Sodium-ion batteries are economical and environmentally sustainable energy storage batteries.Among them,β-NaMnO_(2),a promising sodium-ion cathode material,is a manganese-based oxide with a corrugated laminar structu...Sodium-ion batteries are economical and environmentally sustainable energy storage batteries.Among them,β-NaMnO_(2),a promising sodium-ion cathode material,is a manganese-based oxide with a corrugated laminar structure,which has attracted significant attention due to its structural robustness and relatively high specific capacity.However,it has short cycle life and poor rate capability.To address these issues,Ti atoms,known for enhancing structural stability,and Cu atoms,which facilitate desodiation,were doped intoβ-NaMnO_(2) by first-principles calculation and crystal orbital Hamilton population(COHP)analysis.β-NaMn_(0.8)Ti_(0.1)Cu_(0.1)O_(2) exhibits a notable increase in reversible specific capacity and remarkable rate properties.Operating at a current density of 0.2C(1C=219 mA·g^(–1))and within a voltage range of 1.8–4.0 V,the modified material delivers an initial discharge capacity of 132 mAh·g^(–1).After charge/discharge testing at current densities of 0.2C,0.5C,1C,3C,and 0.2C,the material still maintains a capacity of 110 mA h·g^(–1).The doping of Ti atoms slows down the changes in the crystal structure,resulting in only minimal variation in the lattice constant c/a during the desodiation process.Mn and Cu engage in reversible redox reactions at voltages below 3.0 V and around 3.5 V,respectively.The extended plateau observed in the discharge curve below 3.0 V signifies that Mn significantly contributes to the overall battery capacity.This study provides insights into modifyingβ-NaMnO_(2) as a cathode material,offering experimental evidence and theoretical guidance for enhancing battery performance in Na-ion batteries.展开更多
Based on daily observation data of the Three Gorges Region(TGR)of the Yangtze River basin and global reanalysis data,the climate characteristics,climate events,and meteorological disasters of the TGR in 2022 and 2023 ...Based on daily observation data of the Three Gorges Region(TGR)of the Yangtze River basin and global reanalysis data,the climate characteristics,climate events,and meteorological disasters of the TGR in 2022 and 2023 were analyzed.For the TGR,the average annual temperature for 2022 and 2023 was 0.8℃ and 0.4℃ higher than normal,respectively,making them the two warmest years in the past decade.In 2022,the TGR experienced its warmest summer on record.The average air temperature was 2.4℃ higher than the average,and there were 24.8 days of above-average high temperature days during summer.Rainfall in the TGR varied significantly between 2022 and 2023.Annual rainfall was 18.4%below normal and drier than normal in most parts of the region.In contrast,the precipitation in 2023 was considerably higher than the long-term average,and above normal for almost the entire year.The average wind speed exhibited minimal variation between the two years.However,the number of foggy days and relative humidity increased in 2023 compared to 2022.In 2022–2023,the TGR mainly experienced meteorological disasters such as extreme high temperatures,regional heavy rain and flooding,overcast rain,and inverted spring chill.Analysis indicates that the abnormal western Pacific subtropical high and the abnormal persistence of the eastward-shifted South Asian high were the two important drivers of the durative enhancement of record-breaking high temperature in the summer of 2022.展开更多
Sc and Zn were introduced into O3-NaMn_(0.5)Ni_(0.5)O_(2)(NaMN)using the combination of solution combustion and solid-state method.The effect of Sc and Zn dual-substitution on Na^(+) diffusion dynamics and structural ...Sc and Zn were introduced into O3-NaMn_(0.5)Ni_(0.5)O_(2)(NaMN)using the combination of solution combustion and solid-state method.The effect of Sc and Zn dual-substitution on Na^(+) diffusion dynamics and structural stability of NaMN was investigated.The physicochemical characterizations suggest that the introduction of Sc and Zn broaden Na^(+) diffusion channels and weaken the Na—O bonds,thereby facilitating the diffusion of sodium ions.Simulations indicate that the Sc and Zn dual-substitution decreases the diffusion barrier of Na-ions and improves the conductivity of the material.The dual-substituted NaMn_(0.5)Ni_(0.4)Sc_(0.04)Zn_(0.04)O_(2)(Na MNSZ44)cathode delivers impressive cycle stability with capacity retention of 71.2%after 200 cycles at 1C and 54.8%after 400 cycles at 5C.Additionally,the full cell paired with hard carbon anode exhibits a remarkable long-term cycling stability,showing capacity retention of 64.1%after 250 cycles at 1C.These results demonstrate that Sc and Zn dual-substitution is an effective strategy to improve the Na^(+) diffusion dynamics and structural stability of NaMN.展开更多
Based on the durability characteristics of prestressed concrete structures,the durability limit states of carbonation and chloride ion attack are defined, respectively.Durability predicting models on the basis of reli...Based on the durability characteristics of prestressed concrete structures,the durability limit states of carbonation and chloride ion attack are defined, respectively.Durability predicting models on the basis of reliability mathematics and stochastic processes areconstructed, and the pure theoretical formulae of failure probability of prestressed concretestructures are analyzed. In addition, a simple durability design method for carbonation ofstructures is put forward. According to the analysis, the durability of prestressed concretestructures is superior to that of traditional structures. The research also indicates that theconcrete cover prescribed in the current code (GB 50010-2002) is not adequate. The rational coverthickness should notbe less than 35 or 45 mm according to carbonation or chloride ion attack,respectively.展开更多
