetallic composite coatings produced by high velocity arc spraying (HVAS) and cored wires. The result shows, the main phases in both as sprayed and heat treated Fe Al/WC composite coatings are iron aluminide intermetallics (Fe 3Al+FeAl) and α as well as a little oxide (Al 2O 3) and carbides (WC, W 2C, Fe 2W 2C and Fe 6W 6C). After heat treated at 450-650 ℃, dispersion strengthening of Fe 2W 2C and Fe 6W 6C will lead to a rise in microhardness of the coatings. The microhardness is likely to be the most important factor which influences the sliding wear behavior of the coatings. Increasing the microhardness through heat treatment will improve the sliding wear resistance of the Fe Al/WC composite coatings.

Microphysical Structure of a Nimbostratus over Jilin Province Provided by Airborne Observations

Airborne measurements were collected during a stepwise ascent within a nimbostratus cloud associated with a cold vortex depression over the Jilin Province on 21 June 2005 to study cloud structure and ice particle spectra. The melting layer of the nimbostratus was clearly defined in the radar images. The microphysical structure of the nimbostratus was elucidated by a King liquid water probe and Particle Measuring Systems （PMS） probes aboard the research aircraft. The PMS 2-D images provided detailed information of ice crystal transformations. A thick layer of supercooled cloud was observed, and the high ice particle concentrations at temperatures ranging from -3℃ to -6℃ were consistent with Hallett-Mossop ice multiplication. The shape of ice crystals from near the cloud top to the melting layer were in the form of columns, needles, aggregations, and plates. In addition, significant horizontal variability was evident on the scale of few hundred meters. Particle spectra in this cloud were adequately described by exponential relationships. Relationship between the intercept （No） and slope （2） parameters of an exponential size distribution was well characterized by a power law.

Physical and chemical performances of high Al steels

The effects of acid-soluble Al content on the physical and chemical performances of high Al steels were investigated. The results show that the distribution of acid-soluble Al in steel substrate is uniform. With increasing Al content, the strength and toughness of steels decrease a little but the hardness increases. The average yield strength and tensile strength are 425MPa and 570MPa, respectively, and the Rockwell hardness is 89.7. For non-Al steels the average oxidation rate is up to 0.421mg/(cm2·h) at 1373K. For high Al steels, when the mass fraction of Al is less than 5%, there is a thinner gray oxidized layer on surface and the oxidation rate is high; when the mass fraction of Al is more than 8.0%, the thin, close and yellow glossing film still exists, and the average oxidation rate is only 0.016mg/(cm2·h).

Multilayer adsorption mechanism of coal surface adsorption to three oxygen molecule

Compared chemical bonds change situation of coal surface and oxygen mole- cules before and after coal surface adsorption to three oxygen molecules,after adsorption each oxygen molecule's chemical bond got longer,but had not broken,the coal surface's chemical bonds changed a little.It proves that the coal surface adsorption to five oxygen molecules is the physical adsorption and is the multilayer adsorption according to the op- timized geometry structure.The oxygen molecule's bond length that adsorbed by the side chain of coal surface changes most from 1.258 2×10^(-10) m to 1.316 8×10^(-10) m,which indi- cates this oxygen molecular to be the liveliest.The analysis of charge population reveals that how many electrons shift in the atom is directly proportional to the change of chemical bonds.The more electrons shift in the atom,the more molecule chemical bond changes. In the adsorption state,which is composed of coal surface and five oxygen molecules,the vibration frequency of oxygen molecules drops off,and the adsorption energy reached by calculation is 202.11 kJ/mol.

Impact of ultrasonic power on liquid fraction,microstructure and physical characteristics of A356 alloy molded through cooling slope

This study involves A356 alloy molded through ultrasonically vibrated cooling slope.The slope alongside ultrasonic power enables indispensable shear for engendering slurry from which the semisolid cast/heat treated billets got produced.An examination demonstrates ultrasonically vibrated cooling slope influencing the liquid fraction/microstructure/physical characteristics of stated billets.The investigation encompasses five diverse ultrasonic powers(0,75,150,200,250 W).The ultrasonic power of 150 W delivers finest/rounded microstructure with enhanced physical characteristics.Microstructural modifications reason physical transformations because of grain refinement and grain boundary/Hall-Petch strengthening.A smaller grain size reasons a higher strength/shape factor and an increased homogeneity reasons a higher ductility.Microstructural characteristics get improved by reheating.It is owing to coalescence throughout temperature homogenization.The physical characteristics is improved by reheating because of a reduced porosity and enhanced dissolution besides augmented homogeneity.A direct comparison remains impossible owing to unavailability of researches on ultrasonically vibrated cooling slope.

Review and Discussion on Seismic Subsidence of Loess

The research and achievements made on seismic subsidence of loess,obtained over the past30 years,were reviewed.Seismic Subsidence of Loess(SSL)has been verified by microstructure characteristics,dynamic triaxial experiments,and in-situ explosion tests,and has become an important subject in the field of seismic loess engineering research.While,the research is still in the stage of theoretical study of saturated soil,and there are no representative cases of seismic subsidence of loess in historical earthquakes.It is difficult to express structure characteristics using microstructure morphology.While,soil mechanics are available methods for this.Seismic subsidence judgment is absolute in some certain value ranges for several parameters.Therefore,probabilistic judgment should be developed.The seismic subsidence ratio is estimated mostly by empirical formulas or semiempirical and semi-theoretical formulas,which are based on laboratory data.These formulas are not established on the basis of physical process and mechanics of seismic subsidence,and this leads to more variables,complicated computation,and poor practicability.To solve these problems,we need to distinguish the main factors and corresponding variables,to establish a mechanics model for seismic subsidence estimation,and to characterize its physio-mechanical process.The key of anti-seismic subsidence treatment is to reduce the seismic subsidence property of soils,and to lower the interaction between the soil body and underground structures.

Research progress on cyclodextrins and their derivatives in the synthesis of conducting polymers

Cyclodextrins have gained wide attentions for their unique physicochemicai properties. In recent years, conducting polymers with special micro-structure and properties are synthesized in the presence of cyclodextrins. In this article, the application of cyclodextrins in the synthesis process of conducting polymer metarials is discussed. And authors＇ study results are summarized.

Rheology and microstructure effects of waste spent coffee grounds in modifying asphalt binder

Herein the biowaste by-product spent coffee grounds(SCGs)from coffee industry were incorporated into asphalt binders for performance enhancement.From the analysis of Fourier transform infrared spectroscopy(FTIR),differential scanning calorimetry(DSC),dynamic shear rheometer(DSR),and Brookfield viscosity rheometer,it is confirmed that SCGs have potential prospects as bio-waste modifiers in the application of sustainable pavements.Results demonstrated that the modification process was mainly based on physical reinforcement.Compared with that of the neat asphalt,the shearing stress-resistant ability and high-temperature performance of the SCGs modified binders with the appropriate addition presented a bit of improvement;whereas the binders with 1%and 3%SCGs exhibited remarkably enhanced low-temperature stability.However,notable weaknesses of practical performance were shown for the binder with excessive content of SCGs,indicating the necessity of proportion selecting before application.

创新拼搏形成优秀研究群体——国家重点实验室实践中的几点体会

一、实验室概况 南京大学固体微结构物理实验室始建于1984年,建成于1987年,是国内首批建设、开放的国家重点实验室之一。十多年来,在国家计委、科技部、教育部、基金委等的关怀支持下,在凝聚态物理基础和应用基础研究方面开展了大量工作,取得了不少科研成果。迄今为止,实验室已获得国家级奖4项,省部级奖49项,出版专著48部,发表论文2000余篇。