略论云南省喀斯特地区的环境特征和经济发展模式

本文系统总结了云南省喀斯特地区的普遍特征和近几年来国内外喀斯特地区在环境治理和经济发展方面取得的经验和存在的问题 ,并结合云南省内各喀斯特地区的特点 ,提出了云南喀斯特地区环境保护和经济发展的模式。

Environmental Regulation,Pollution Treatment Productivity,and Industrial Environmental TFP in China

Amidst growing environmental protection intensity by the Chinese government, this paper investigates the effects of environmental regulation on China＇s industrial pollution treatment productivity and environmental TFP. By estimating China＇s pollution treatment productivity between 2001 and 2008 and analyzing environmental regulation intensity and the effects of the relevant factors and pollution treatment productivity using panel data, this paper discovers that （1） pollution treatment productivity contributed a significant share of about 40% to industrial environmental TFP during the investigation period; （2） environmental regulation may not necessarily cause adverse impacts on pollution treatment efficiency and productivity but demonstrates a U-shaped relationship： when the share of pollution treatment cost in industrial value-added is above the range of 3.8%-5.1%, environmental regulation is likely to promote pollution treatment productivity and thus environmental TFP Judging by the estimation result, enhancing environmental protection and expediting the development of ecological civilization are conducive to China ＂s economic transition towards an intensive, efficient, circular, and sustainable development pattern. China＇s current industrial development has the capacity to tolerate a rather demanding level of pollution treatment and management and China needs to further rely on energy conservation and the environmental production industries to promote the progress of pollution treatment technologies.

Factors affecting ice crystal purity during freeze concentration process for urine treatment

Freeze concentration has great potential in treating wastewaters containing soluble pollutions. It is important for freeze concentration process to produce ice crystals with large size and high purity. In this work raw urines of 4660 -7914 mg/L in COD, 512. 71 -872. 41 mg/L in NH3 -N and 22600 -28800 μs/cm in electric conductivity were studied. Urines were frozen by a digital refrigerated circulator bath. Ice crystals were purified by ice-water steep and vacuum filtration. The COD, NH3 - N, and electric conductivity levels of the melted ices were measured to reflect ice crystal purity. Effects of coolant temperature, ice crystal shape, initial solution temperature, solution concentration, ice seeding, re-crystallization process and crystallization time on ice crystal purity were analyzed. The results show that an appropriate coolant temperature, suspended ice crystals, an initial solution temperature of about 6 ℃, introduction of seed ice, addition of re-crystallization process, and crystallization time of less than 30 min axe in favor of producing ice crystals with high purity. Under such conditions, more than 99 percent of inorganic salts, COD and NH3 - N sources in raw urine could he removed.

Polychlorinated dibenzo-p-dioxins and dibenzofurans in flue gas emissions from municipal solid waste incinerators in China

Polychlorinated dibenzo-p-dioxins and furans （PCDD/Fs） emissions in flue gas from two types of municipal solid waste incinerators （MSWIs） most commonly used in China were investigated in this study. The selected incinerators include two grate-type MSWIs： MSWI-A （350 t/d） and MSWI-B 050 t/d）, and two fluidized bed MSWIs： MSWI-C （400 t/d） and MSWI-D （400 t/d）, which are all equipped with semi-dry lime scrubber and bag filter except MSWI-D equipped with cyclone and wet scrubber （WS） as air pollutant control device （APCD）. Results indicated that the emission concentration and the international toxic equivalents （I-TEQs） of the PCDD/Fs from the stacks were in the range of 1.210-10.273 ng/Nm^3 and 0.019-0.201 ng I-TEQ/Nm^3, respectively. They were greatly lower than the emission regulation standard of PCDD/Fs in China （1.0 ng I-TEQ/Nm^3）. However, only the PCDD/Fs emission level from MSWI-C was below 0.1 ng I-TEQ/Nm^3. Although the homologue profiles were distinct, the contributions of the 2,3,7,8-subsituted congeners to the total I-TEQ were similar among all the investigated MSWIs. Two major 2,3,7,8-substituted congeners, 2,3,4,7,8-PeCDF and 1,2,3,7,8-PeCDD, account for 47% and 9% （average values） of the total I-TEQ values, respectively. The correlation between PCDD/Fs levels and composition of flue gas was also discussed.