基金National Key R&D Program of China(2022YFB3807700)National Natural Science Foundation of China(22133005,22103093)+4 种基金Science and Technology Commission of Shanghai Municipality(21ZR1472900,22ZR1471600,23ZR1472600)Youth Innovation Promotion Association CAS(2022251)Shanghai Super Post-Doctor Incentive Program(2022665)China Postdoctoral Science Foundation(2023M733621)Shanghai Explorer Program(Batch I)(23TS1401500)。
文摘Sodium-ion batteries are economical and environmentally sustainable energy storage batteries.Among them,β-NaMnO_(2),a promising sodium-ion cathode material,is a manganese-based oxide with a corrugated laminar structure,which has attracted significant attention due to its structural robustness and relatively high specific capacity.However,it has short cycle life and poor rate capability.To address these issues,Ti atoms,known for enhancing structural stability,and Cu atoms,which facilitate desodiation,were doped intoβ-NaMnO_(2) by first-principles calculation and crystal orbital Hamilton population(COHP)analysis.β-NaMn_(0.8)Ti_(0.1)Cu_(0.1)O_(2) exhibits a notable increase in reversible specific capacity and remarkable rate properties.Operating at a current density of 0.2C(1C=219 mA·g^(–1))and within a voltage range of 1.8–4.0 V,the modified material delivers an initial discharge capacity of 132 mAh·g^(–1).After charge/discharge testing at current densities of 0.2C,0.5C,1C,3C,and 0.2C,the material still maintains a capacity of 110 mA h·g^(–1).The doping of Ti atoms slows down the changes in the crystal structure,resulting in only minimal variation in the lattice constant c/a during the desodiation process.Mn and Cu engage in reversible redox reactions at voltages below 3.0 V and around 3.5 V,respectively.The extended plateau observed in the discharge curve below 3.0 V signifies that Mn significantly contributes to the overall battery capacity.This study provides insights into modifyingβ-NaMnO_(2) as a cathode material,offering experimental evidence and theoretical guidance for enhancing battery performance in Na-ion batteries.
基金supported by the National Key Research and Development Program of China[grant number 2023YFC3206001]the Three Gorges Project Comprehensive Monitoring Program for Operational Safety[grant number SK2023019]which funded by the Ministry of Water Resources of China.
文摘Based on daily observation data of the Three Gorges Region(TGR)of the Yangtze River basin and global reanalysis data,the climate characteristics,climate events,and meteorological disasters of the TGR in 2022 and 2023 were analyzed.For the TGR,the average annual temperature for 2022 and 2023 was 0.8℃ and 0.4℃ higher than normal,respectively,making them the two warmest years in the past decade.In 2022,the TGR experienced its warmest summer on record.The average air temperature was 2.4℃ higher than the average,and there were 24.8 days of above-average high temperature days during summer.Rainfall in the TGR varied significantly between 2022 and 2023.Annual rainfall was 18.4%below normal and drier than normal in most parts of the region.In contrast,the precipitation in 2023 was considerably higher than the long-term average,and above normal for almost the entire year.The average wind speed exhibited minimal variation between the two years.However,the number of foggy days and relative humidity increased in 2023 compared to 2022.In 2022–2023,the TGR mainly experienced meteorological disasters such as extreme high temperatures,regional heavy rain and flooding,overcast rain,and inverted spring chill.Analysis indicates that the abnormal western Pacific subtropical high and the abnormal persistence of the eastward-shifted South Asian high were the two important drivers of the durative enhancement of record-breaking high temperature in the summer of 2022.
基金financial support from the National Natural Science Foundation of China(No.52377220)the Natural Science Foundation of Hunan Province,China(No.kq2208265)。
文摘Sc and Zn were introduced into O3-NaMn_(0.5)Ni_(0.5)O_(2)(NaMN)using the combination of solution combustion and solid-state method.The effect of Sc and Zn dual-substitution on Na^(+) diffusion dynamics and structural stability of NaMN was investigated.The physicochemical characterizations suggest that the introduction of Sc and Zn broaden Na^(+) diffusion channels and weaken the Na—O bonds,thereby facilitating the diffusion of sodium ions.Simulations indicate that the Sc and Zn dual-substitution decreases the diffusion barrier of Na-ions and improves the conductivity of the material.The dual-substituted NaMn_(0.5)Ni_(0.4)Sc_(0.04)Zn_(0.04)O_(2)(Na MNSZ44)cathode delivers impressive cycle stability with capacity retention of 71.2%after 200 cycles at 1C and 54.8%after 400 cycles at 5C.Additionally,the full cell paired with hard carbon anode exhibits a remarkable long-term cycling stability,showing capacity retention of 64.1%after 250 cycles at 1C.These results demonstrate that Sc and Zn dual-substitution is an effective strategy to improve the Na^(+) diffusion dynamics and structural stability of NaMN.
文摘Based on the durability characteristics of prestressed concrete structures,the durability limit states of carbonation and chloride ion attack are defined, respectively.Durability predicting models on the basis of reliability mathematics and stochastic processes areconstructed, and the pure theoretical formulae of failure probability of prestressed concretestructures are analyzed. In addition, a simple durability design method for carbonation ofstructures is put forward. According to the analysis, the durability of prestressed concretestructures is superior to that of traditional structures. The research also indicates that theconcrete cover prescribed in the current code (GB 50010-2002) is not adequate. The rational coverthickness should notbe less than 35 or 45 mm according to carbonation or chloride ion attack,respectively.
