The influence of the interaction between surrounding rock and lining on the long-term behaviour of a tunnel in service is significant.In this paper,we proposed a mechanical model of the circular lined tunnel with the ...The influence of the interaction between surrounding rock and lining on the long-term behaviour of a tunnel in service is significant.In this paper,we proposed a mechanical model of the circular lined tunnel with the alterable mechanical property under hydrostatic stress and radially inner surface pressure of the lining.The alterable mechanical properties of the surrounding rock and the lining are embodied by the changing of their elasticity modulus with service time and radial direction of the tunnel,respectively.The proposed mechanical model is successfully validated by comparison with the existing theoretical models and the numerical simulation,respectively.The influences of the main parameters of the proposed mechanical model,such as the radial power-law indexes and the time-varying coefficients of the surrounding rock and the lining,as well as the radially inner surface pressure of the lining,on the interface displacement and pressure between surrounding rock and lining are investigated.The research results can provide some valuable references for timely diagnosis and correct evaluation of the long-term behaviours of a tunnel in service.展开更多
Tunnel water inrush is one of the common geological disasters in the underground engineering construction.In order to effectively evaluate and control the occurrence of water inrush,the risk assessment model of tunnel...Tunnel water inrush is one of the common geological disasters in the underground engineering construction.In order to effectively evaluate and control the occurrence of water inrush,the risk assessment model of tunnel water inrush was proposed based on improved attribute mathematical theory.The trigonometric functions were adopted to optimize the attribute mathematical theory,avoiding the influence of mutation points and linear variation zones in traditional linear measurement functions on the accuracy of the model.Based on comprehensive analysis of various factors,five parameters were selected as the evaluation indicators for the model,including tunnel head pressure,permeability coefficient of surrounding rock,crushing degree of surrounding rock,relative angle of joint plane and tunnel section size,under the principle of dimension rationality,independence,directness and quantification.The indicator classifications were determined.The links among measured data were analyzed in detail,and the objective weight of each indicator was determined by using similar weight method.Thereby the tunnel water inrush risk assessment model is established and applied in four target segments of two different tunnels in engineering.The evaluation results and the actual excavation data agree well,which indicates that the model is of high credibility and feasibility.展开更多
This study examines the socio-spatial context of uneven development and the residential accessibility of green space in Dalian of Liaoning Province, China. The social fairness was analyzed with a community scale as th...This study examines the socio-spatial context of uneven development and the residential accessibility of green space in Dalian of Liaoning Province, China. The social fairness was analyzed with a community scale as the basis. We combined social scientific methods with a GIS method using a behavior accessibility model from the perspectives of fairness of urban green space allocation based on social geography, geographic information science, management science and many other related discipline theories. The results show that: 1) Most of the urban green space distribution presents an unbalanced phenomenon, and it does not match with the population distribution; 2) We found some differences in the accessibility of the population with different attributes and opportunities to use and enjoy the urban green spaces, mainly due to: the dual social and spatial attributes of the residents and the serious stratum differentiation generated were the internal causes; the residential space differentiation and the pursuit of economic and real estate development were the direct causes; and unreasonable planning, in regard to the fact that government policies did not give consideration to efficiency and fairness, was also an important factor.展开更多
By using the dynamic characteristic of one direction S-rough sets(one direction singular rough sets) and dual of one direction S-rough sets(dual of one direction singular rough sets), the concepts of attribute dis...By using the dynamic characteristic of one direction S-rough sets(one direction singular rough sets) and dual of one direction S-rough sets(dual of one direction singular rough sets), the concepts of attribute disturbance of knowledge, the attribute disturbance degree of knowledge, and the disturbance coefficient of knowledge are given. By employing these concepts, the cardinal order theorem of the attribute disturbance knowledge, the unit circle theorem of the attribute disturbance knowledge, and the discernible theorem of the attribute disturbance knowledge are presented.展开更多
Although the high diversity of plant species in the rupestrian fields has been primarily attributed to the existence of a set of distinct habitats, few studies support this assertion. The present study aimed to furthe...Although the high diversity of plant species in the rupestrian fields has been primarily attributed to the existence of a set of distinct habitats, few studies support this assertion. The present study aimed to further investigate the relationship between physical and chemical attributes of soils with the diversity of plant species in this unique ecosystem. The rupestrian field is a unique vegetation formation that covers some of the southeastern Brazilian mountains in the transition of the Atlantic rain forest and the Cerrado(savanna). Different habitats occur according to soil characteristics(e.g., presence of rocks, sand, fertility, hydrology, etc.). These attributes ultimately influence the vegetation that is highly adapted to the harsh edaphic and climatic mountain conditions. Five distinct habitats were studied by us: rocky outcrops, peat bogs, sandy bogs, quartz gravel fields, and "cerrado"(savanna). A floristic survey indicated that four families are found at greater frequency: Poaceae, Asteraceae, Cyperaceae, and Leguminosae. The greatest diversity of plant species was found in the rocky outcrops habitat, followed by cerrado, peat bog, quartz gravel grassland, and sandy bogs, respectively. The main difference in the floristic composition among these habitats was related to the dominant species. Trachypogon spicatus(Poaceae) was the most dominant species in the rocky outcrops, Axonopus siccus(Poaceae) in the peat bogs, Lagenocarpus rigidus(Cyperaceae) in the sandy bogs, Schizachyrium tenerum(Poaceae) in the cerrado, while Vellozia sp. 8(Velloziaceae) dominated the vegetation in the quartz gravel grassland. This study demonstrated that physical and chemical soil properties strongly related the diversity of plant species occurring in the different habitats of rupestrian fields.展开更多
