As a novel advanced oxidation process (AOP), electro-Fenton process is powerful for degrading most organic compounds including toxic and non-biodegradable ones, and so has attracted great attention. This paper reviews...As a novel advanced oxidation process (AOP), electro-Fenton process is powerful for degrading most organic compounds including toxic and non-biodegradable ones, and so has attracted great attention. This paper reviews this process in detail including the mechanism, electrolytic bath, electrode materials, aerations and operation parameters. The application of electro-Fenton method in wastewater treatment is evaluated and summarized. Future work in this field is suggested, and three main directions of new electrode exploitation, development of assisted technologies and mechanistic study should be strengthened.展开更多
Water eutrophication has become a worldwide environmental problem in recent years,and understanding the mechanisms of water eutrophication will help for prevention and remediation of water eutrophication.In this paper...Water eutrophication has become a worldwide environmental problem in recent years,and understanding the mechanisms of water eutrophication will help for prevention and remediation of water eutrophication.In this paper,recent advances in current status and major mechanisms of water eutrophication,assessment and evaluation criteria,and the influencing factors were reviewed.Water eutrophication in lakes,reservoirs,estuaries and rivers is widespread all over the world and the severity is increasing,especially in the developing countries like China.The assessment of water eutrophication has been advanced from simple individual parameters like total phosphorus,total nitrogen,etc.,to comprehensive indexes like total nutrient status index.The major influencing factors on water eutrophication include nutrient enrichment,hydrodynamics,environmental factors such as temperature,salinity,carbon dioxide,element balance,etc.,and microbial and biodiversity.The occurrence of water eutrophication is actually a complex function of all the possible influencing factors.The mechanisms of algal blooming are not fully understood and need to be further investigated.展开更多
Freeze concentration has great potential in treating wastewaters containing soluble pollutions. It is important for freeze concentration process to produce ice crystals with large size and high purity. In this work ra...Freeze concentration has great potential in treating wastewaters containing soluble pollutions. It is important for freeze concentration process to produce ice crystals with large size and high purity. In this work raw urines of 4660 -7914 mg/L in COD, 512. 71 -872. 41 mg/L in NH3 -N and 22600 -28800 μs/cm in electric conductivity were studied. Urines were frozen by a digital refrigerated circulator bath. Ice crystals were purified by ice-water steep and vacuum filtration. The COD, NH3 - N, and electric conductivity levels of the melted ices were measured to reflect ice crystal purity. Effects of coolant temperature, ice crystal shape, initial solution temperature, solution concentration, ice seeding, re-crystallization process and crystallization time on ice crystal purity were analyzed. The results show that an appropriate coolant temperature, suspended ice crystals, an initial solution temperature of about 6 ℃, introduction of seed ice, addition of re-crystallization process, and crystallization time of less than 30 min axe in favor of producing ice crystals with high purity. Under such conditions, more than 99 percent of inorganic salts, COD and NH3 - N sources in raw urine could he removed.展开更多
An improved configuration of the membrane stack was adopted in the electrodeionization (EDI) cell to prevent precipitation of bivalent metal hydroxide during the running. The operational parameters that influenced t...An improved configuration of the membrane stack was adopted in the electrodeionization (EDI) cell to prevent precipitation of bivalent metal hydroxide during the running. The operational parameters that influenced the removal of copper ions from the dilute solution were optimized. The result showed that a moderate decrease in the inlet pH value and a moderate increase in the applied voltage could achieve a better removal effect. The steady process of electroplating wastewater treatment could be achieved with a removal efficiency of more than 99.5% and an enrichment factor of 5-14. The concentration of copper in purified water was less than 0.23 mg/L. This demonstrated the applicability of recovering heavy metal ions and purified water from electroplating effluent for industrial reuse.展开更多
