The basal theory of Gauss-MRF is expounded and 2-5 order Gauss MRF models are established. Parameters of the 2-5 order Gauss-MRF models for 300 wood samples' surface texture are also estimated by using LMS. The data ...The basal theory of Gauss-MRF is expounded and 2-5 order Gauss MRF models are established. Parameters of the 2-5 order Gauss-MRF models for 300 wood samples' surface texture are also estimated by using LMS. The data analysis shows that: 1) different rexture parameters have a clear scattered distribution, 2) the main direction of texture is the direction represented by the maximum parameter of Gauss-MRF parameters, and 3) for those samples having the same main direction, the finer the texture is, the greater the corresponding parameter is, and the smaller the other parameters are; and the higher the order of Gauss-MRF is, the more clearly the texture is described. On the condition of the second order Gauss MRF model, parameter B1, B2 of tangential texture are smaller than that of radial texture, while B3 and B4 of tangential texture are greater than that of radial texture. According to the value of separated criterion, the parameter of the fifth order Gauss-MRF is used as feature vector for Hamming neural network classification. As a result, the ratio of correctness reaches 88%.展开更多
A rotating axisymmetric circular nanoplate is modeled by the Mindlin plate theory.The Mindlin plate theory incorporates the nonlocal scale and strain gradient effects.The shear deformation of the circular nanoplate is...A rotating axisymmetric circular nanoplate is modeled by the Mindlin plate theory.The Mindlin plate theory incorporates the nonlocal scale and strain gradient effects.The shear deformation of the circular nanoplate is considered and the nonlocal strain gradient theory is utilized to derive the governing differential equation of motion that describes the out-of-plane free vibration behaviors of the nanoplate.The differential quadrature method is used to solve the governing equation numerically,and the natural frequencies of the out-of-plane vibration of rotating nanoplates are obtained accordingly.Two kinds of boundary conditions are commonly used in practical engineering,namely the fixed and simply supported constraints,and are considered in numerical examples.The variations of natural frequencies with respect to the thickness to radius ratio,the angular velocity,the nonlocal characteristic scale and the material characteristic scale are analyzed in detail.In particular,the critical angular velocity that measures whether the rotating circular nanoplate is stable or not is obtained numerically.The presented study has reference significance for the dynamic design and control of rotating circular nanostructures in current nano-technologies and nano-devices.展开更多
By using metal nitrates as starting materials and citric acid as a complexing agent, Y2Si207:Re3+ (Re=Eu, Tb) phosphors were prepared by a sol-gel method. X-ray diffraction was employed to characterize the resulti...By using metal nitrates as starting materials and citric acid as a complexing agent, Y2Si207:Re3+ (Re=Eu, Tb) phosphors were prepared by a sol-gel method. X-ray diffraction was employed to characterize the resulting samples. The results of XRD indicate that the α-Y2Si2O7 nanocrystal with size of 27 nm is obtained at 1000 ℃ and the doping ion content does not influence the structure. The excitation spectra in the UV and VUV ranges and the emission spectra of Re^3+ doped samples were measured. The excitation spectra in the VUV range is due to absorption of host, that in the UV range is ascribed to absorption transitions from 4f to 5d state of the Tb^3+ and the charge transfer in the En^3+-O^2- bond. The spectral energy distribution of the Tb^3+ emission depends strongly on the Tb3+ concentration. The dependence of photolumineseenee intensity on Re^3+ concentration is also discussed in detail. The fluorescent decay curves at room temperature were measured and analyzed.展开更多
Besides opening geometry, in situ stress and material properties, opening support also has significant effects on stress redistribution around a roadway. To investigate these effects of rock bolts on the stress redist...Besides opening geometry, in situ stress and material properties, opening support also has significant effects on stress redistribution around a roadway. To investigate these effects of rock bolts on the stress redistribution around a roadway, a series of numerical studies were carried out using the finite difference method. Since the stress changes around a roadway caused by rock bolting is small relative to the in situ stress, they cannot obviously be observed in stress contour plots. To overcome this difficulty, a new result processing methodology was developed using the contouring program Surfer. With this methodology, the effects of rock bolts on stress redistribution can obviously be analyzed. Numerical