Some key factors on the heavy metals removal efficiencies were studied when soil washing technology was used in the remediation of soils contaminated by multiple heavy metals. The results show that the dissolubilities...Some key factors on the heavy metals removal efficiencies were studied when soil washing technology was used in the remediation of soils contaminated by multiple heavy metals. The results show that the dissolubilities of Cu and Zn are promoted by humic acids, but Pb and Cd are inhibited by humic acids; heavy metals in the clay are more difficult to be extracted than silt; the strong acidic soils can cause the protonation of EDTA and weaken its extracting ability; EDTA is effective for extracting Pb and Cd, while oxalate (OX) is effective for extracting Cu and Zn; and biosurfactant can be used as additive to improve the removal of some particular heavy metals.展开更多
Environmental pollution affects the quality of pedosphere,hydrosphere,atmosphere,lithosphere and biosphere.Great efforts have been made in the last two decades to reduce pollution sources and remedy the polluted soil ...Environmental pollution affects the quality of pedosphere,hydrosphere,atmosphere,lithosphere and biosphere.Great efforts have been made in the last two decades to reduce pollution sources and remedy the polluted soil and water resources.Phytoremediation,being more cost-effective and fewer side effects than physical and chemical approaches,has gained increasing popularity in both academic and practical circles.More than 400 plant species have been identified to have potential for soil and water remediation.Among them,Thlaspi,Brassica,Sedum alfredii H.,and Arabidopsis species have been mostly studied.It is also expected that recent advances in biotechnology will play a promising role in the development of new hyperaccumulators by transferring metal hyperaccumulating genes from low biomass wild species to the higher biomass producing cultivated species in the times to come.This paper attempted to provide a brief review on recent progresses in research and practical applications of phytoremediation for soil and water resources.展开更多
Four assessment methods (two pollution indexes and two fuzzy mathematical models) were employed to investigate the environmental quality of four soils around a ferroalloy plant in Nanjing City. Environmental quality...Four assessment methods (two pollution indexes and two fuzzy mathematical models) were employed to investigate the environmental quality of four soils around a ferroalloy plant in Nanjing City. Environmental quality was assessed as class Ⅳ (moderately polluted) for each soil with single-factor index method, and was identified to be classes Ⅳ, Ⅲ (slightly polluted), Ⅲ, and Ⅲ for soils A, B, C, and D, respectively, with the comprehensive index model. In comparison with the single-factor index method, the comprehensive index model concerned both dominant parameter and average contribution of all factors to the integrated environmental quality. Using the two fuzzy mathematical methods (single-factor deciding and weighted average models), the environmental risks were determined to be classes Ⅳ, Ⅲ, Ⅱ (clean), and Ⅱ for soils A, B, C, and D, respectively. However, divergence of the membership degree to each pollution class still occurred between the two methods. In fuzzy mathematical methods, membership functions were used to describe the limits between different pollution degrees, and different weights were allocated for the factors according to pollution contribution. Introduction of membership degree and weight of each factor to fuzzy mathematical models made the methods more reasonable in the field of environmental risk assessment.展开更多
Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent sus...Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent susceptibility (Xfd) showed the absence of superparamagnetic (SP) grains in the samples. The IRM20mT (isothermal remanent magnetization at 20 mT) being linearly proportional to SIRM (saturation isothermal remanent magnetization) (R^2=0.901), suggested that ferrimagnetic minerals were responsible for the magnetic properties of automobile emission particulates. The average contents of Cu, Cd, Pb and Fe in automobile emission particulates were 95.83, 22.14, 30.58 and 34727.31 mg/kg, respectively. Significant positive correlations exist between the magnetic parameters and the contents ofPb, Cu and Fe. The magnetic parameters of automobile emission particulates reflecting concentration of magnetic particles increased linearly with increase of Pb and Cu content, showed that the magnetic measurement could be used as a preliminary index for detection of Pb and Cu pollution.展开更多
Soils can often be contaminated simultaneously by more than one heavy metal. The sorption-desorption behavior of a metal in a soil will be affected by the presence of other metals. Therefore, selective retention and c...Soils can often be contaminated simultaneously by more than one heavy metal. The sorption-desorption behavior of a metal in a soil will be affected by the presence of other metals. Therefore, selective retention and competitive adsorption of the soils to heavy metals can affect their availability and movement through the soils. In this study, the simultaneous competitive adsorption of four heavy metals (Cd, Cu, Hg, and Pb) on ten agricultural soils collected from the Changjiang and Zhujiang deltas, China was assessed. The results showed that the competition affected the behavior of heavy metal cations in such a way that the soils adsorbed less Cd and Hg, and more Pb and Cu with increasing total metal concentrations, regardless of the molar concen- tration applied. As the applied concentrations increased, Pb and Cu adsorption increased, while Cd and Hg adsorption decreased. The adsorption sequence most found was Pb>Cu>Hg>Cd. The maximum adsorption capacity for the heavy metal cations was calculated, and affected markedly by soil properties. The results suggest that Hg and Cd have higher mobility associated to the lower adsorption and that Pb and Cu present the opposite behavior. Significant correlations were found between the maximum adsorption capacity of the metals and pH value and exchangeable acid, suggesting that soil pH and exchangeable acid were key factors controlling the solubility and mobility of the metals in the agricultural soils.展开更多
