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环己烷存在下环糊精诱导a-溴代萘室温燐光 被引量:14
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作者 谢剑炜 许金钩 +1 位作者 陈国珍 刘长松 《中国科学(B辑)》 CSCD 北大核心 1996年第3期269-274,共6页
微量环己烷存在下,β-环糊精能诱导α-溴代萘发射强的室温燐光.发光光谱、燐光寿命和荧光偏振的实验证实了β-环糊精一环已烷一α-溴代萘三元包络物的形成.测定了三元包络物的表观形成常数,讨论了环已烷对β-环糊精诱导α-溴代萘室温燐... 微量环己烷存在下,β-环糊精能诱导α-溴代萘发射强的室温燐光.发光光谱、燐光寿命和荧光偏振的实验证实了β-环糊精一环已烷一α-溴代萘三元包络物的形成.测定了三元包络物的表观形成常数,讨论了环已烷对β-环糊精诱导α-溴代萘室温燐光的影响机制. 展开更多
关键词 环糊环 己烷 Α-溴代萘 室温磷光
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Homomorphism and Isomorphism of Regular Power Ring 被引量:3
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作者 姚炳学 《Chinese Quarterly Journal of Mathematics》 CSCD 2000年第2期23-28,共6页
The upgrade of all kinds of algebraic structures has been emphasized with the development of fuzzy mathematics.The concept of hypergroup was raised first by Prof.LI Hong_xing in [1]and HX ring was done in [2].In thi... The upgrade of all kinds of algebraic structures has been emphasized with the development of fuzzy mathematics.The concept of hypergroup was raised first by Prof.LI Hong_xing in [1]and HX ring was done in [2].In this paper ,some properties of power ring and quasi_quotient ring are further studied based on paper [3~6].Especially,several theorems of homomorphism and isomorphism of regular power ring are established. 展开更多
关键词 subsemiring semiideal HX ring power ring regular power ring quasi_quotient ring
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Synthesis and Characterization of Peralkylated β-Cyclodextrins Used as Gas Chromatographic Stationary Phasest
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作者 戴荣继 傅若农 +1 位作者 冯宗财 周伟 《Journal of Beijing Institute of Technology》 EI CAS 1994年第2期144-154,共11页
Six peralkylated β- cyclodec\xtrins used as capillary gas chromatographic stationary phases were prepared and characterized by differential by differential scannning calorimetry(DSC) and pyrolysis gas chromatograp... Six peralkylated β- cyclodec\xtrins used as capillary gas chromatographic stationary phases were prepared and characterized by differential by differential scannning calorimetry(DSC) and pyrolysis gas chromatography (PyGC). The DSC profiles illustrated that the peralkylated β-cyclodextrins synthesized possess the supercoooled state and the glass state below their melting point The PYGC results showed that the long-chain alkylated β-cyclodextrins are more thermostable than the short-chain. one All ofthese peralkylated β-cyclodextrins are suitable for use as capillary column gas chromatographic stationary phases,which can easily be coatal on the fused silica capilary columns and have nice chromatographic retention behaviour. For example, the capillary colunns coated with these materials can excellently separate three methylphenol isomers and six dimehylphenol isomers. 展开更多
关键词 CYCLODEXTRIN gas chromatography/peralkylated cyclodextrin
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Mechanism and Kinetics of Thermal Dissociation of Inclusion Complex of β-Cyclodextrin and 1-Methylcyclopropene 被引量:5
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作者 Yi He Ting Sun 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2006年第1期89-92,共4页
The inclusion-complex of CD-MCP (β-cyclodextrin (β-CD) including 1-methylcyclopropene (1-MCP)) was prepared and characterized. Basing on programmed-heating procedure and weight-temperature analysis, as well as... The inclusion-complex of CD-MCP (β-cyclodextrin (β-CD) including 1-methylcyclopropene (1-MCP)) was prepared and characterized. Basing on programmed-heating procedure and weight-temperature analysis, as well as the application of Satava-Sestak's, Ozawa's and Kissinger's methods, the mechanism and kinetics of thermal dissociation of this inclusion complex were studied. An additional mass loss is found at 170-180℃. The mechanism of thermal dissociation of CD-MCP is dominated by a one-dimensional random nucleation and subsequent growth process (A2/3). The activation energy Es and the pre-exponential factor AS for the process are 102.14 kJ/mol and 3.63×10^10s^-1, respectively. This ES value shows that there is no strong chemical intere, ctions between β-CD and 1-MC;P, 展开更多
关键词 1-methylcyclopropene Β-CYCLODEXTRIN Inclusion complex KINETICS MECHANISM Thermal dissociation
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