An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with tert-butyl-hydroperoxide catalyzed by titanium silicalite 1 （TS-1） in ambient-temper...An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with tert-butyl-hydroperoxide catalyzed by titanium silicalite 1 （TS-1） in ambient-temperature ionic liquid [emim]BF4. Good yield and higher selectivity of products were found in the ionic liquid compared with in molecular solvent. The research results showed 13.2% conversion of cyclohexane, 97.6% cyclohexanol and cyclohexanone selectivity were obtained in ionic liquid under mild conditions of 90℃.展开更多
基金Supported by the National Natural Science Foundation of China （20776037）.
文摘An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with tert-butyl-hydroperoxide catalyzed by titanium silicalite 1 （TS-1） in ambient-temperature ionic liquid [emim]BF4. Good yield and higher selectivity of products were found in the ionic liquid compared with in molecular solvent. The research results showed 13.2% conversion of cyclohexane, 97.6% cyclohexanol and cyclohexanone selectivity were obtained in ionic liquid under mild conditions of 90℃.