Comparative analysis of hydrogen-producing bacteria and its immobilized cells for characteristics of hydrogen production

A strain of hydrogen producing bacteria was immobilized by polyvinyl alcohol-boric acid method, with the addition of a small amount of calcium alginate. The immobilized cells were insensitive to the presence of traces of O2. Moreover, the immobilized cells increased both the evolution rate and the yield of hydrogen production. Batch experiments with a medium containing 10 g/L glucose demonstrated the yields of hydrogen production by the immobilized and free cells were 2.14 mol/mol glucose and 1.69 mol/mol glucose, respectively. In continuous cultures at medium retention time of 2.0 h, the yield and the evolution rate of hydrogen production by the immobilized cells were 2.31 mol/mol glucose and 1 435.4 ml/（L·h） respectively. However, at medium retention time of 6.0 h, the yield and the evolution rate of hydrogen production by free cells were only 1.75 mol/mol glucose and 362.9 ml/（L·h）, respectively.

Fuzzy Control of Nitrate Recirculation and External Carbon Addition in A/O Nitrogen Removal Process

Nitrogen and phosphorous concentrations of effluent water must be taken into account for the design and operation of wastewater treatment plants. In addition, the requirement for effluent quality is becoming strict. Therefore, intelligent control approaches are recently required in removing biological nutrient. In this study, fuzzy control has been successfully applied to improve the nitrogen removal. Experimental results showed that a close relationship between nitrate concentration and oxidation-reduction potential (ORP) at the end of anoxic zone was found for anoxic/oxic (A/O) nitrogen removal process treating synthetic wastewater. ORP can be used as online fuzzy control parameter of nitrate recirculation and external carbon addition. The established fuzzy logic controller that includes two inputs and one output can maintain ORP value at - 86 mV and - 90 mV by adjusting the nitrate recirculation flow and external carbon dosage respectively to realize the optimal control of nitrogen removal, improving the effluent quality and reducing the operating cost.

ECOLOGICAL RESTORATION:OUR HOPE FOR THE FUTURE?

Ecological restoration is widely employed from tens to millions of hectares in space,and from tens of days to thousands of years in time, which forces consideration of it thoroughly. We argue that three questions are the most important among the contents relevant of ecological restoration, including why, what and how to restore degraded systems. Why to restore determines whether or not the degraded ecological systems should be restored. What to restore is the goal of ecological restoration. The explicit goal of ecological restoration is necessary to guide ecological restoration workers in pursuit of excellence and prevent restoration from being swamped by purely technological activities. And how to restore means the methods and steps we should apply. To ensure the final success of ecological restoration, restored sites should be monitored and managed for long time to determine whether the selected methods are appropriate, and can be remedy better. Only to deal with these effectively, ecological restoration would be the hope for the future.

Degradation of 4-Chlorophenol Solution by Synergetic Effect of Dual-frequency Ultrasound with Fenton Reagent

4-Chlorophenol (4-CP) solution was treated by dual-frequency ultrasound inconjunction with Fenton reagent, and obvious improvement in the 4-CP degradation rate was observedin this advanced oxidation process. Experimental results showed that ultrasonic intensity,saturating gas and pH value affected greatly the 4-CP removal rate. Among four different saturatinggases (Ar, O_2, air and N_2), 4-CP degradation with Ar-saturated solution was the best. However, inthe view of practical wastewater treatment, using oxygen as the saturating gas would be moreeconomical. The addition of Fenton reagent followed the first-order kinetics and increased the 4-CPdegradation rate. The 4-CP removal rate increased by around 126% within 15 min treatment. Thesynergetic effect of dual-frequency ultrasound with Fenton reagent on 4-CP degradation was obviouslyobserved.

