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现场表面拉曼光谱研究Fe-Mo合金诱导共沉积 被引量:2
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作者 牛振江 姚士冰 周绍民 《物理化学学报》 SCIE CAS CSCD 北大核心 1998年第12期1074-1079,共6页
现场表面拉曼光谱结果显示,在0.2mol·L-1Na2MoO4,pH=4.0的溶液中,电位正于0.5V(vsSCE)时只观察到多钼酸盐的拉曼峰(940、880和450cm-1).负于-0.5V时,出现中心位于730cm-1的宽峰.同时电极表面有蓝色膜生成.表明混合... 现场表面拉曼光谱结果显示,在0.2mol·L-1Na2MoO4,pH=4.0的溶液中,电位正于0.5V(vsSCE)时只观察到多钼酸盐的拉曼峰(940、880和450cm-1).负于-0.5V时,出现中心位于730cm-1的宽峰.同时电极表面有蓝色膜生成.表明混合氧化态(MO(Ⅳ),MO(Ⅴ))氧化膜的形成.730cm-1的峰在-1.9V时仍然存在,说明氧化膜没有被进一步还原.在钼酸钠溶液中同时含有0.1mol·L-1FeSO4和0.2mol·L-1柠檬酸时,中间态氧化膜的拉曼峰的中心移到740cm-1.且峰强度随着电位从-1.3V负移到-1.9V而逐渐减弱并最终消失.电极表面沉积层呈银白色,说明由于Fe2+的存在,钼的中间态氧化膜的结构发生了变化,能够被进一步还原形成Fe-Mo合金,表现出诱导共沉积的特征. 展开更多
关键词 现场表面 拉曼光谱 铁钼合金 诱导共沉积
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轧机主减速机轴承座孔的现场表面修复实践 被引量:2
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作者 王银军 王孝建 冯华北 《通用机械》 2007年第4期41-42,共2页
应用“堆焊后镗削修复”、“电刷镀修复”这两种表面维修技术,先后两次成功对轧机的主减速机轴承座孔进行现场抢修。
关键词 轴承座孔 堆焊 镗削 电刷镀 现场表面修复
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现场表面增强红外光谱法研究离子液体中锌电沉积过程:水的影响
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作者 于奥秋 周尉 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2018年第5期630-637,共8页
利用离子液体[Emim]BF4作为电解液,研究了不同锌盐种类对提高锌电沉积过程效率的影响.分别将4种锌盐Zn(BF4)2、ZnCl2、ZnSO4、Zn(NO3)2添加到离子液体中,循环伏安结果表明引入ZnCl2可以达到较高的电流密度以及较好的反应可逆性.在此基础... 利用离子液体[Emim]BF4作为电解液,研究了不同锌盐种类对提高锌电沉积过程效率的影响.分别将4种锌盐Zn(BF4)2、ZnCl2、ZnSO4、Zn(NO3)2添加到离子液体中,循环伏安结果表明引入ZnCl2可以达到较高的电流密度以及较好的反应可逆性.在此基础上,进一步研究了微量水对锌电沉积过程的影响,发现体积比为5%的水的引入可以使锌的沉积电位正移,提高反应电流密度,并同时提高体系可逆性.综合考虑电极反应电流密度、可逆性及锌盐溶解度,本文选择较为理想的ZnCl2作为锌盐,对其在无水离子液体体系及有水体系分别进行了现场表面增强红外光谱法研究,对锌电沉积过程中的电极界面结构进行了分析,得到了不同电位下电极的界面结构示意图. 展开更多
关键词 离子液体 锌电沉积 可逆性 现场表面增强红外光谱 界面结构
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现场表面增强红外光谱法研究离子液体/电极界面结构 被引量:1
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作者 许源荣 齐成紫 +2 位作者 印仁和 成旦红 周尉 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2014年第2期163-168,174,共7页
采用现场表面增强红外光谱法(SEIRAS)对金电极与离子液体1-丁基-3-甲基咪唑三氟甲基磺酸盐([Bmim][OTf])的界面电化学双电层结构进行了研究.循环伏安结果表明离子液体[Bmim][OTf]在金电极上的电化学窗口为4.0 V以上.SEIRAS结果显示阴阳... 采用现场表面增强红外光谱法(SEIRAS)对金电极与离子液体1-丁基-3-甲基咪唑三氟甲基磺酸盐([Bmim][OTf])的界面电化学双电层结构进行了研究.循环伏安结果表明离子液体[Bmim][OTf]在金电极上的电化学窗口为4.0 V以上.SEIRAS结果显示阴阳离子在电极表面上发生脱吸附的电位区间以及阳离子和阴离子在电极表面上发生竞争的共吸附,同时阴阳离子在金电极界面上的脱吸附有显著的延迟效应产生,其原因与离子的表面吸附能和马德龙(Madelung)位能综合作用有关. 展开更多
关键词 离子液体 双电层 现场表面增强红外光谱 延迟效应
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过渡金属表面γ-氨丙基三甲氧基硅烷膜的研究
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作者 陈惠 沈晓英 +2 位作者 顾伟 顾仁敖 任斌 《光散射学报》 2003年第3期143-148,共6页
本文对在过渡金属铁、镍电极表面制备得到的γ-氨丙基三甲氧基硅烷(γ-APS)膜进行了研究。实验中对硅烷膜用X-射线光电子能谱(XPS)、现场表面增强拉曼散射光谱(SERS)和原子力显微镜(AFM)进行了表征。X-射线光电子能谱(XPS)的结果发现存... 本文对在过渡金属铁、镍电极表面制备得到的γ-氨丙基三甲氧基硅烷(γ-APS)膜进行了研究。实验中对硅烷膜用X-射线光电子能谱(XPS)、现场表面增强拉曼散射光谱(SERS)和原子力显微镜(AFM)进行了表征。X-射线光电子能谱(XPS)的结果发现存在两个N1s峰,表明γ-APS膜中的氨基有两种存在方式:自由氨基和质子化氨基。实验中还发现现场表面增强拉曼散射光谱(SERS)是研究金属/γ-APS体系中界面层结构非常有效的手段,SERS结果表明硅醇羟基和氨基发生了竞争吸附,且γ-APS分子在外加电位等条件的影响下吸附状态会发生一定变化。原子力显微镜(AFM)的表征结果在微观上显示电极表面的γ-APS膜上形成了一种较规则的微孔结构,这种结构可能与基底的性质有关。 展开更多
关键词 过渡金属 γ-氨丙基三甲氧基硅烷膜 现场表面增强拉曼散射光谱 X-射线光电子能谱 原子力显微镜
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氯甲酚纳米乳消毒剂的消毒效果观察 被引量:3
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作者 穆素雨 柳东阳 +5 位作者 白渊哲 杨万云 师玉露 李爽 宁梦夏 杨雪峰 《中国兽医杂志》 CAS 北大核心 2016年第5期35-37,共3页
利用物体表面现场消毒试验方法,观察了氯甲酚纳米乳消毒剂的消毒效果。结果表明,氯甲酚纳米乳消毒剂的消毒效果随消毒剂浓度的升高和作用时间的延长而增强。当高于0.1%氯甲酚纳米乳消毒剂对卫生间水泥地面的自然菌作用5 min以上时,杀灭... 利用物体表面现场消毒试验方法,观察了氯甲酚纳米乳消毒剂的消毒效果。结果表明,氯甲酚纳米乳消毒剂的消毒效果随消毒剂浓度的升高和作用时间的延长而增强。当高于0.1%氯甲酚纳米乳消毒剂对卫生间水泥地面的自然菌作用5 min以上时,杀灭对数值均大于1,消毒合格;0.5%氯甲酚纳米乳消毒剂对兔舍地面的自然菌作用10 min以上,高于1.0%氯甲酚纳米乳消毒剂作用5 min以上时,杀灭对数值均大于1,消毒合格。结果提示,氯甲酚纳米乳消毒剂的消毒效果良好,值得在畜牧兽医实践中推广应用。 展开更多
