飞机螺旋桨在服役过程中由于地域性差异和天气的变化可能会遇到各种苛刻的环境。因此,理想的飞机螺旋桨用橡胶复合材料必须具备极好的超疏水性能、延迟结冰性能和环境耐久性。本文通过模板法和高温处理制备了硅橡胶超疏水表面,研究了低...飞机螺旋桨在服役过程中由于地域性差异和天气的变化可能会遇到各种苛刻的环境。因此,理想的飞机螺旋桨用橡胶复合材料必须具备极好的超疏水性能、延迟结冰性能和环境耐久性。本文通过模板法和高温处理制备了硅橡胶超疏水表面,研究了低温冷冻、高温加热和紫外辐照对超疏水硅橡胶疏水性能的影响。此外,为了揭示超疏水硅橡胶在空气湿度影响下的延迟冻结行为,设计了延迟结冰装置,并利用扫描电子显微镜(Scanning electron microscopy,SEM)和能谱仪(Enery dispersive spectrometer,EDS)分析了超疏水性能的变化和延迟冻结机理。结果表明,制备的超疏水硅橡胶具有良好的环境耐久性和延迟冻结性能,在飞机螺旋桨超疏水电热防冰方面具有实际应用价值。展开更多
This paper presents an experimental study on the alkali-resistant properties of basalt fiber reinforced polymers (BFRP) bars under a typical concrete environment. BFRP bars were embedded in concrete and exposed to d...This paper presents an experimental study on the alkali-resistant properties of basalt fiber reinforced polymers (BFRP) bars under a typical concrete environment. BFRP bars were embedded in concrete and exposed to different aggressive environments, including tap water, saline solution and ambient temperature environments, to study the effects of the type of solution and relative humidity (RH) on the durability of BFRP. Meanwhile, BFRP bars were directly immersed in an alkaline solution for comparison. The acceleration factor describing the relationship between the alkaline solution immersion and the moisture-saturated concrete was also obtained. Aging was accelerated with a temperature of 60 ℃. The results show that the chloridion in the saline solution does not have any harmful effects on the degradation of the concrete-encased BFRP bars. Contact with an alkaline (high pH) concrete pore-water solution is the primary reason for the degradation of the BFRP bars. The degradation rate of concrete-encased BFRP bars is accelerated when a high temperature and a high humidity are present simultaneously. The degradation rate of the BFRP bars is relatively quick at the initial stage and slows down with exposure time. Results show that the degradation of 2.18 years in moisture-saturated concrete at 60 ℃corresponds to that of one year when directly immersed in an alkaline solution (other conditions remaining the same) for the BFRP bars analyzed.展开更多
Raining and sun-shining processes in natural climate were simulated by water spraying and infrared lightshining alternately as wetting-drying cycles in accelerated durability test. The accelerating effects of the wet-...Raining and sun-shining processes in natural climate were simulated by water spraying and infrared lightshining alternately as wetting-drying cycles in accelerated durability test. The accelerating effects of the wet-ting-drying cycles and the variation of corrosion current density and corrosion potential of steel bar in concrete undersuch conditions were studied. The result shows that the main reason leading to accelerating corrosion of steel bar inconcrete is the wetting-drying cycles, which can cause the increase of corrosion potential difference between the an-ode and cathode of steel bar corrosion cell and the decrease of concrete resistance. Corrosion rate of the steel bar inconcrete under four typical conditions, including wetting-drying cycle, long time submerging in water, long time ex-posure to indoor and outdoor environment were measured and compared. The test results indicate that the corrosionrates under the four typical conditions are in the order of spraying and infrared light shining cycles, outdoor environ-ment, indoor environment, and submerging in water, respectively.展开更多
A reliability-based quantitative durability design methodology is presented for reinforced concrete(RC)structures in the marine environment on the basis of natural exposure data derived from four berths(1.5,1.5,4 and ...A reliability-based quantitative durability design methodology is presented for reinforced concrete(RC)structures in the marine environment on the basis of natural exposure data derived from four berths(1.5,1.5,4 and 15 years)of a concrete port.More than 200 chloride profiles are obtained and analyzed.The relationship between nominal surface chloride ion concentration and altitude is discussed.Subsequently,the formula of the apparent chloride diffusion coefficient is proposed with consideration of the surrounding temperature,sodium chloride solution concentration,age factor and altitude.Then,the reliability-based method to predict the durability of RC structures is developed according to Fick s second law.Relationships between the predicted penetration depth of the chloride ion,the ratio of the wetting time per-period and the corresponding altitude are discussed.Subsequently,the environmental zonation methodology is established for concrete structures under a marine chloride environment by considering the ratio of the wetting time per-period of concrete as the zoning index.Finally,the corres-ponding durability design method for each zone level is established,which contains the durability design regulations of the specimen,and correction coefficients for different water/binder ratios,ages,temperatures and chloride ion concentrations.展开更多
