[Objective] Many strata emerge in the high-quality tea producing area in Qionglai Mountains,which belongs to Mesozoic Cretaceous(K),Mingshan Fm(E1-2mn)and Dayi conglomerate Team(N)of Cenozoic Tertiary System as well a...[Objective] Many strata emerge in the high-quality tea producing area in Qionglai Mountains,which belongs to Mesozoic Cretaceous(K),Mingshan Fm(E1-2mn)and Dayi conglomerate Team(N)of Cenozoic Tertiary System as well as Quaternary System(Q).Analysis on the migrating features of soil heavy metal from each stratum to tea leaves showed that the enrichment ability of elements was Cu>Cd>Zn>Ni>Hg>As>Cr>Pb.By comparing the soil background values with the soil base values of Sichuan hilly area and Chengdu economic region,it could be concluded that Cd,Hg,Mo,Pb and Se were enriched,and other metal elements existed at a level close to that of the comparing areas.The pH was a little acidic,and high quality tea cultivation could be developed here at present.With the increase of human activities,the environment of study area tends to deteriorate.Therefore,land planning and use should be reasonable.The government should control the environment nearby and prevent pollution.展开更多
NIH 3T3 cells, a mouse fibroblast cell line used as routine target cells for transfection experiments, undergo spontaneous transformation in our experiments after they form a confluent sheet in medium containing fetal...NIH 3T3 cells, a mouse fibroblast cell line used as routine target cells for transfection experiments, undergo spontaneous transformation in our experiments after they form a confluent sheet in medium containing fetal bovina serum (FBS) or lower coneentrafcion of calf serum (CS). The transformation takes the form of foci of multiplying cells among the surrounding cells which have stopped cell division. However, no focus of transformed cells could be seen in medium containing high concentration (10%) of OS. Further experiments indicated that the frequency of transformation is highly dependent on the concentration of serum and the transformation in OS is changeable when the cells are passaged in FBS. 8H-thymidine autoradiography has been proved to be a sensitive measurement indicator for foous formation. Our results suggest that the high frequency of transformation and its dependence on confmenoy as well as on medium composition are characteristics of cell differentiation rather than mutation. The role of the NIH 3T3 cell line as a cancer-initiated cell population and its accelerated transformation by rat oncogene might be considered as a form of tumor promotion is discussed.展开更多
2,2’,7,7’-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9’-spirobifluorene(spiro-OMeTAD), as the most commonly used hole transport material(HTM), plays a significant role in the normal structured(n-i-p) high-efficiency ...2,2’,7,7’-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9’-spirobifluorene(spiro-OMeTAD), as the most commonly used hole transport material(HTM), plays a significant role in the normal structured(n-i-p) high-efficiency perovskite solar cells(PSCs). In general, it is prepared by a halogen solvent(chlorobenzene, CBZ) and needs an ion dopant(lithium bis(trifluoromethanesulfonyl)imide, Li-TFSI) to improve its conductivity and hole mobility. However, such a halogen solvent is not environmentally friendly and the widely used LiTFSI dopant would affect the stability of PSCs. Herein, we develop a non-halogen solvent-tetrahydrofuran(THF)-prepared spiro-OMeTAD solution with a new p-type dopant,potassium bis(fluorosulfonyl)imide(K-FSI), to apply into PSCs. By this strategy, high-hole-mobility spiro-OMeTAD film is achieved. Meanwhile, the potassium ions introduced by diffusion into perovskite surface passivate the interfacial defects. Therefore, a hysteresis-free champion PSC with an efficiency of 21.02% is obtained, along with significantly improved stability against illumination and ambient conditions. This work provides a new strategy for HTMs toward hysteresis-free high-efficiency and stable PSCs by substituting dopants.展开更多
基金Supported by International Special Funds to Finance the Construction of Modern Agricultural Technology SystemYouth Science and Technology Foundation of Sichuan Province(09ZQ026-019)Economic and Trade Commission Project of Technological Innovationin Sichuan Province(High Technology Innovation of Famous GreenTea Flavor)
文摘[Objective] Many strata emerge in the high-quality tea producing area in Qionglai Mountains,which belongs to Mesozoic Cretaceous(K),Mingshan Fm(E1-2mn)and Dayi conglomerate Team(N)of Cenozoic Tertiary System as well as Quaternary System(Q).Analysis on the migrating features of soil heavy metal from each stratum to tea leaves showed that the enrichment ability of elements was Cu>Cd>Zn>Ni>Hg>As>Cr>Pb.By comparing the soil background values with the soil base values of Sichuan hilly area and Chengdu economic region,it could be concluded that Cd,Hg,Mo,Pb and Se were enriched,and other metal elements existed at a level close to that of the comparing areas.The pH was a little acidic,and high quality tea cultivation could be developed here at present.With the increase of human activities,the environment of study area tends to deteriorate.Therefore,land planning and use should be reasonable.The government should control the environment nearby and prevent pollution.
文摘NIH 3T3 cells, a mouse fibroblast cell line used as routine target cells for transfection experiments, undergo spontaneous transformation in our experiments after they form a confluent sheet in medium containing fetal bovina serum (FBS) or lower coneentrafcion of calf serum (CS). The transformation takes the form of foci of multiplying cells among the surrounding cells which have stopped cell division. However, no focus of transformed cells could be seen in medium containing high concentration (10%) of OS. Further experiments indicated that the frequency of transformation is highly dependent on the concentration of serum and the transformation in OS is changeable when the cells are passaged in FBS. 8H-thymidine autoradiography has been proved to be a sensitive measurement indicator for foous formation. Our results suggest that the high frequency of transformation and its dependence on confmenoy as well as on medium composition are characteristics of cell differentiation rather than mutation. The role of the NIH 3T3 cell line as a cancer-initiated cell population and its accelerated transformation by rat oncogene might be considered as a form of tumor promotion is discussed.
基金financially supported by the National Key Research and Development Plan (2019YFE0107200 and 2017YFE0131900)the National Natural Science Foundation of China (21875178 and 91963209)Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory (XHD2020-001 and XHT2020-005)。
文摘2,2’,7,7’-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9’-spirobifluorene(spiro-OMeTAD), as the most commonly used hole transport material(HTM), plays a significant role in the normal structured(n-i-p) high-efficiency perovskite solar cells(PSCs). In general, it is prepared by a halogen solvent(chlorobenzene, CBZ) and needs an ion dopant(lithium bis(trifluoromethanesulfonyl)imide, Li-TFSI) to improve its conductivity and hole mobility. However, such a halogen solvent is not environmentally friendly and the widely used LiTFSI dopant would affect the stability of PSCs. Herein, we develop a non-halogen solvent-tetrahydrofuran(THF)-prepared spiro-OMeTAD solution with a new p-type dopant,potassium bis(fluorosulfonyl)imide(K-FSI), to apply into PSCs. By this strategy, high-hole-mobility spiro-OMeTAD film is achieved. Meanwhile, the potassium ions introduced by diffusion into perovskite surface passivate the interfacial defects. Therefore, a hysteresis-free champion PSC with an efficiency of 21.02% is obtained, along with significantly improved stability against illumination and ambient conditions. This work provides a new strategy for HTMs toward hysteresis-free high-efficiency and stable PSCs by substituting dopants.