The intensive management practices in greenhouse production may alter the soil physicochemical properties and contribute to the accumulation of heavy metals(HMs). To determine the HM concentrations in vegetable soil i...The intensive management practices in greenhouse production may alter the soil physicochemical properties and contribute to the accumulation of heavy metals(HMs). To determine the HM concentrations in vegetable soil in relation to soil physicochemical properties and cultivation age, we conducted a soil survey for typical greenhouse soils in Shouguang, China. The results indicated that Cd is a major HM pollutant in the tested soils, as the only HM element exceeding the allowed limit for vegetable soil. The surveyed data was analyzed with regression analysis, correlation analysis and canonical correspondence analysis(CCA). A positive correlation is observed between HM pollution level and cultivation age. CCA results suggest that the HM pollution level and distribution in soil are significantly affected by soil physicochemical properties, which was a function of years of cultivation as revealed by regression analysis. In summary, cultivation age is an important factor to affect soil physicochemical properties(organic matter and inorganic nutrients) as well as HM contamination.展开更多
This work constitutes a contribution to the study of the physical-chemical performance of some heavy metals and micro-nutrients in the Argan trees. The samples are harvested from small Argan trees, three samples (soi...This work constitutes a contribution to the study of the physical-chemical performance of some heavy metals and micro-nutrients in the Argan trees. The samples are harvested from small Argan trees, three samples (soil, wood, leaves) per tree. The content of various heavy metals and micro-nutrient in aerial parts (leaves, wood and soil) were analyzed in the Argan tree by the method of ICP-ES. The results of analysis of data for the chemical variables were measured for several trees at different measurement times, do not affect the dispersion of the data. The use of chemometrics has allowed us to interpret the results obtained especially those related to the characterization of heavy metals and micro-nutrient after calibration by variable regression of these results in order to get an overall estimate of the optimal content, and to follow changes in the methods of treatment. The results of the characteristics of Argan trees have been treated using the statistical method of Principal Component Analysis (MFA), The MFA was used to analyze the three groups simultaneously. These groups are fairly similar.展开更多
We introduce here a work package for a National Natural Science Foundation of China Major Project. We propose to develop computational methodology starting from the theory of electronic excitation processes to predict...We introduce here a work package for a National Natural Science Foundation of China Major Project. We propose to develop computational methodology starting from the theory of electronic excitation processes to predicting the opto-electronic property for organic materials, in close collaborations with experiments. Through developing methods for the electron dynamics, considering superexchange electronic couplings, spin-orbit coupling elements between excited states, electron-phonon relaxation, intermolecular Coulomb and exchange terms we combine the statistical physics approaches including dynamic Monte Carlo, Boltzmann transport equation and Boltzmann statistics to predict the macroscopic properties of opto-electronic materials such as light-emitting efficiency, charge mobility, and exciton diffusion length. Experimental synthesis and characterization of D-A type ambipolar transport material as well as novel carbon based material will provide a test ground for the verification of theory.展开更多
Graphitized nanocarbon materials can be an ideal catalyst support for heterogeneous catalytic systems. Their unique physical and chemical properties, such as large surface area, high adsorption capacity, excellent the...Graphitized nanocarbon materials can be an ideal catalyst support for heterogeneous catalytic systems. Their unique physical and chemical properties, such as large surface area, high adsorption capacity, excellent thermal and mechanical stability, outstanding electronic properties, and tunable porosity, allow the anchoring and dispersion of the active metals. Therefore, currently they are used as the key support material in many catalytic processes. This review summarizes recent relevant applications in supported catalysts that use graphitized nanocarbon as supports for catalytic oxidation, hydrogenation, dehydrogenation, and C-C coupling reactions in liquid-phase and gas-solid phase-reaction systems. The latest developments in specific features derived from the morphology and characteristics of graphitized na- nocarbon-supported metal catalysts are highlighted, as well as the differences in the catalytic behavior of graphitized nano- carbon-supported metal catalysts versus other related cata- lysts. The scientific challenges and opportunities in this field are also discussed.展开更多
基金supported by the Innovation Research Team of High-Level Local Universities in Shanghai [SHSM U-ZDCX20212801]Shanghai Jiao Tong University School of M edicine-Nursing Development ProgramClinical Research Fund from Health Commission of Shanghai [202140514]
基金Project(U1934210) supported by the Key Project of High-speed Rail Joint Fund of National Natural Science Foundation of ChinaProject(8202037) supported by the Natural Science Foundation of Beijing,China。
文摘The influence of the interaction between surrounding rock and lining on the long-term behaviour of a tunnel in service is significant.In this paper,we proposed a mechanical model of the circular lined tunnel with the alterable mechanical property under hydrostatic stress and radially inner surface pressure of the lining.The alterable mechanical properties of the surrounding rock and the lining are embodied by the changing of their elasticity modulus with service time and radial direction of the tunnel,respectively.The proposed mechanical model is successfully validated by comparison with the existing theoretical models and the numerical simulation,respectively.The influences of the main parameters of the proposed mechanical model,such as the radial power-law indexes and the time-varying coefficients of the surrounding rock and the lining,as well as the radially inner surface pressure of the lining,on the interface displacement and pressure between surrounding rock and lining are investigated.The research results can provide some valuable references for timely diagnosis and correct evaluation of the long-term behaviours of a tunnel in service.