关键词 氯甲酚 纳米乳 消毒剂 物体表面现场消毒试验
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Preliminary validation of SMOS sea surface salinity measurements in the South China Sea 被引量:3
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作者 任永政 董庆 贺明霞 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2015年第1期262-271,共10页
The SMOS(soil moisture and ocean salinity) mission undertaken by the European Space Agency(ESA) has provided sea surface salinity(SSS) measurements at global scale since 2009.Validation of SSS values retrieved from SM... The SMOS(soil moisture and ocean salinity) mission undertaken by the European Space Agency(ESA) has provided sea surface salinity(SSS) measurements at global scale since 2009.Validation of SSS values retrieved from SMOS data has been done globally and regionally.However,the accuracy of SSS measurements by SMOS in the China seas has not been examined in detail.In this study,we compared retrieved SSS values from SMOS data with in situ measurements from a South China Sea(SCS) expedition during autumn 2011.The comparison shows that the retrieved SSS values using ascending pass data have much better agreement with in situ measurements than the result derived from descending pass data.Accuracy in terms of bias and root mean square error(RMS) of the SSS retrieved using three different sea surface roughness models is very consistent,regardless of ascending or descending orbits.When ascending and descending measurements are combined for comparison,the retrieved SSS using a semi-empirical model shows the best agreement with in situ measurements,with bias-0.33 practical salinity units and RMS 0.74.We also investigated the impact of environmental conditions of sea surface wind and sea surface temperature on accuracy of the retrieved SSS.The SCS is a semi-closed basin where radio frequencies transmitted from the mainland strongly interfere with SMOS measurements.Therefore,accuracy of retrieved SSS shows a relationship with distance between the validation sites and land. 展开更多
关键词 sea surface salinity (SSS) soil moisture and ocean salinity (SMOS) sea surface roughnessmodel South China Sea (SCS)
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Impacts of internal waves on chlorophyll a distribution in the northern portion of the South China Sea 被引量:3
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作者 杨顶田 叶海彬 王桂芬 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2010年第5期1095-1101,共7页
Internal waves can bring nutrients to the upper level of water bodies and facilitate phytoplankton photosynthesis.Internal waves occur frequently in the northern portion of the South China Sea and inflict an important... Internal waves can bring nutrients to the upper level of water bodies and facilitate phytoplankton photosynthesis.Internal waves occur frequently in the northern portion of the South China Sea and inflict an important effect on chlorophyll a distribution.In this study,in-situ observation and satellite remote sensing data were used to study the effects of internal waves on chlorophyll a distribution.Based on the in-situ observations,lower chlorophyll a concentrations were present in the middle and bottom level in areas in which internal waves occur frequently,while the surface chlorophyll a distribution increased irregularly,and a small area with relatively higher chlorophyll a concentrations was observed in the area around the Dongsha Island.Satellite remote sensing showed that the chlorophyll a concentration increased in the area near Dongsha Island,where internal waves frequently occurred.The results of the increased chlorophyll a concentration in the surface water near Dongsha Island in the northern portion of the South China Sea indicated that internal waves could uplift phytoplankton and facilitate phytoplankton growth. 展开更多