A Framework of Environmental Modelling and Information Sharing for Urban Air Pollution Control and Management

More effective environmental pollution control and management are needed due to the increasing environ-mental impacts from a range of human activities and the growing public demands for a better living environment. Urban air pollution is a serious environmental issue that poses adverse impacts on the health of people and the environment in most metropolitan areas. In this paper,we propose a geoinformatics augmented framework of environmental modelling and information sharing for supporting effective urban air pollution control and management. This framework is out-lined in terms of its key components and processes including: 1) an integrated,adaptive network of sensors for envi-ronmental monitoring; 2) a set of distributed,interoperable databases for data management; 3) a set of intelligent,robust algorithms and models for environmental modelling; 4) a set of flexible,efficient user interfaces for data access and in-formation sharing; and 5) a reliable,high capacity,high performance computing and communication infrastructure for integrating and supporting other framework components and processes.

A New Method for Effluent Treatment System Design

this paper mainly discusses the design of distributed effluenttreatment systems with single contami- nant. A new method is putforward and four basic rules are provided. The key point of themethod is that global optimality is obtained by guaranteeing theoptimality of each step taken in the design. Costs per unit mass ofremoved contaminant are used as a scale to choose the nextcombination of an effluent stream and a treatment process. Theremaining problem is updated after each choice. As for multiplecontaminants, a two-stage method is adopted.

Mountain Water Tower and Ecological Risk Estimation of the Mesta-Nestos Transboundary River Basin (Bulgaria-Greece)

The Mesta-Nestos river basin in Bulgaria and Greece is a case study for transboundary decision-making support in south-eastern Europe and a show-case for the development of methodologies and information-gathering for the integrated regional planning of water resources. Land-use conflicts in this water-scarce region cover a wide spectrum of activities like agricultural irrigation, drinking water production, diversions for industrial water, and risk of pollution from mining, to name a few examples. Measurements of the water quality were carried out in the upper basin. Results will be illustrated by the example of the environmental situation in the alpine region of the Pirin National Park as well as in the Razlog Basin with a stronger anthropogenic impact and pollution around a former uranium mine near the village of Elesnica. The social and economic development of this transboundary region is a recently established priority for mean an increase in water usage the water resources if regional the future. It will and more stress for impacts of global climate change are verified. Problem-focused management of the catchment area as a whole on the basis of proved geo-data sets is needed for the future.

Performance of BAC process for treatment of micro-polluted water

Biological activated carbon (BAC) has been developed on the granular activated carbon by immobilization of selected and acclimated species of bacteria to treat the micro-polluted water. The BAC removal efficiencies for nitrobenzene, permanganate index, turbidity and ammonia were investigated. Effects of shock loading and SEM (Scanning Electron Microscope) observation on BAC were studied. Backwashing and its intensity of BAC were also discussed. The results showed that BAC took short time to start up and recover to the normal condition after shock loading. The shock loading studies showed that the removal efficiency of BAC was not completely inhibited even at high concentration of nitrobenzene. Backwashing performed once every 10-20 d, or an average of 15 d. Backwashing intensity was 12-14 L/(s·m2) with air and 3-4 L/(s·m2) with water.