This study aims to reveal the mechanism that how the content of steel fibers and strength grades affect the macro performance of the ultra-high performance fiber reinforced cementitious composite (UHPFRCC) and to st...This study aims to reveal the mechanism that how the content of steel fibers and strength grades affect the macro performance of the ultra-high performance fiber reinforced cementitious composite (UHPFRCC) and to study the UHPFRCC durability under the combined effect of loads and environments. Three types of high and ultra-high performance fiber reinforced cement composites with different strength grades (100, 150, 200 MPa) and different steel fiber volume fractions (0%, 1%, 2%, 3%) are prepared. The main properties of mechanical performance and short-term durability are studied. A preloading frame is designed to apply a four- point load external flexural stress with a stress selection ratio of 0.5 for UHPFRCC150 specimens. The results show that the growth in strength grade with a proper content of steel fiber greatly increases the strength and toughness of the HPFRCC and the UHPFRCC while decreasing the dry-shrinkage ratio. For the loaded specimens, the existence of steel fiber can reduce the negative influence of tensile stress on the Cl- penetration resistance of the UHPFRCC in addition to improving its ability to resist the freeze-thaw damage.展开更多
Defects in protective-coating systems on steel surfaces are inevitable in practical engineering applications. A composite coating system, including a primer, middle coat and topcoat, were used to protect carbon steel ...Defects in protective-coating systems on steel surfaces are inevitable in practical engineering applications. A composite coating system, including a primer, middle coat and topcoat, were used to protect carbon steel from corrosion in a marine environment. Two environmental additives, glass fibers and thiourea, were applied in the middle coat to modify the coating system. The long-term corrosion durability and self-healing ability of the scratched coating system were evaluated by multiple methods. Results of the electrochemical technologies indicated that the coating system that contained 0.5 wt.% fibers and 0.5 wt.% thiourea presented good corrosion protection and self-healing for carbon steel when immersed in 3.5% NaCl for 120 d. Evolution of localized corrosion factors with time, as obtained from the current distribution showed that fibers combined with thiourea could inhibit the occurrence of local corrosion in scratched coating systems and retarded the corrosion development significantly. Surface characterization suggested that adequate thiourea could be absorbed tmiformly on fibers for a long time to play an important role in protecting the carbon steel. Finally, schematic models were established to demonstrate the action of fibers and thiourea on the exposed surface of the carbon steel and the scratched coating system in the entire deterioration process.展开更多
基金supported by Sichuan Science and Technology Plan Project(No.23NSFSC1923)the special fund support for Basic Scientific Research Business Expenses of Central Universities(No.J2023-033).
文摘飞机螺旋桨在服役过程中由于地域性差异和天气的变化可能会遇到各种苛刻的环境。因此,理想的飞机螺旋桨用橡胶复合材料必须具备极好的超疏水性能、延迟结冰性能和环境耐久性。本文通过模板法和高温处理制备了硅橡胶超疏水表面,研究了低温冷冻、高温加热和紫外辐照对超疏水硅橡胶疏水性能的影响。此外,为了揭示超疏水硅橡胶在空气湿度影响下的延迟冻结行为,设计了延迟结冰装置,并利用扫描电子显微镜(Scanning electron microscopy,SEM)和能谱仪(Enery dispersive spectrometer,EDS)分析了超疏水性能的变化和延迟冻结机理。结果表明,制备的超疏水硅橡胶具有良好的环境耐久性和延迟冻结性能,在飞机螺旋桨超疏水电热防冰方面具有实际应用价值。
基金The National Key Basic Research Program of China(973 Program)(No.2012CB026200)the Key Project of Chinese Ministry of Education(No.113029A)+1 种基金the National Key Technology R&D Program of China during the 12th Five Year Plan Period(No.2011BAB03B09)the Fundamental Research Funds for the Central Universities
文摘This paper presents an experimental study on the alkali-resistant properties of basalt fiber reinforced polymers (BFRP) bars under a typical concrete environment. BFRP bars were embedded in concrete and exposed to different aggressive environments, including tap water, saline solution and ambient temperature environments, to study the effects of the type of solution and relative humidity (RH) on the durability of BFRP. Meanwhile, BFRP bars were directly immersed in an alkaline solution for comparison. The acceleration factor describing the relationship between the alkaline solution immersion and the moisture-saturated concrete was also obtained. Aging was accelerated with a temperature of 60 ℃. The results show that the chloridion in the saline solution does not have any harmful effects on the degradation of the concrete-encased BFRP bars. Contact with an alkaline (high pH) concrete pore-water solution is the primary reason for the degradation of the BFRP bars. The degradation rate of concrete-encased BFRP bars is accelerated when a high temperature and a high humidity are present simultaneously. The degradation rate of the BFRP bars is relatively quick at the initial stage and slows down with exposure time. Results show that the degradation of 2.18 years in moisture-saturated concrete at 60 ℃corresponds to that of one year when directly immersed in an alkaline solution (other conditions remaining the same) for the BFRP bars analyzed.