关键词 internal waves chlorophyll a distribution northern South China Sea
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Intelligent Camera for Surface Defect Inspection
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作者 CHENG Wan-sheng ZHAO Jie WANG Ke-cheng 《Semiconductor Photonics and Technology》 CAS 2007年第1期33-38,共6页
An intelligent camera for surface defect inspection is presented which can pre-process the surface image of a rolled strip and pick defective areas out at a spead of 1 600 meters per minute. The camera is made up of a... An intelligent camera for surface defect inspection is presented which can pre-process the surface image of a rolled strip and pick defective areas out at a spead of 1 600 meters per minute. The camera is made up of a high speed line CCD, a 60 Mb/s CCD digitizer with correlated double sampling function, and a field programmable gate array(FPGA), which can quickly distinguish defective areas using a perceptron embedded in FPGA thus the data to be further processed would dramatically be reduced. Some experiments show that the camera can meet high producing speed, and reduce cost and complexity of automation surface inspection systems. 展开更多
关键词 intelligent camera surface defect inspection FPGA PERCEPTRON
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A surface-based hiding function linking flume and field data 被引量:1
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作者 ZHANG LiGuo FU XuDong DUAN Jennifer G 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2017年第10期1560-1569,共10页
The quantification of the sheltering and exposure effects of non-uniform sediments has been widely achieved through hiding function models. Big challenge exists so far in the model parameter that is highly variable an... The quantification of the sheltering and exposure effects of non-uniform sediments has been widely achieved through hiding function models. Big challenge exists so far in the model parameter that is highly variable and differs greatly between laboratory flumes and field streams. This paper presents an improved surface-based hiding fimction. The force balance for particle inception was formulated and the allocation of the overall bed shear stress into each group of sediments was mimicked. The new hiding function was examined against and agrees well with the documented field and flume data. It was shown that the hiding fimction is closely related to the relative flow depth and the reference elevation in the velocity profile in addition to the bed material gradation. The power law of velocity profile that applies to both flume flows and natural streams can link the flume and field data together. The hiding function with b = 1/6 and b = 1/2 is applicable to natural streams and laboratory flumes, respectively. The value orb = 0.263 also works well for gravel bed rivers. The range of the reference elevation, namely z0 = 0.4Dm-1.4Dm, is recommended for either the flume or field data. The new hiding function contributes to addressing clearer physical meanings and a useful perspective for further improvement. 展开更多
关键词 hiding function relative flow depth flume and field data reference elevation
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