Breakthrough Technologies for the Biorefining of Organic Solid and Liquid Wastes

Organic solid and liquid wastes contain large amounts of energy, nutrients, and water, and should not be perceived as merely waste. Recycling, composting, and combustion of non-recyclables have been practiced for decades to capture the energy and values from municipal solid wastes. Treatment and disposal have been the primary management strategy for wastewater. As new technologies are emerging, alternative options for the utilization of both solid wastes and wastewater have become available. Considering the complexity of the chemical, physical, and biological properties of these wastes, multiple technologies may be required to maximize the energy and value recovery from the wastes. For this purpose, biorefin- ing tends to be an appropriate approach to completely utilize the energy and value available in wastes. Research has demonstrated that non-recyclable waste materials and bio-solids can be converted into usable heat, electricity, fuel, and chemicals through a variety of processes, and the liquid waste streams have the potential to support crop and algae growth and provide other energy recovery and food production options. In this paper, we propose new biorefining schemes aimed at organic solid and liquid wastes from municipal sources, food and biological processing plants, and animal production facilities. Four new breakthrough technologies-namely, vacuum-assisted thermophilic anaerobic digestion, extended aquaponics, oily wastes to biodiesel via glycerolysis, and microwave-assisted thermochemical conversion-can be incorporated into the biorefining schemes, thereby enabling the complete utilization of those wastes for the production of chemicals, fertilizer, energy （biogas, syngas, biodiesel, and bio-oil）, foods, and feeds, and resulting in clean water and a significant reduction in pollutant emissions.

Degradation of chlorophenol by in－situ electrochemically generated oxidant

A novel in-situ electrochemical oxidation method was applied to the degradation of wastewater containing chlorophenol. Under oxygen sparging, the strong oxidant, hydrogen dioxide, could be in-situ generated through the reduction of oxygen on the surface of the cathode. The removal rate ofchlorophenol could be increased 149% when oxygen was induced in the electrochemical cell. The promotion factor was estimated to be about 82.63% according to the pseudo-first-order reaction rate constant (min^-1). Important operating parameters such as current density, sparged oxygen rate were investigated. Higher sparged oxygen rate could improve the degradation of chlorophenol. To make full use of oxygen, however, sparged oxygen rate of 0.05 m3/h was adopted in this work. Oxidation-reduction potential could remarkably affect the generation of hydrogen peroxide. It was found that the removal rate of chlorophenol was not in direct proportion to the applied current density. The optimum current density was 3.5 mA/cm^2 when initial chlorophenol concentration was 100 mg/L and sparged oxygen rate was 0.05 m^3/h.

State Space Approach to Mass Exchange Network Synthesis

State space approach is an effective method to mass-exchange network (MEN) synthesis. By decomposing the network into two interactive parts, a distribution network and a process operator, the synthesis problem can be formulated into a mixed integer nonlinear programming (MINLP) model. In this article, a generalized state space model based on typical MEN is established and verified in two cases. A new asymmetrical operator and cost index are also adopted to speed up the solution process. The results demonstrate the efficiency of the proposed approach.

Composition and distribution of main pollution trace element in water environment of mining subsidence

The impact on these water bodies of the surrounding coal production activities and the power plant through research the content and characteristics of harmful trace elements in coal contained in these water bodies.F,Hg,Se and As these four trace ele- ments increased 0.92%,0.78%,0.70% and 0.81% respectively in Datong mining subsi- dence pool from November 2004 to November 2006;the four elements increased 1.58%, 1.23%,1.08% and 0.92% respectively in Xie'er mining subsidence pool;the four ele- ments increased 1.16%,1.06%,1.02% and 1.01% respectively in Pansan mining sub- sidence pool.The conclusions show that the absolute values of F,Hg,Se and As in mining subsidence pool are relate with their background value,while the increase in their concen- tration and their environment of mine and electricity plant surrounded are closely linked.

Inactivation of Giardia by Ozone and Its Disinfect Mechanisms

This study was to investigate the effect of ozone （ O3 ） inactivation on Giardia in water by the fluorescence staining method. In order to elucidate the dominant mechanisms of inactivation, cell surface or inner cell components damage were comparatively examined by scanning dectron microscopy （SEM）. Results suggested that O3 had a stronger effect on inactivating capability. Firstly, when the concentration of O3 was above 2.0 mg/L and the contact time was up to 5 min, it showed a significant inactivating effect. Secondly, the effect of turbidity on inactivation was also found to be significant in synthetic water; when turbidity increased, the inactivating effect decreased. Thirdly, the inactivating rates were improved with a temperature increase from 5 to 25℃, but decreased when the temperature were out of this range. The inactivating capability of O3 was stronger under acidic conditions than alkalic conditions. Lastly, when the concentration of organic matter in the reactive system was increased, probably due to the competition between G/ard/a and organics on O3, the inactivating rate was decreased; in addition, the cellular morphology of Giardia varied with different contact times. At contact time of 30 s, cells were rotundity and sphericity; at 60 s they became folded, underwent emboly, and burst; and at 240 s, the cell membrane of Giardia shrinked and collapsed completely.