基金Project(50078054) supported by National Natural Science Foundation of China and Youth Scientific Research Fund of CUMT
文摘Raining and sun-shining processes in natural climate were simulated by water spraying and infrared lightshining alternately as wetting-drying cycles in accelerated durability test. The accelerating effects of the wet-ting-drying cycles and the variation of corrosion current density and corrosion potential of steel bar in concrete undersuch conditions were studied. The result shows that the main reason leading to accelerating corrosion of steel bar inconcrete is the wetting-drying cycles, which can cause the increase of corrosion potential difference between the an-ode and cathode of steel bar corrosion cell and the decrease of concrete resistance. Corrosion rate of the steel bar inconcrete under four typical conditions, including wetting-drying cycle, long time submerging in water, long time ex-posure to indoor and outdoor environment were measured and compared. The test results indicate that the corrosionrates under the four typical conditions are in the order of spraying and infrared light shining cycles, outdoor environ-ment, indoor environment, and submerging in water, respectively.
基金The National Natural Science Foundation of China(No.51508162)
文摘A reliability-based quantitative durability design methodology is presented for reinforced concrete(RC)structures in the marine environment on the basis of natural exposure data derived from four berths(1.5,1.5,4 and 15 years)of a concrete port.More than 200 chloride profiles are obtained and analyzed.The relationship between nominal surface chloride ion concentration and altitude is discussed.Subsequently,the formula of the apparent chloride diffusion coefficient is proposed with consideration of the surrounding temperature,sodium chloride solution concentration,age factor and altitude.Then,the reliability-based method to predict the durability of RC structures is developed according to Fick s second law.Relationships between the predicted penetration depth of the chloride ion,the ratio of the wetting time per-period and the corresponding altitude are discussed.Subsequently,the environmental zonation methodology is established for concrete structures under a marine chloride environment by considering the ratio of the wetting time per-period of concrete as the zoning index.Finally,the corres-ponding durability design method for each zone level is established,which contains the durability design regulations of the specimen,and correction coefficients for different water/binder ratios,ages,temperatures and chloride ion concentrations.
基金The Technical Research Program from NV Bekaert SA of Belgium (No. 8612000003)the National Natural Science Foundation of China (No. 50908047)
文摘This study aims to reveal the mechanism that how the content of steel fibers and strength grades affect the macro performance of the ultra-high performance fiber reinforced cementitious composite (UHPFRCC) and to study the UHPFRCC durability under the combined effect of loads and environments. Three types of high and ultra-high performance fiber reinforced cement composites with different strength grades (100, 150, 200 MPa) and different steel fiber volume fractions (0%, 1%, 2%, 3%) are prepared. The main properties of mechanical performance and short-term durability are studied. A preloading frame is designed to apply a four- point load external flexural stress with a stress selection ratio of 0.5 for UHPFRCC150 specimens. The results show that the growth in strength grade with a proper content of steel fiber greatly increases the strength and toughness of the HPFRCC and the UHPFRCC while decreasing the dry-shrinkage ratio. For the loaded specimens, the existence of steel fiber can reduce the negative influence of tensile stress on the Cl- penetration resistance of the UHPFRCC in addition to improving its ability to resist the freeze-thaw damage.
基金Supported by the Open Project of Key Laboratory of Marine New Materials of CNITECH(No.LMMT-KFKT-2014-008)the National Basic Research Program of China(973 Program)(No.2014CB643304)
文摘Defects in protective-coating systems on steel surfaces are inevitable in practical engineering applications. A composite coating system, including a primer, middle coat and topcoat, were used to protect carbon steel from corrosion in a marine environment. Two environmental additives, glass fibers and thiourea, were applied in the middle coat to modify the coating system. The long-term corrosion durability and self-healing ability of the scratched coating system were evaluated by multiple methods. Results of the electrochemical technologies indicated that the coating system that contained 0.5 wt.% fibers and 0.5 wt.% thiourea presented good corrosion protection and self-healing for carbon steel when immersed in 3.5% NaCl for 120 d. Evolution of localized corrosion factors with time, as obtained from the current distribution showed that fibers combined with thiourea could inhibit the occurrence of local corrosion in scratched coating systems and retarded the corrosion development significantly. Surface characterization suggested that adequate thiourea could be absorbed tmiformly on fibers for a long time to play an important role in protecting the carbon steel. Finally, schematic models were established to demonstrate the action of fibers and thiourea on the exposed surface of the carbon steel and the scratched coating system in the entire deterioration process.