This study investigated selected properties of soils affected by wastewater and its relationship with some heavy metals. A free survey technique involving target sampling was used in siting soil profile pits. Soil sam...This study investigated selected properties of soils affected by wastewater and its relationship with some heavy metals. A free survey technique involving target sampling was used in siting soil profile pits. Soil samples were collected based on horizon differentiation and analyzed using routine and special analytical techniques. Soil data were subjected to correlation analysis using SAS program. Results show that all heavy metals studied had values above critical limits in the polluted soils using known standards and that these biotoxic metals decreased with soil depths. Highly significant (P=0.01 and 0.05) relationships were established between investigated heavy metals and some soil properties, especially soil pH and organic matter. Further studies involving more edaphic properties, biotoxic metals and their bioaccessibility in crops growing on wastewater soils will surely enhance knowledge and management of these highly anthropogenically influenced soils of the study site.展开更多
The characteristics of membrane fouling and cleaning, in a hybrid MBR process, was investigated. Under the condition of sub-critical flux operation, a characteristic three-stage trans-membrane pressure (TMP) profile...The characteristics of membrane fouling and cleaning, in a hybrid MBR process, was investigated. Under the condition of sub-critical flux operation, a characteristic three-stage trans-membrane pressure (TMP) profile is observed as time passes. The initially extended period of slow pressure rise, followed by a somewhat faster rise, is then sup- planted by a sudden transition to rapid pressure rise. Membrane cleaning experiments and SEM examination make it apparent that the rapid TMP rise is mainly caused by the accumulation of a surface cake layer, which is a reversible fouling that can be removed by tap water washing. Fouling caused by a gel layer, which is an irreversible fouling, can be removed efficiently by chemical cleaning. NaC10 can oxidize the gel layer, which is formed mainly of macromo-lecular organic substances. The HC1 can remove inorganic particles formed by Ca^2+, Mg^2+ ions etc. The sequence of chemicals used in membrane cleaning has an influence on the cleaning result. The effect of the NaC1O+HC1 cleaning procedure is superior to that of the HCI+NaC1O one. Particle size distribution measurements (PSD) reveal that fine particles are inclined to deposit or attach on the membrane surface, or in the membrane pores, and caused rapid fouling.展开更多
Remote sensing techniques and geographic information systems offer a good means of collecting and manipulating the data required for assessing conservation practices. A method for automatic generation of most of the d...Remote sensing techniques and geographic information systems offer a good means of collecting and manipulating the data required for assessing conservation practices. A method for automatic generation of most of the data required by the Agricultural Non point Source erosion model is developed from three sources:(1) file with contour lines from the topographic maps(TM), (2) soil mapping units from the soil surveys, and (3)land cover from land sat TM image classification.展开更多
Sugarcane pulp residue (SPR), a waste from sugar-refinery, which possesses a large surface area, can be used for removing chromium (Cr(Ⅲ) and Cr(Ⅵ)) from wastewater. In this work, the kinetics, isotherms of...Sugarcane pulp residue (SPR), a waste from sugar-refinery, which possesses a large surface area, can be used for removing chromium (Cr(Ⅲ) and Cr(Ⅵ)) from wastewater. In this work, the kinetics, isotherms of Cr(Ⅲ) and Cr(V[) adsorption and their removal by SPR were investigated. The results show that the removal percentages of Cr(Ⅵ) and Cr(Ⅲ) increase with increasing SPR dosage and temperature and decrease with increasing SPR particle size and the initial concentration of chromium ions. However, the influence of pH value on the Cr(Ⅵ) removal differs from that of the Cr(Ⅲ) removal. The Cr(Ⅵ) removal percentage decreases with increasing pH values, while the Cr(Ⅲ) removal percentage increases with increasing pH value. The adsorption kinetics of Cr(Ⅵ) and Cr(Ⅲ) well fits with pseudo-second-order model. Langmuir adsorption isotherm can well describe the adsorption phenomena of chromium ions with the maximum adsorption capacity of 0.567 mg/g for Cr(Ⅵ) and 3.446 mg/g for Cr(Ⅲ). Moreover, SPR reveals higher adsorption capacity for Cr(Ⅲ) than that for Cr(Ⅵ), which implies that SPR has more potential application for Cr(Ⅲ)-containing wastewater treatment than that for Cr(Ⅵ)-containing wastewater treatment.展开更多
The performance of the Dongying multi-stage ponds-wetlands ecosystem was investigated in this work. Study of the removal of different pollutants (BOD5, COD, SS, TP, TN, NH3-N, etc.) in different temperature seasons an...The performance of the Dongying multi-stage ponds-wetlands ecosystem was investigated in this work. Study of the removal of different pollutants (BOD5, COD, SS, TP, TN, NH3-N, etc.) in different temperature seasons and different units in this system indicated that effluent BOD5 and SS were constant to less than 11 mg/L and 14 mg/L throughout the experimental proc- esses; but that the removal efficiencies of pollutants such as TP, TN, NH3-N, COD varied greatly with season. The higher the temperature was, the higher was the observed removal in this system. Additionally, each unit of the system functioned differently in removing pollutants. BOD5 and SS were mainly removed in the first three units (hybrid facultative ponds, aeration ponds and aerated fish ponds), whereas nitrogen and phosphates were mainly removed in hydrophyte ponds and constructed reed wetlands. The multi-stage ponds-wetlands ecosystem exhibits good potential of removing different pollutants, and the effluent quality meet several standards for wastewater reuse.展开更多