results show that in the three patterns of rock bolts installed in the roof, in the roof and the two lateral sides, and in all the four sides of the rectangular roadway, the maximum stress magnitude of the increase is 0.931 MPa, 2.46 MPa,and 6.5 MPa, respectively; the bolt number of 5 can form an integrated ground arch; the appropriate length and pre-tensioned force of the rock bolt is 2.0 m and 60 k N, respectively. What is more, the ground arch action under the function of rock bolting is able to be effectively examined. The rock bolts dramatically increase the minor principal stress around a roadway which results in significant increase in material strength. Consequently, the major principal stress that the material can carry will greatly increase.With adequate supports, an integrated ground arch which is critical for the stability of roadway will be formed around the roadway.展开更多
To further test whether polynitriprismanes are capable of being potential high energy density materials (HEDMs), extensive theoretical calculations were carried out to investigate on a series of polynitrotriprisman...To further test whether polynitriprismanes are capable of being potential high energy density materials (HEDMs), extensive theoretical calculations were carried out to investigate on a series of polynitrotriprismanes (PNNPs): C6H6-.(NO2). (n=1-6) Heats of formation (HOFs), strain energies (SE), and disproportionation energy (DE) were obtained using B3LYP/6-311+G(2df, 2p)//B3LYP/6-31G* method by designing different isodesmic reactions, respectively. Detonation properties of PNNPs were obtained by the well-known KAMLET-JACOBS equations, using the predicted densities (p) obtained by Monte Carlo method and HOFs. It is found that they increase as the number of nitro groups n varies from 1 to 6, and PNNPs with n〉4 have excellent detonation properties The relative stability and the pyrolysis mechanism of PNNPs were evaluated by the calculated bond dissociation energy (BDE). The comparison of BDE suggests that rupturing the C--C bond is the trigger for thermolysis of PNNPs. The computed BDE for cleavage of C--C bond (88.5 kJ/mol) further demonstrates that only the hexa-nitrotriprismane can be considered to be the target of HEDMs.展开更多
An Ostwald ripening-based route is proposed to prepare Ni-rich layered cathodes with Co-rich surface for li- thium-ion batteries (LIBs). Commercially available Nio.aCo0.1 Mn0.8(OH)2 and spray pyrolysis derived por...An Ostwald ripening-based route is proposed to prepare Ni-rich layered cathodes with Co-rich surface for li- thium-ion batteries (LIBs). Commercially available Nio.aCo0.1 Mn0.8(OH)2 and spray pyrolysis derived porous Co304 are used as mixed precursors. During the lithiation reaction process under high-temperature, the porous Co304 microspheres scatter primary particles and spontaneously redeposit on the surface of Ni-rich spheres according to Ostwald ripening mechanism, forming the Ni-rich materials with Co-rich outer layers. When evaluated as cathode for LIBs, the resultant material shows ability to inhibit the cation disorder, relieves the phase transition from H2 to H3 and diminishes side re- actions between the electrolyte and Ni-rich cathode material. As a result, the obtained material with Co-rich outer layers exhibits much more improved cycle and rate performance than the material without Co-rich outer layers. Particularly, NCM-Co-1 (molar ratio of Nio.sCo0.1Mn0.1(OH)2/Co3Oa is 60:1) delivers a reversible capacity of 159.2 mA h g-1 with 90.5% capacity retention after 200 cycles at 1 C. This strategy pro- rides a general and efficient way to produce gradient sub- stances and to address the surface problems of Ni-rich cathode materials.展开更多
Free longitudinal vibrations of non-uniform rods are investigated by a proposed method, which results in a series solution. In a special case, with the proposed method an exact solution with a concise form can be obta...Free longitudinal vibrations of non-uniform rods are investigated by a proposed method, which results in a series solution. In a special case, with the proposed method an exact solution with a concise form can be obtained, which imply four types of profiles with variation in geometry or material properties. However, the WKB (Wentzel-Kramers-Brillouin) method leads to a series solution, which is a Taylor expansion of the results of the proposed method. For the arbitrary non-uniform rods, the comparison indicates that the WKB method is simpler, but the convergent speed of the series solution resulting from the pro-posed method is faster than that of the WKB method, which is also validated numerically using an exact solution of a kind of non-uniform rods with Kummer functions.展开更多
