Hursts rescaled range (R/S) analysis and Wolfs attractor reconstruction technique have been adopted to estimate the local fractal dimensions and the local largest Lyapunov exponents in terms of the time series pressur...Hursts rescaled range (R/S) analysis and Wolfs attractor reconstruction technique have been adopted to estimate the local fractal dimensions and the local largest Lyapunov exponents in terms of the time series pressure fluctuations obtained from a gas liquid solid three phase self aspirated reversed flow jet loop reactor,respectively.The results indicate that the local fractal dimensions and the local largest Lyapunov exponents in both the jet region and the tubular region inside the draft tube increase with the increase in the jet liquid flowrates and the solid loadings,the local fractal dimension profiles are similar to those of the largest Lyapunov exponent,the local largest lyapunov exponents are positive for all cases,and the flow behavior of such a reactor is chaotic.The local nonlinear characteristic parameters such as the local fractal dimension and the local largest Lyapunov exponent could be applied to further study the flow properties such as the flow regime transitions and flow structures of this three phase jet loop reactor.展开更多
Pickering emulsions stabilized by salicylic acid and arginine modified titanium dioxide （TiO2-SA-Arg） nanopar- tides were prepared in this study for photocatalytic degradation of nitrobenzene in a rotating annular r...Pickering emulsions stabilized by salicylic acid and arginine modified titanium dioxide （TiO2-SA-Arg） nanopar- tides were prepared in this study for photocatalytic degradation of nitrobenzene in a rotating annular reactor, and the effects of various design parameters of the rotating annular reactor, initial nitrobenzene concentration, catalyst amount, and solution pH on the degradation rate of nitrobenzene were investigated. Meanwhile, the degradation mechanism of nitrobenzene was proposed. The results show that increasing the aeration rate, the rotational speed, and light intensity results in a higher photocatalytic degradation rate of nitrobenzene owing to the effective clearance of electrons and a high quantity of oxidative free radicals. The degradation of nitroben- zene in the rotating annular reactor follows the pseudo first-order kinetics, but it is not well described by the Langmuir-Hinshdwood equation. Aeration has a significant effect on the photocatalytic degradation pathway of nitrobenzene. Because nitrobenzene can undergo reduction reaction as electron acceptors and oxidative deg- radation initiated by hydroxyl free radicals, the photocatalytic degradation of nitrobenzene follows the reduction mechanism under no aeration, but the oxidation mechanism under aeration.展开更多
文摘Hursts rescaled range (R/S) analysis and Wolfs attractor reconstruction technique have been adopted to estimate the local fractal dimensions and the local largest Lyapunov exponents in terms of the time series pressure fluctuations obtained from a gas liquid solid three phase self aspirated reversed flow jet loop reactor,respectively.The results indicate that the local fractal dimensions and the local largest Lyapunov exponents in both the jet region and the tubular region inside the draft tube increase with the increase in the jet liquid flowrates and the solid loadings,the local fractal dimension profiles are similar to those of the largest Lyapunov exponent,the local largest lyapunov exponents are positive for all cases,and the flow behavior of such a reactor is chaotic.The local nonlinear characteristic parameters such as the local fractal dimension and the local largest Lyapunov exponent could be applied to further study the flow properties such as the flow regime transitions and flow structures of this three phase jet loop reactor.
文摘Pickering emulsions stabilized by salicylic acid and arginine modified titanium dioxide （TiO2-SA-Arg） nanopar- tides were prepared in this study for photocatalytic degradation of nitrobenzene in a rotating annular reactor, and the effects of various design parameters of the rotating annular reactor, initial nitrobenzene concentration, catalyst amount, and solution pH on the degradation rate of nitrobenzene were investigated. Meanwhile, the degradation mechanism of nitrobenzene was proposed. The results show that increasing the aeration rate, the rotational speed, and light intensity results in a higher photocatalytic degradation rate of nitrobenzene owing to the effective clearance of electrons and a high quantity of oxidative free radicals. The degradation of nitroben- zene in the rotating annular reactor follows the pseudo first-order kinetics, but it is not well described by the Langmuir-Hinshdwood equation. Aeration has a significant effect on the photocatalytic degradation pathway of nitrobenzene. Because nitrobenzene can undergo reduction reaction as electron acceptors and oxidative deg- radation initiated by hydroxyl free radicals, the photocatalytic degradation of nitrobenzene follows the reduction mechanism under no aeration, but the oxidation mechanism under aeration.