Solid-liquid hydrocyclones are mainly used to separate large particles, such as the particles of drilling fluid in petroleum industry, and large mineral particles. Till now the hydrocyclonic separation for fine partic...Solid-liquid hydrocyclones are mainly used to separate large particles, such as the particles of drilling fluid in petroleum industry, and large mineral particles. Till now the hydrocyclonic separation for fine particles is still a big problem. Basic separation principle of hydrocyclones and experimental research facility are simply introduced. The difficulty of separating fine particle is analyzed. Based on a solid-liquid hydrocyclone used for separating fine particles, relationships of dimensionless pressure characteristic parameters, i.e. Euler number and pressure drop ratio, with several main dimensionless parameters, such as split ratio, swirl number and gas-liquid ratio, were experimentally studied in detail. The research was carried out by using the hydrocyclonic separation experimental rig at the University of Bradford. It is shown that the less the size of particle, the less the value of radius of the balance orbit occupied by the particle, and then the more difficult for the particle to be separated. Experiments indicate that Euler number of the tested hydrocyclone increases with the rise of Reynolds number, split ratio, swirl number and gas-liquid ratio respectively, and the pressure drop ratio falls with the increase of Reynolds number, split ratio and swirl number respectively. It is concluded that the most effective way to decrease the unit energy dissipation of hydrocyclone is to reduce swirl number or gas-liquid ratio of the mixed media.展开更多
A novel semi-fragile audio watermarking algorithm in DWT domain is proposed in this paper.This method transforms the original audio into 3-layer wavelet domain and divides approximation wavelet coefficients into many ...A novel semi-fragile audio watermarking algorithm in DWT domain is proposed in this paper.This method transforms the original audio into 3-layer wavelet domain and divides approximation wavelet coefficients into many groups.Through computing mean quantization of per group,this algorithm embeds the watermark signal into the average value of the wavelet coefficients.Experimental results show that our semi-fragile audio watermarking algorithm is not only inaudible and robust against various common images processing,but also fragile to malicious modification.Especially,it can detect the tampered regions effectively.展开更多
This study examines the possibility of using live spirulina to biologically remove aqueous lead of low concentration (below 50 mg/L) from wastewater. The spirulina cells were first immersed for seven days in five wast...This study examines the possibility of using live spirulina to biologically remove aqueous lead of low concentration (below 50 mg/L) from wastewater. The spirulina cells were first immersed for seven days in five wastewater samples containing lead of different concentrations, and the growth rate was determined by light at wavelength of 560 nm. The 72 h-EC50 (72 h medium effective concentration) was estimated to be 11.46 mg/L (lead). Afterwards, the lead adsorption by live spirulina cells was conducted. It was observed that at the initial stage (0–12 min) the adsorption rate was so rapid that 74% of the metal was bio- logically adsorbed. The maximum biosorption capacity of live spirulina was estimated to be 0.62 mg lead per 105 alga cells.展开更多
Detoxification of chlorinated organic compounds via reaction with nickel/iron powder was implemented in aqueous solution. Compared to iron, nickel/iron bimetallic powder had higher hydrodechlorination activities for b...Detoxification of chlorinated organic compounds via reaction with nickel/iron powder was implemented in aqueous solution. Compared to iron, nickel/iron bimetallic powder had higher hydrodechlorination activities for both atrazine (ATR) and p-chlorophenol (pCP); nickel/iron (2.96%, w/w) was shown to have the largest specific surface area and the optimum proportion for the dechlorination of both ATR and pCP. Electrochemical measurements showed that the adsorbed hydrogen atom on the nickel must have been the dominant reductive agent for the dechlorination of both ATR andpCP in this system.展开更多