The convective heat transfer coefficient and surface emissivity before and after flame occurrence on a wood specimen surface and the flame heat flux were estimated using the repulsive particle swarm optimization algor...The convective heat transfer coefficient and surface emissivity before and after flame occurrence on a wood specimen surface and the flame heat flux were estimated using the repulsive particle swarm optimization algorithm and cone heater test results. The cone heater specified in the ISO 5660 standards was used, and six cone heater heat fluxes were tested. Preservative-treated Douglas fir 21 mm in thickness was used as the wood specimen in the tests. This study confirmed that the surface temperature of the specimen, which was calculated using the convective heat transfer coefficient, surface emissivity and flame heat flux on the wood specimen by a repulsive particle swarm optimization algorithm, was consistent with the measured temperature. Considering the measurement errors in the surface temperature of the specimen, the applicability of the optimization method considered in this study was evaluated.展开更多
Computer simulation with Monte Carlo is an important tool to investigate the function and equilibrium properties of many biological and soft matter materials solvable in solvents.The appropriate treatment of long-rang...Computer simulation with Monte Carlo is an important tool to investigate the function and equilibrium properties of many biological and soft matter materials solvable in solvents.The appropriate treatment of long-range electrostatic interaction is essential for these charged systems,but remains a challenging problem for large-scale simulations.We develop an efficient Barnes-Hut treecode algorithm for electrostatic evaluation in Monte Carlo simulations of Coulomb many-body systems.The algorithm is based on a divide-and-conquer strategy and fast update of the octree data structure in each trial move through a local adjustment procedure.We test the accuracy of the tree algorithm,and use it to perform computer simulations of electric double layer near a spherical interface.It is shown that the computational cost of the Monte Carlo method with treecode acceleration scales as log N in each move.For a typical system with ten thousand particles,by using the new algorithm,the speed has been improved by two orders of magnitude from the direct summation.展开更多
基金This paper is supported by the Municipal Natural Science Foundation of Harbin (2004AFX X J 0 20) and Provincial Natural Science Foundation of Heilongjiang (C2004-03).
文摘The basal theory of Gauss-MRF is expounded and 2-5 order Gauss MRF models are established. Parameters of the 2-5 order Gauss-MRF models for 300 wood samples' surface texture are also estimated by using LMS. The data analysis shows that: 1) different rexture parameters have a clear scattered distribution, 2) the main direction of texture is the direction represented by the maximum parameter of Gauss-MRF parameters, and 3) for those samples having the same main direction, the finer the texture is, the greater the corresponding parameter is, and the smaller the other parameters are; and the higher the order of Gauss-MRF is, the more clearly the texture is described. On the condition of the second order Gauss MRF model, parameter B1, B2 of tangential texture are smaller than that of radial texture, while B3 and B4 of tangential texture are greater than that of radial texture. According to the value of separated criterion, the parameter of the fifth order Gauss-MRF is used as feature vector for Hamming neural network classification. As a result, the ratio of correctness reaches 88%.
基金supported by the Natural Science Foundation of China(No.11972240)the China Postdoctoral Science Foundation(No.2020M671574)the University Natural Science Research Project of Anhui Province(No.KJ2018A0481).
文摘A rotating axisymmetric circular nanoplate is modeled by the Mindlin plate theory.The Mindlin plate theory incorporates the nonlocal scale and strain gradient effects.The shear deformation of the circular nanoplate is considered and the nonlocal strain gradient theory is utilized to derive the governing differential equation of motion that describes the out-of-plane free vibration behaviors of the nanoplate.The differential quadrature method is used to solve the governing equation numerically,and the natural frequencies of the out-of-plane vibration of rotating nanoplates are obtained accordingly.Two kinds of boundary conditions are commonly used in practical engineering,namely the fixed and simply supported constraints,and are considered in numerical examples.The variations of natural frequencies with respect to the thickness to radius ratio,the angular velocity,the nonlocal characteristic scale and the material characteristic scale are analyzed in detail.In particular,the critical angular velocity that measures whether the rotating circular nanoplate is stable or not is obtained numerically.The presented study has reference significance for the dynamic design and control of rotating circular nanostructures in current nano-technologies and nano-devices.