Reconstructing long-term vegetation buffers along streams in agricultural landscapes has become a common environmental restoration strategy for improving water quality and wildlife habitat connectivity.This article de...Reconstructing long-term vegetation buffers along streams in agricultural landscapes has become a common environmental restoration strategy for improving water quality and wildlife habitat connectivity.This article developed a linear weighted model to rank the priority of agricultural sub-basins for the establishment of vegetative buffers.The method was applied to an agricultural watershed of 146 km2 in Ontario,Canada.The watershed was divided into 11 sub-basins as basic decision units.In each subbasin,four stream buffer schemes with widths of 5,10,15 and 20m were generated.For each buffer,three benefit-cost attributes of reconstructing vegetation cover were estimated,which include acreage per dollar,sediment abatement per dollar and habitat benefit per dollar.These attributes were first normalized using a linear normalization approach to eliminate the effects across different units.The normalized attributes were then integrated using a simple additive weighting method to rank the 11 sub-basins for prioritizing spatial restoration action.A sensitivity analysis was also conducted to observe the impact of a change in attribute weights on the management decisions.The results suggest that vegetation buffers reconstructed for achieving the water quality goal are not effective in improving habitat connectivity and vice versa.展开更多
Referring to GB5618-1995 about heavy metal pollution,and using statistical analysis SPSS,the major pollutants of mine area farmland heavy metal pollution were identified by variable clustering analysis.Assessment and ...Referring to GB5618-1995 about heavy metal pollution,and using statistical analysis SPSS,the major pollutants of mine area farmland heavy metal pollution were identified by variable clustering analysis.Assessment and classification were done to the mine area farmland heavy metal pollution situation by synthetic principal components analysis (PCA).The results show that variable clustering analysis is efficient to identify the principal components of mine area farmland heavy metal pollution.Sort and clustering were done to the synthetic principal components scores of soil sample,which is given by synthetic principal components analysis.Data structure of soil heavy metal contaminations relationships and pollution level of different soil samples are discovered.The results of mine area farmland heavy metal pollution quality assessed and classified with synthetic component scores reflect the influence of both the major and compound heavy metal pol- lutants.Identification and assessment results of mine area farmland heavy metal pollution can provide reference and guide to propose control measures of mine area farmland heavy metal pollution and focus on the key treatment region.展开更多
Significant quantities of slag are generated as waste material or by-product every day from steel industries. They usually contain considerable quantities of valuable metals and materials. Transforming these solid was...Significant quantities of slag are generated as waste material or by-product every day from steel industries. They usually contain considerable quantities of valuable metals and materials. Transforming these solid wastes from one form to another to be reused either by the same production unit or by different industrial installation is very much essential not only for conserving metals and mineral resources but also for protecting the environment. The sustainable development concept requires a more efficient management of waste materials and preservation of environment. The paper presents the basic characteristics of slag, analyses and it's modification by incorporating some essential plant nutrients and the possibility of its application as fertilizer was studied.展开更多
The current status of catalytic reforming in China is reviewed and a forecastof the development in a couple of years or a decade is given. Distinguished from the past decade,the future trend will be focused on revamps...The current status of catalytic reforming in China is reviewed and a forecastof the development in a couple of years or a decade is given. Distinguished from the past decade,the future trend will be focused on revamps, expansions, higher severity, diversified feeds,combination with other processes for higher product quality, and novel catalysts and equipment.展开更多
基金Project(20050532009) supported by the Doctoral Foundation of Ministry of Education of ChinaProjects(2006BAD03A1704, 2006BAD03A1706) supported by the National 11th-Five Technology Supporting Project
文摘Some key factors on the heavy metals removal efficiencies were studied when soil washing technology was used in the remediation of soils contaminated by multiple heavy metals. The results show that the dissolubilities of Cu and Zn are promoted by humic acids, but Pb and Cd are inhibited by humic acids; heavy metals in the clay are more difficult to be extracted than silt; the strong acidic soils can cause the protonation of EDTA and weaken its extracting ability; EDTA is effective for extracting Pb and Cd, while oxalate (OX) is effective for extracting Cu and Zn; and biosurfactant can be used as additive to improve the removal of some particular heavy metals.