基金Project(2013CB036004) supported by National Basic Research Program(973)of ChinaProject(51378510) supported by National Natural Science Foundation of China
文摘Tunnel water inrush is one of the common geological disasters in the underground engineering construction.In order to effectively evaluate and control the occurrence of water inrush,the risk assessment model of tunnel water inrush was proposed based on improved attribute mathematical theory.The trigonometric functions were adopted to optimize the attribute mathematical theory,avoiding the influence of mutation points and linear variation zones in traditional linear measurement functions on the accuracy of the model.Based on comprehensive analysis of various factors,five parameters were selected as the evaluation indicators for the model,including tunnel head pressure,permeability coefficient of surrounding rock,crushing degree of surrounding rock,relative angle of joint plane and tunnel section size,under the principle of dimension rationality,independence,directness and quantification.The indicator classifications were determined.The links among measured data were analyzed in detail,and the objective weight of each indicator was determined by using similar weight method.Thereby the tunnel water inrush risk assessment model is established and applied in four target segments of two different tunnels in engineering.The evaluation results and the actual excavation data agree well,which indicates that the model is of high credibility and feasibility.
基金Under the auspices of National Natural Science Foundation of China(No.41471140)
文摘This study examines the socio-spatial context of uneven development and the residential accessibility of green space in Dalian of Liaoning Province, China. The social fairness was analyzed with a community scale as the basis. We combined social scientific methods with a GIS method using a behavior accessibility model from the perspectives of fairness of urban green space allocation based on social geography, geographic information science, management science and many other related discipline theories. The results show that: 1) Most of the urban green space distribution presents an unbalanced phenomenon, and it does not match with the population distribution; 2) We found some differences in the accessibility of the population with different attributes and opportunities to use and enjoy the urban green spaces, mainly due to: the dual social and spatial attributes of the residents and the serious stratum differentiation generated were the internal causes; the residential space differentiation and the pursuit of economic and real estate development were the direct causes; and unreasonable planning, in regard to the fact that government policies did not give consideration to efficiency and fairness, was also an important factor.
基金Foundation item: Supported by the Nature Science Foundation of Shandong Province(Y2007H02)
文摘By using the dynamic characteristic of one direction S-rough sets(one direction singular rough sets) and dual of one direction S-rough sets(dual of one direction singular rough sets), the concepts of attribute disturbance of knowledge, the attribute disturbance degree of knowledge, and the disturbance coefficient of knowledge are given. By employing these concepts, the cardinal order theorem of the attribute disturbance knowledge, the unit circle theorem of the attribute disturbance knowledge, and the discernible theorem of the attribute disturbance knowledge are presented.
