Apostichopus japonicus Selenka is an ideal tonic food that is used traditionally in many Asian countries, and it contains many bioactive substances, such as antioxidant, antimicrobial, and anticancer materials. To con...Apostichopus japonicus Selenka is an ideal tonic food that is used traditionally in many Asian countries, and it contains many bioactive substances, such as antioxidant, antimicrobial, and anticancer materials. To convert waste liquid generated during production into a useful resource, extract from waste liquid was isolated by column chromatography and studied by the pyrogallol autoxidation and 1,10-phenanthroline-Fe^2＋ oxidation methods. Results show that the extract scavenged about 91% of the superoxide anion radical at a concentration of 1.4 mg/mL and 24% of the hydroxyl radical at 3.3 mg/mL. Four compounds were isolated and identified from the extract： 2,4-dihydroxy-5-methyl-1,3-azine; 2,4-dihydroxy- 1,3-diazine; 3-O-β-D-quinovopranosyl-（1→2）-4-O-sodium sulfate-β-D-xylopranosyl]-holosta-9（11）-ene313,12β,17α-triol; and 24-ethyl-5α-cholesta-7-ene-3β-O-β-D-xylopyranoside. All of these compounds are known in A. japonicus, and were found in the waste liquid for the first time.展开更多
K2FeO4 powders were synthesized by the ex-situ and in-situ electrochemical methods, respectively, and characterized by infrared spectrum （IR）, scanning electron microscopy （SEM）, X-ray powder diffraction （XRD） a...K2FeO4 powders were synthesized by the ex-situ and in-situ electrochemical methods, respectively, and characterized by infrared spectrum （IR）, scanning electron microscopy （SEM）, X-ray powder diffraction （XRD） and BET. Their electrochemical performances were investigated by means of galvanostatic discharge and electrochemi-cal impedance spectroscopy （EIS）. The results of physical characterization showed that the two samples have simi-lar structural features, but their surface morphologies and oriented growth of the crystals are different, which results in smaller specific surface area and lower solubility of the ex-situ electrosynthesized K2FeO4 sample. The results of discharge experiments indicated that the ex-situ electrosythesized K2FeO4 electrode has much larger discharge ca-pacity and lower electrode polarization than the in-situ electrosynthesized K2FeO4 electrode. It was found from the results of EIS that lower electrochemical polarization might be responsible for the improvement on the discharge performance of the ex-situ electrosynthesized K2FeO4 electrode.展开更多
The general finite difference schemes with intrinsic parallelism for the boundary value problem of the semilinear parabolic system of divergence type with bounded measurable coefficients is studied. By the approach of...The general finite difference schemes with intrinsic parallelism for the boundary value problem of the semilinear parabolic system of divergence type with bounded measurable coefficients is studied. By the approach of the discrete functional analysis, the existence and uniqueness of the discrete vector solutions of the nonlinear difference system with intrinsic parallelism are proved. Moreover the unconditional stability of the general difference schemes with intrinsic parallelism justified in the sense of the continuous dependence of the discrete vector solution of the difference schemes on the discrete initial data of the original problems in the discrete W_2^(2,1) (Q△) norms. Finally the convergence of the discrete vector solutions of the certain difference schemes with intrinsic parallelism to the unique generalized solution of the original semilinear parabolic problem is proved.展开更多
Convective heat transfer coefficient is one of the most vital parameters which reveals the thermal efficiency of a pipe flow.To obtain such coefficients for problems with variable pipe wall temperature,numerical itera...Convective heat transfer coefficient is one of the most vital parameters which reveals the thermal efficiency of a pipe flow.To obtain such coefficients for problems with variable pipe wall temperature,numerical iterative methods should be used which could be time-consuming and less accurate.In this paper,thermophysical properties of fluids are assumed to be constant.We define a variable related to the temperature gradient of the pipe wall and study the varying law of the local coefficient.Then,a sample-based scheme is proposed to avoid the calculation of a time-consuming problem in the use of solutions with low computing cost.To verify its accuracy,several problems in normal circle pipes with variable factors,such as the various temperatures of the pipe wall,the different radius of the pipe,and various velocities of fluid flow,are well resolved.Meanwhile,its validity in a convergent pipe is also studied.From the obtained results,the high accuracy and efficiency of the proposed scheme can be confirmed.Therefore,the proposed scheme for determining the convective heat transfer coefficient has great potential in engineering problems.展开更多
基金Supported by the National Special Research Fund for Non-Profit Sector(Ocean)(No.201205025-5)
文摘Apostichopus japonicus Selenka is an ideal tonic food that is used traditionally in many Asian countries, and it contains many bioactive substances, such as antioxidant, antimicrobial, and anticancer materials. To convert waste liquid generated during production into a useful resource, extract from waste liquid was isolated by column chromatography and studied by the pyrogallol autoxidation and 1,10-phenanthroline-Fe^2＋ oxidation methods. Results show that the extract scavenged about 91% of the superoxide anion radical at a concentration of 1.4 mg/mL and 24% of the hydroxyl radical at 3.3 mg/mL. Four compounds were isolated and identified from the extract： 2,4-dihydroxy-5-methyl-1,3-azine; 2,4-dihydroxy- 1,3-diazine; 3-O-β-D-quinovopranosyl-（1→2）-4-O-sodium sulfate-β-D-xylopranosyl]-holosta-9（11）-ene313,12β,17α-triol; and 24-ethyl-5α-cholesta-7-ene-3β-O-β-D-xylopyranoside. All of these compounds are known in A. japonicus, and were found in the waste liquid for the first time.