The low removal efficiency of total nitrogen (TN) is one of the main disadvantages of traditional single stage subsurface infiltration system, which combines an anaerobic tank and a soil filter field. In this study,...The low removal efficiency of total nitrogen (TN) is one of the main disadvantages of traditional single stage subsurface infiltration system, which combines an anaerobic tank and a soil filter field. In this study, a full-scale, two-stage anaerobic tank and soil trench system was designed and operated to evaluate the feasibility and performances in treating sewage from a school campus for over a one-year monitoring period. The raw sewage was prepared and fed into the first anaerobic tank and second tank by 60% and 40%, respectively. This novel process could decrease chemical oxygen demand with the dichromate method by 89%-96%, suspended solids by 91%-97%, and total phosphorus by 91%-97%. The denitrification was satisfactory in the second stage soil trench, so the removals of TN as well as ammonia nitrogen (NH4^+-N) reached 68%-75% and 96% 99%, respectively. It appeared that the removal efficiency of TN in this two-stage anaerobic tank and soil trench system was more effective than that in the single stage soil infiltration system. The effluent met the discharge standard for the sewage treatment plant (GB18918-2002) of China.展开更多
A new type of dehydration unit for natural gas was briefly described and its basic structure and working principles were presented. An indoor test rig for testing the unit performance was set up and the experimental r...A new type of dehydration unit for natural gas was briefly described and its basic structure and working principles were presented. An indoor test rig for testing the unit performance was set up and the experimental results were given. The results showed that the unit could attain a maximum dew point depression of about 20℃ without any need of external mechanical power and chemicals. The pressure loss ratio, shock wave and the flow rate had great influence on the dehydration characteristics. From the systematic analysis of the factors that affect the dehydration efficiency of the unit, the suggestions for improving the unit are put forward.展开更多
Method for decolrizing dyed wastewater was researched and the affecting factors dicussed. The result shows that the conditions for getting an optimum decolorization effect are: a reaction time of 60 min, a coke size o...Method for decolrizing dyed wastewater was researched and the affecting factors dicussed. The result shows that the conditions for getting an optimum decolorization effect are: a reaction time of 60 min, a coke size of 5~10 mm, a solid/liquid ratio of 1∶10, an air blast volume of 4 m3/h, and proper Fe/coke ratio determined by the type of dye material. The system acidity influences dyed wastewater in different ways, i.e., acid condition is good for the decolorization of scarlet 3R and methyl orange simulated wastewater but bad for that of alkali violet 5BN simulated wastewater, while the decolorization of dispersed yellow E-RGFL simulated wastewater has nothing to do with pH.展开更多
Two nonfoaming bubble separation techniques, air stripping and solvent sublation, are presented and discussed in order to recover butyl acetate (BA) from discharged wastewater after solvent extraction of penicillin. R...Two nonfoaming bubble separation techniques, air stripping and solvent sublation, are presented and discussed in order to recover butyl acetate (BA) from discharged wastewater after solvent extraction of penicillin. Results show air stripping is not suitable for the recovery of BA from the wastewater. Axial concentration of BA had a noted maximum point along the column. In contrast, solvent sublation is very effective to recover BA from the wastewater. In solvent sublation experiments, axial concentration of BA along the column first increased and then decreased from the bottom to the top because of two primary mass transport processes. One is the transport by adsorption or attachment to ascending bubbles, and the other is by dispersion at water-solvent interface and by water film in organic solvent layer. In order to elucidate the high removal efficiency in solvent sublation, the microstructure of the wastewater was studied with optic microscope, which was showed to be an emulsion of BA in water at large concentration of BA. Solvent sublation can be successfully used in the removal of BA from its emulsion in the wastewater. The surface tension of simulated solution composed of lysozyme and BA was studied to understand mutual effect of biological materials and BA. Results show that lysozyme affects the adsorption of BA at air-water interface and they may form a complex between BA and lysozyme molecules.展开更多