文摘Although the high diversity of plant species in the rupestrian fields has been primarily attributed to the existence of a set of distinct habitats, few studies support this assertion. The present study aimed to further investigate the relationship between physical and chemical attributes of soils with the diversity of plant species in this unique ecosystem. The rupestrian field is a unique vegetation formation that covers some of the southeastern Brazilian mountains in the transition of the Atlantic rain forest and the Cerrado(savanna). Different habitats occur according to soil characteristics(e.g., presence of rocks, sand, fertility, hydrology, etc.). These attributes ultimately influence the vegetation that is highly adapted to the harsh edaphic and climatic mountain conditions. Five distinct habitats were studied by us: rocky outcrops, peat bogs, sandy bogs, quartz gravel fields, and "cerrado"(savanna). A floristic survey indicated that four families are found at greater frequency: Poaceae, Asteraceae, Cyperaceae, and Leguminosae. The greatest diversity of plant species was found in the rocky outcrops habitat, followed by cerrado, peat bog, quartz gravel grassland, and sandy bogs, respectively. The main difference in the floristic composition among these habitats was related to the dominant species. Trachypogon spicatus(Poaceae) was the most dominant species in the rocky outcrops, Axonopus siccus(Poaceae) in the peat bogs, Lagenocarpus rigidus(Cyperaceae) in the sandy bogs, Schizachyrium tenerum(Poaceae) in the cerrado, while Vellozia sp. 8(Velloziaceae) dominated the vegetation in the quartz gravel grassland. This study demonstrated that physical and chemical soil properties strongly related the diversity of plant species occurring in the different habitats of rupestrian fields.
基金Under the auspices of National Key Research and Development Program of China(No.2016YFD0800304)Natural Science Foundation of Shandong(No.ZR2017MD023,ZR2018BD003)
文摘The intensive management practices in greenhouse production may alter the soil physicochemical properties and contribute to the accumulation of heavy metals(HMs). To determine the HM concentrations in vegetable soil in relation to soil physicochemical properties and cultivation age, we conducted a soil survey for typical greenhouse soils in Shouguang, China. The results indicated that Cd is a major HM pollutant in the tested soils, as the only HM element exceeding the allowed limit for vegetable soil. The surveyed data was analyzed with regression analysis, correlation analysis and canonical correspondence analysis(CCA). A positive correlation is observed between HM pollution level and cultivation age. CCA results suggest that the HM pollution level and distribution in soil are significantly affected by soil physicochemical properties, which was a function of years of cultivation as revealed by regression analysis. In summary, cultivation age is an important factor to affect soil physicochemical properties(organic matter and inorganic nutrients) as well as HM contamination.
文摘This work constitutes a contribution to the study of the physical-chemical performance of some heavy metals and micro-nutrients in the Argan trees. The samples are harvested from small Argan trees, three samples (soil, wood, leaves) per tree. The content of various heavy metals and micro-nutrient in aerial parts (leaves, wood and soil) were analyzed in the Argan tree by the method of ICP-ES. The results of analysis of data for the chemical variables were measured for several trees at different measurement times, do not affect the dispersion of the data. The use of chemometrics has allowed us to interpret the results obtained especially those related to the characterization of heavy metals and micro-nutrient after calibration by variable regression of these results in order to get an overall estimate of the optimal content, and to follow changes in the methods of treatment. The results of the characteristics of Argan trees have been treated using the statistical method of Principal Component Analysis (MFA), The MFA was used to analyze the three groups simultaneously. These groups are fairly similar.
基金the National Natural Science Foundation of China (21290191)
文摘We introduce here a work package for a National Natural Science Foundation of China Major Project. We propose to develop computational methodology starting from the theory of electronic excitation processes to predicting the opto-electronic property for organic materials, in close collaborations with experiments. Through developing methods for the electron dynamics, considering superexchange electronic couplings, spin-orbit coupling elements between excited states, electron-phonon relaxation, intermolecular Coulomb and exchange terms we combine the statistical physics approaches including dynamic Monte Carlo, Boltzmann transport equation and Boltzmann statistics to predict the macroscopic properties of opto-electronic materials such as light-emitting efficiency, charge mobility, and exciton diffusion length. Experimental synthesis and characterization of D-A type ambipolar transport material as well as novel carbon based material will provide a test ground for the verification of theory.
基金supported by the Ministry of Science and Technology (2016YFA0204100)the National Natural Science Foundation of China (21573254 and 91545110)+1 种基金the Youth Innovation Promotion Association (CAS)the Sinopec China and Strategic Priority Research Program of the Chinese Academy of Sciences (XDA09030103)
文摘Graphitized nanocarbon materials can be an ideal catalyst support for heterogeneous catalytic systems. Their unique physical and chemical properties, such as large surface area, high adsorption capacity, excellent thermal and mechanical stability, outstanding electronic properties, and tunable porosity, allow the anchoring and dispersion of the active metals. Therefore, currently they are used as the key support material in many catalytic processes. This review summarizes recent relevant applications in supported catalysts that use graphitized nanocarbon as supports for catalytic oxidation, hydrogenation, dehydrogenation, and C-C coupling reactions in liquid-phase and gas-solid phase-reaction systems. The latest developments in specific features derived from the morphology and characteristics of graphitized na- nocarbon-supported metal catalysts are highlighted, as well as the differences in the catalytic behavior of graphitized nano- carbon-supported metal catalysts versus other related cata- lysts. The scientific challenges and opportunities in this field are also discussed.