文摘By using metal nitrates as starting materials and citric acid as a complexing agent, Y2Si207:Re3+ (Re=Eu, Tb) phosphors were prepared by a sol-gel method. X-ray diffraction was employed to characterize the resulting samples. The results of XRD indicate that the α-Y2Si2O7 nanocrystal with size of 27 nm is obtained at 1000 ℃ and the doping ion content does not influence the structure. The excitation spectra in the UV and VUV ranges and the emission spectra of Re^3+ doped samples were measured. The excitation spectra in the VUV range is due to absorption of host, that in the UV range is ascribed to absorption transitions from 4f to 5d state of the Tb^3+ and the charge transfer in the En^3+-O^2- bond. The spectral energy distribution of the Tb^3+ emission depends strongly on the Tb3+ concentration. The dependence of photolumineseenee intensity on Re^3+ concentration is also discussed in detail. The fluorescent decay curves at room temperature were measured and analyzed.
基金Financial support for this work provided by the National Key Scientific Apparatus Development of Special Item (No.2012YQ24012705)is deeply appreciated
文摘Besides opening geometry, in situ stress and material properties, opening support also has significant effects on stress redistribution around a roadway. To investigate these effects of rock bolts on the stress redistribution around a roadway, a series of numerical studies were carried out using the finite difference method. Since the stress changes around a roadway caused by rock bolting is small relative to the in situ stress, they cannot obviously be observed in stress contour plots. To overcome this difficulty, a new result processing methodology was developed using the contouring program Surfer. With this methodology, the effects of rock bolts on stress redistribution can obviously be analyzed. Numerical results show that in the three patterns of rock bolts installed in the roof, in the roof and the two lateral sides, and in all the four sides of the rectangular roadway, the maximum stress magnitude of the increase is 0.931 MPa, 2.46 MPa,and 6.5 MPa, respectively; the bolt number of 5 can form an integrated ground arch; the appropriate length and pre-tensioned force of the rock bolt is 2.0 m and 60 k N, respectively. What is more, the ground arch action under the function of rock bolting is able to be effectively examined. The rock bolts dramatically increase the minor principal stress around a roadway which results in significant increase in material strength. Consequently, the major principal stress that the material can carry will greatly increase.With adequate supports, an integrated ground arch which is critical for the stability of roadway will be formed around the roadway.
基金Projects(2006DFA41090,2007DFA40680) supported by the International Cooperation Project on Traditional Chinese Medicines of Ministry of Science and Technology of ChinaProject(20475066) supported by the National Natural Science Foundation of China
文摘To further test whether polynitriprismanes are capable of being potential high energy density materials (HEDMs), extensive theoretical calculations were carried out to investigate on a series of polynitrotriprismanes (PNNPs): C6H6-.(NO2). (n=1-6) Heats of formation (HOFs), strain energies (SE), and disproportionation energy (DE) were obtained using B3LYP/6-311+G(2df, 2p)//B3LYP/6-31G* method by designing different isodesmic reactions, respectively. Detonation properties of PNNPs were obtained by the well-known KAMLET-JACOBS equations, using the predicted densities (p) obtained by Monte Carlo method and HOFs. It is found that they increase as the number of nitro groups n varies from 1 to 6, and PNNPs with n〉4 have excellent detonation properties The relative stability and the pyrolysis mechanism of PNNPs were evaluated by the calculated bond dissociation energy (BDE). The comparison of BDE suggests that rupturing the C--C bond is the trigger for thermolysis of PNNPs. The computed BDE for cleavage of C--C bond (88.5 kJ/mol) further demonstrates that only the hexa-nitrotriprismane can be considered to be the target of HEDMs.
