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(一)-莰烷磺内酰胺法立体选择性合成米象虫和玉米象虫聚集合信息素
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作者 李焰 黄锦霞 +2 位作者 陈祖兴 徐章煌 邹其超 《有机化学》 SCIE CAS CSCD 北大核心 1998年第3期224-227,共4页
本文以(-)-莰垸-2,10-磺内酰胺(2)为原料经六步反应立体选择性地合成了米象虫和玉米象虫聚集信息素(4S,5R)-Sitophilure,两个手性中心是由N-丙酰基-莰烷-2,10-磺内酰胺(3)与丙醛进行的不对称顺式醛醇缩合反应一次性引入的。该全合成的... 本文以(-)-莰垸-2,10-磺内酰胺(2)为原料经六步反应立体选择性地合成了米象虫和玉米象虫聚集信息素(4S,5R)-Sitophilure,两个手性中心是由N-丙酰基-莰烷-2,10-磺内酰胺(3)与丙醛进行的不对称顺式醛醇缩合反应一次性引入的。该全合成的对映异构体纯度可达96%e.e。 展开更多
关键词 Sitophilure 玉米象虫 聚集信息素 合成
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Optimum Insecticide Doses Determination of Seed Oil of Three Botanicals Jatropha Curcas L., Helianthus Annus L. and Cocos Nucifera L. against Maize Weevil Sitophilus Zeamais Mots.
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作者 Rachael Folake Ogunleye Mary Omofolarin Ogunkoya Francis Olawale Abulude 《Journal of Life Sciences》 2011年第4期298-301,共4页
The insecticidal effect of four dosage rates of three botanicals namely Jatropha curcas, Heliathus annus and Cocos nucifera was tested on the maize weevil Sitophilus zeamais Mots.. This is done for the purpose of find... The insecticidal effect of four dosage rates of three botanicals namely Jatropha curcas, Heliathus annus and Cocos nucifera was tested on the maize weevil Sitophilus zeamais Mots.. This is done for the purpose of finding a replacement for conventional insecticides which has been found to be harmful to man. The seed oil was applied topically at the rate of 0.1, 0.2, 0.3 and 0.4 mL per insect. There were a total of 20 insects per Petri-dish. There were four replicates per treatment. Insect mortality was recorded on 12 hourly basis for 48 hours. The results of insects treated with all dosage rates of C. nucifera showed a significantly higher mortality when compared with the control. In the case ofH. annus, insect mortality ranged from 40-100, 70-100, 60-100 and 80-100% and for J. curcas the result ranged from 0.0-100, 40-100, 80-100 and 80-100% for rates of 0.1, 0.2, 0.3 and 0.4 mL, respectively, from 12 hrs to 48 hrs post application. The control experiment remained at 0% level throughout the period of the experiments. 展开更多
关键词 Seed oil botanicals insecticides Sitophilus zeamais.
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