基金Project supported by the Higher Education Commission,Government of Pakistan for the faculty training under the R & D Project"Strengthening Department of Soil Science and Soil and Water Conservation" at the University of Florida,USA,a grant from the St. Lucie River Water Initiative (SFWMD contract No. OT060162),USA,in partthe Program for Changjiang Scholars and Innovative Research Team in University (No.IRT0536),China
文摘Environmental pollution affects the quality of pedosphere,hydrosphere,atmosphere,lithosphere and biosphere.Great efforts have been made in the last two decades to reduce pollution sources and remedy the polluted soil and water resources.Phytoremediation,being more cost-effective and fewer side effects than physical and chemical approaches,has gained increasing popularity in both academic and practical circles.More than 400 plant species have been identified to have potential for soil and water remediation.Among them,Thlaspi,Brassica,Sedum alfredii H.,and Arabidopsis species have been mostly studied.It is also expected that recent advances in biotechnology will play a promising role in the development of new hyperaccumulators by transferring metal hyperaccumulating genes from low biomass wild species to the higher biomass producing cultivated species in the times to come.This paper attempted to provide a brief review on recent progresses in research and practical applications of phytoremediation for soil and water resources.
基金the PhD Fund of the National Education Ministry of China (No20030284038)the Interna-tional Foundation for Science (NoW/4215)
文摘Four assessment methods (two pollution indexes and two fuzzy mathematical models) were employed to investigate the environmental quality of four soils around a ferroalloy plant in Nanjing City. Environmental quality was assessed as class Ⅳ (moderately polluted) for each soil with single-factor index method, and was identified to be classes Ⅳ, Ⅲ (slightly polluted), Ⅲ, and Ⅲ for soils A, B, C, and D, respectively, with the comprehensive index model. In comparison with the single-factor index method, the comprehensive index model concerned both dominant parameter and average contribution of all factors to the integrated environmental quality. Using the two fuzzy mathematical methods (single-factor deciding and weighted average models), the environmental risks were determined to be classes Ⅳ, Ⅲ, Ⅱ (clean), and Ⅱ for soils A, B, C, and D, respectively. However, divergence of the membership degree to each pollution class still occurred between the two methods. In fuzzy mathematical methods, membership functions were used to describe the limits between different pollution degrees, and different weights were allocated for the factors according to pollution contribution. Introduction of membership degree and weight of each factor to fuzzy mathematical models made the methods more reasonable in the field of environmental risk assessment.
基金Project supported by the National Natural Science Foundation of China (No. 40371056)the Foundation for the Author of NationalExcellent Doctoral Dissertation of China (No. 200149)
文摘Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent susceptibility (Xfd) showed the absence of superparamagnetic (SP) grains in the samples. The IRM20mT (isothermal remanent magnetization at 20 mT) being linearly proportional to SIRM (saturation isothermal remanent magnetization) (R^2=0.901), suggested that ferrimagnetic minerals were responsible for the magnetic properties of automobile emission particulates. The average contents of Cu, Cd, Pb and Fe in automobile emission particulates were 95.83, 22.14, 30.58 and 34727.31 mg/kg, respectively. Significant positive correlations exist between the magnetic parameters and the contents ofPb, Cu and Fe. The magnetic parameters of automobile emission particulates reflecting concentration of magnetic particles increased linearly with increase of Pb and Cu content, showed that the magnetic measurement could be used as a preliminary index for detection of Pb and Cu pollution.