基金the financial support of the National Basic Research Program of China (2014CB643406)the National Natural Science Foundation of China (51674296, 51574287, 51704332)+1 种基金the National Postdoctoral Program for Innovative Talents (BX201700290)the Fundamental Research Funds for the Central Universities of Central South University (2017zzts125)
文摘An Ostwald ripening-based route is proposed to prepare Ni-rich layered cathodes with Co-rich surface for li- thium-ion batteries (LIBs). Commercially available Nio.aCo0.1 Mn0.8(OH)2 and spray pyrolysis derived porous Co304 are used as mixed precursors. During the lithiation reaction process under high-temperature, the porous Co304 microspheres scatter primary particles and spontaneously redeposit on the surface of Ni-rich spheres according to Ostwald ripening mechanism, forming the Ni-rich materials with Co-rich outer layers. When evaluated as cathode for LIBs, the resultant material shows ability to inhibit the cation disorder, relieves the phase transition from H2 to H3 and diminishes side re- actions between the electrolyte and Ni-rich cathode material. As a result, the obtained material with Co-rich outer layers exhibits much more improved cycle and rate performance than the material without Co-rich outer layers. Particularly, NCM-Co-1 (molar ratio of Nio.sCo0.1Mn0.1(OH)2/Co3Oa is 60:1) delivers a reversible capacity of 159.2 mA h g-1 with 90.5% capacity retention after 200 cycles at 1 C. This strategy pro- rides a general and efficient way to produce gradient sub- stances and to address the surface problems of Ni-rich cathode materials.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11072157 and 10932006) the Program for Chang-jiang Scholars and Innovative Research Team in University (IRT0971).
文摘Free longitudinal vibrations of non-uniform rods are investigated by a proposed method, which results in a series solution. In a special case, with the proposed method an exact solution with a concise form can be obtained, which imply four types of profiles with variation in geometry or material properties. However, the WKB (Wentzel-Kramers-Brillouin) method leads to a series solution, which is a Taylor expansion of the results of the proposed method. For the arbitrary non-uniform rods, the comparison indicates that the WKB method is simpler, but the convergent speed of the series solution resulting from the pro-posed method is faster than that of the WKB method, which is also validated numerically using an exact solution of a kind of non-uniform rods with Kummer functions.
基金support from the research fund of the National Emergency Management Agency.(NEMA- Infra-2014-103)
文摘The convective heat transfer coefficient and surface emissivity before and after flame occurrence on a wood specimen surface and the flame heat flux were estimated using the repulsive particle swarm optimization algorithm and cone heater test results. The cone heater specified in the ISO 5660 standards was used, and six cone heater heat fluxes were tested. Preservative-treated Douglas fir 21 mm in thickness was used as the wood specimen in the tests. This study confirmed that the surface temperature of the specimen, which was calculated using the convective heat transfer coefficient, surface emissivity and flame heat flux on the wood specimen by a repulsive particle swarm optimization algorithm, was consistent with the measured temperature. Considering the measurement errors in the surface temperature of the specimen, the applicability of the optimization method considered in this study was evaluated.
基金supported by National Natural Science Foundation of China (Grant Nos.11101276 and 91130012)the support from the Alexander von Humboldt Foundation for a research stay at the Institute of Compututional Physics,University of Stuttgart
文摘Computer simulation with Monte Carlo is an important tool to investigate the function and equilibrium properties of many biological and soft matter materials solvable in solvents.The appropriate treatment of long-range electrostatic interaction is essential for these charged systems,but remains a challenging problem for large-scale simulations.We develop an efficient Barnes-Hut treecode algorithm for electrostatic evaluation in Monte Carlo simulations of Coulomb many-body systems.The algorithm is based on a divide-and-conquer strategy and fast update of the octree data structure in each trial move through a local adjustment procedure.We test the accuracy of the tree algorithm,and use it to perform computer simulations of electric double layer near a spherical interface.It is shown that the computational cost of the Monte Carlo method with treecode acceleration scales as log N in each move.For a typical system with ten thousand particles,by using the new algorithm,the speed has been improved by two orders of magnitude from the direct summation.