基金Supported by the National Natural Science Foundation of China (No.50172041)partly by the Chinese State Key Labora-tory for Corrosion and Protection.
文摘K2FeO4 powders were synthesized by the ex-situ and in-situ electrochemical methods, respectively, and characterized by infrared spectrum （IR）, scanning electron microscopy （SEM）, X-ray powder diffraction （XRD） and BET. Their electrochemical performances were investigated by means of galvanostatic discharge and electrochemi-cal impedance spectroscopy （EIS）. The results of physical characterization showed that the two samples have simi-lar structural features, but their surface morphologies and oriented growth of the crystals are different, which results in smaller specific surface area and lower solubility of the ex-situ electrosynthesized K2FeO4 sample. The results of discharge experiments indicated that the ex-situ electrosythesized K2FeO4 electrode has much larger discharge ca-pacity and lower electrode polarization than the in-situ electrosynthesized K2FeO4 electrode. It was found from the results of EIS that lower electrochemical polarization might be responsible for the improvement on the discharge performance of the ex-situ electrosynthesized K2FeO4 electrode.
基金Project supported by China "National Key Program for Developing Basic Sciences" (No.G1999032801) the National Natural Science Foundation of China (No.19932010) the Science and Technology Foundation of Chinese Academy of Engineering Physics (No.200206
文摘The general finite difference schemes with intrinsic parallelism for the boundary value problem of the semilinear parabolic system of divergence type with bounded measurable coefficients is studied. By the approach of the discrete functional analysis, the existence and uniqueness of the discrete vector solutions of the nonlinear difference system with intrinsic parallelism are proved. Moreover the unconditional stability of the general difference schemes with intrinsic parallelism justified in the sense of the continuous dependence of the discrete vector solution of the difference schemes on the discrete initial data of the original problems in the discrete W_2^(2,1) (Q△) norms. Finally the convergence of the discrete vector solutions of the certain difference schemes with intrinsic parallelism to the unique generalized solution of the original semilinear parabolic problem is proved.
基金the National Natural Science Foundation of China(Grant No.12072103)the Fundamental Research Funds for the Central Universities(Grant No.B200202126)+2 种基金the Natural Science Foundation of Jiangsu Province(Grant No.BK20190073)the State Key Laboratory of Acoustics,Chinese Academy of Sciences(Grant No.SKLA202001)the China Postdoctoral Science Foundation(Grant Nos.2017M6I 1669 and 2018T110430).
文摘Convective heat transfer coefficient is one of the most vital parameters which reveals the thermal efficiency of a pipe flow.To obtain such coefficients for problems with variable pipe wall temperature,numerical iterative methods should be used which could be time-consuming and less accurate.In this paper,thermophysical properties of fluids are assumed to be constant.We define a variable related to the temperature gradient of the pipe wall and study the varying law of the local coefficient.Then,a sample-based scheme is proposed to avoid the calculation of a time-consuming problem in the use of solutions with low computing cost.To verify its accuracy,several problems in normal circle pipes with variable factors,such as the various temperatures of the pipe wall,the different radius of the pipe,and various velocities of fluid flow,are well resolved.Meanwhile,its validity in a convergent pipe is also studied.From the obtained results,the high accuracy and efficiency of the proposed scheme can be confirmed.Therefore,the proposed scheme for determining the convective heat transfer coefficient has great potential in engineering problems.