基金Project supported by the National Basic Research Program (973) of China (Nos. 2005CB121104 and 2002CB410804)the National Natural Science Foundation of China (No. 40471064)the Natural Science Foundation of Zhejiang Province (No. R306011), China
文摘Soils can often be contaminated simultaneously by more than one heavy metal. The sorption-desorption behavior of a metal in a soil will be affected by the presence of other metals. Therefore, selective retention and competitive adsorption of the soils to heavy metals can affect their availability and movement through the soils. In this study, the simultaneous competitive adsorption of four heavy metals (Cd, Cu, Hg, and Pb) on ten agricultural soils collected from the Changjiang and Zhujiang deltas, China was assessed. The results showed that the competition affected the behavior of heavy metal cations in such a way that the soils adsorbed less Cd and Hg, and more Pb and Cu with increasing total metal concentrations, regardless of the molar concen- tration applied. As the applied concentrations increased, Pb and Cu adsorption increased, while Cd and Hg adsorption decreased. The adsorption sequence most found was Pb>Cu>Hg>Cd. The maximum adsorption capacity for the heavy metal cations was calculated, and affected markedly by soil properties. The results suggest that Hg and Cd have higher mobility associated to the lower adsorption and that Pb and Cu present the opposite behavior. Significant correlations were found between the maximum adsorption capacity of the metals and pH value and exchangeable acid, suggesting that soil pH and exchangeable acid were key factors controlling the solubility and mobility of the metals in the agricultural soils.
基金supported by "SUST Spring Bud" Project (Grant no.2008AZZ110)National Key Technology R&D Program of China project (Grant no.2006BAJ15B02)
文摘Reconstructing long-term vegetation buffers along streams in agricultural landscapes has become a common environmental restoration strategy for improving water quality and wildlife habitat connectivity.This article developed a linear weighted model to rank the priority of agricultural sub-basins for the establishment of vegetative buffers.The method was applied to an agricultural watershed of 146 km2 in Ontario,Canada.The watershed was divided into 11 sub-basins as basic decision units.In each subbasin,four stream buffer schemes with widths of 5,10,15 and 20m were generated.For each buffer,three benefit-cost attributes of reconstructing vegetation cover were estimated,which include acreage per dollar,sediment abatement per dollar and habitat benefit per dollar.These attributes were first normalized using a linear normalization approach to eliminate the effects across different units.The normalized attributes were then integrated using a simple additive weighting method to rank the 11 sub-basins for prioritizing spatial restoration action.A sensitivity analysis was also conducted to observe the impact of a change in attribute weights on the management decisions.The results suggest that vegetation buffers reconstructed for achieving the water quality goal are not effective in improving habitat connectivity and vice versa.
文摘Referring to GB5618-1995 about heavy metal pollution,and using statistical analysis SPSS,the major pollutants of mine area farmland heavy metal pollution were identified by variable clustering analysis.Assessment and classification were done to the mine area farmland heavy metal pollution situation by synthetic principal components analysis (PCA).The results show that variable clustering analysis is efficient to identify the principal components of mine area farmland heavy metal pollution.Sort and clustering were done to the synthetic principal components scores of soil sample,which is given by synthetic principal components analysis.Data structure of soil heavy metal contaminations relationships and pollution level of different soil samples are discovered.The results of mine area farmland heavy metal pollution quality assessed and classified with synthetic component scores reflect the influence of both the major and compound heavy metal pol- lutants.Identification and assessment results of mine area farmland heavy metal pollution can provide reference and guide to propose control measures of mine area farmland heavy metal pollution and focus on the key treatment region.
文摘Significant quantities of slag are generated as waste material or by-product every day from steel industries. They usually contain considerable quantities of valuable metals and materials. Transforming these solid wastes from one form to another to be reused either by the same production unit or by different industrial installation is very much essential not only for conserving metals and mineral resources but also for protecting the environment. The sustainable development concept requires a more efficient management of waste materials and preservation of environment. The paper presents the basic characteristics of slag, analyses and it's modification by incorporating some essential plant nutrients and the possibility of its application as fertilizer was studied.
文摘The current status of catalytic reforming in China is reviewed and a forecastof the development in a couple of years or a decade is given. Distinguished from the past decade,the future trend will be focused on revamps, expansions, higher severity, diversified feeds,combination with other processes for higher product quality, and novel catalysts and equipment.