Problems of drinking water treatment along Ismailia Canal Province, Egypt

The present drinking water purification system in Egypt uses surface water as a raw water supply without a preliminary filtration process.On the other hand,chlorine gas is added as a disinfectant agent in two steps,pre-and post-chlorination.Due to these reasons most of water treatment plants suffer low filtering effectiveness and produce the trihalomethane(THM) species as a chlorination by-product.The Ismailia Canal represents the most distal downstream of the main Nile River.Thus its water contains all the proceeded pollutants discharged into the Nile.In addition,the downstream reaches of the canal act as an agricultural drain during the closing period of the High Dam gates in January and February every year.Moreover,the wide industrial zone along the upstream course of the canal enriches the canal water with high concentrations of heavy metals.The obtained results indicate that the canal gains up to 24.06×106 m3 of water from the surrounding shallow aquifer during the closing period of the High Dam gates,while during the rest of the year,the canal acts as an influent stream losing about 99.6×106 m3 of its water budget.The reduction of total organic carbon(TOC) and suspended particulate matters(SPMs) should be one of the central goals of any treatment plan to avoid the disinfectants by-products.The combination of sedimentation basins,gravel pre-filtration and slow sand filtration,and underground passage with microbiological oxidation-reduction and adsorption criteria showed good removal of parasites and bacteria and complete elimination of TOC,SPM and heavy metals.Moreover,it reduces the use of disinfectants chemicals and lowers the treatment costs.However,this purification system under the arid climate prevailing in Egypt should be tested and modified prior to application.

Research on ground water pollution by ieacheate of waste dump of open pit coal mine

On the basis of investigation and research on the pollution source and pollution pathway of Yujiagou area,by the ground water quality analysis and the leaching and soaking experiments of the gangue,reliable data were obtained.The experiment results prove that these inorganic salt elements are easily dissolved by the water.The main pollu- tion factors in the ground water are consisted with the main pollution factor in the leading water of the gangue.By synthetically analyzing,a conclusion is shown that the salts in the leacheate of the waste dump of open pit coal mine are the primary pollution source for groundwater of Yujiagou area.An assessment is made about the degree of pollution of the ground water in the study area.

Water Environment Pollution in Three-Gorge Reservoir Area and Treatment Technology

After the erection of Three-Gorge Reservoir, the water environment in the reservoir area will be turned into water bodies like lakes, and the self-clarification ability of water will also be much slower than ever. Now, the quality of water in most segments in upper reaches of Yangtze River cannot meet the requirements of l-ll class Environment Quality Standard (GHZB1-1999). In Yangtze River, dialing River and Wujiang River, the main indexes such as colon bacillus, nonionic ammonia, chemical oxygen demand (COD), petroleum, phenol, total phosphorus (TP), heavy metal, etc., have exceeded the standard limits. The water bodies of the reservoir area are facing serious risk of eutrophicationm. To solve that problem, a countermea-sure of multi-spot diverted treatment and separate discharge is recommended. For doing this, lots of small-scale wastewater treatment facilities employing updated activated sludge treatment technologies are to be set up. Up to now, a number of sewage treatment technologies to control eutrophication of water have been developed, which include processes of sequencing batch activated sludge (SBR), absorbing bio-degradation (AB), oxidation channel, package intermittent aeration system (PIAS), intermittent cycle extended aeration system (ICEAS), UNITANK and so on. The Effective one to be applied in the reservoir area should convey the requirements of ecological agriculture, forestry and urban planning, and be accompanied by legal support for appropriate exploitation of natural resources.