With the development of EMC technology, EMC assessment has become increasingly important in EMC design. Although numerous EMC assessment models are available today, few of them can provide a tradeoff between efficienc...With the development of EMC technology, EMC assessment has become increasingly important in EMC design. Although numerous EMC assessment models are available today, few of them can provide a tradeoff between efficiency and accuracy for the specific case of military vehicular communication systems. Face to this situation, a modified four-level assessment model is proposed in the paper. First, the development of EMC assessment technology is briefly reviewed, and the theoretical mechanism of EMI environment is introduced. Then, the architecture of the proposed model is outlined, and the assessment methods are explored. To demonstrate the application of it, an example involving a communication system in a military vehicle is presented. From the physical layer to the signal layer, a hierarchical assessment on the entire system is successfully performed based on the proposed model, and we can make a qualitative EMC assessment on the EMC performance of the system. Based on a comparison with the traditional model, we conclude that the proposed model is more accurate, more efficient and less time-consuming, which is suitable for the EMC assessment on militaryvehicular communication systems. We hope that the proposed model will serve as a useful reference for system-level EMC assessments for other systems.展开更多
Large amounts of ammonium and a low content of biodegradable chemical oxygen demand(COD) are contained in leachate from aged landfills, together with the effluent containing high concentration of nitric nitrogen aft...Large amounts of ammonium and a low content of biodegradable chemical oxygen demand(COD) are contained in leachate from aged landfills, together with the effluent containing high concentration of nitric nitrogen after biochemical treatment. Treatment effect of anaerobic ammonium oxidation (anammox) process on the mixture of the leachate and its biochemical effluent was investigated. The results show that the average removal efficiencies of ammonium, nitric nitrogen and total nitrogen are 87.51%, 74.95% and 79.59%, respectively, corresponding to the average ratio of removed nitric nitrogen to ammonium, i.e. 1.14 during the steady phase of anammox activity. The mean removal efficiency of COD is only 24.01% during the experimental period. Thc,dcmand of total phosphorous for the anammox process is unobvious. Especially, the alkalinity and pH value of the effluent are close to those of the inftuent during the steady phase of anammox activity. In addition, it is demonstrated that the status of the anammox bioreactor can be indicated by the alkalinity and pH value during the course of the experiment. The anammox bioreactor has shown potential for nitrogen removal in the leachate mixture. However, COD and total phosphorous in the leachate mixture need further treatment for removal efficiencies of COD and total phosphorous are not good in the anammox bioreactor.展开更多
基金Project supported by the National Natural Science Foundation of China (No. 50478049)the Natural Science Foundation of Guangdong Province (No. 04011215), China
文摘As a novel advanced oxidation process (AOP), electro-Fenton process is powerful for degrading most organic compounds including toxic and non-biodegradable ones, and so has attracted great attention. This paper reviews this process in detail including the mechanism, electrolytic bath, electrode materials, aerations and operation parameters. The application of electro-Fenton method in wastewater treatment is evaluated and summarized. Future work in this field is suggested, and three main directions of new electrode exploitation, development of assisted technologies and mechanistic study should be strengthened.
基金Project supported by the Key Project from the Ministry of Education of China (No. 705824)the Project from Science and Technology Bureau of Zhejiang Province (No. 2006C13059)a grant from the St. Lucie River Water Initiative (SFWMD contract No. OT060162),USA,in part
文摘Water eutrophication has become a worldwide environmental problem in recent years,and understanding the mechanisms of water eutrophication will help for prevention and remediation of water eutrophication.In this paper,recent advances in current status and major mechanisms of water eutrophication,assessment and evaluation criteria,and the influencing factors were reviewed.Water eutrophication in lakes,reservoirs,estuaries and rivers is widespread all over the world and the severity is increasing,especially in the developing countries like China.The assessment of water eutrophication has been advanced from simple individual parameters like total phosphorus,total nitrogen,etc.,to comprehensive indexes like total nutrient status index.The major influencing factors on water eutrophication include nutrient enrichment,hydrodynamics,environmental factors such as temperature,salinity,carbon dioxide,element balance,etc.,and microbial and biodiversity.The occurrence of water eutrophication is actually a complex function of all the possible influencing factors.The mechanisms of algal blooming are not fully understood and need to be further investigated.
基金Sponsored by the High Technology Research and Development Programm of China(Grant No.2002AA743022).
文摘Freeze concentration has great potential in treating wastewaters containing soluble pollutions. It is important for freeze concentration process to produce ice crystals with large size and high purity. In this work raw urines of 4660 -7914 mg/L in COD, 512. 71 -872. 41 mg/L in NH3 -N and 22600 -28800 μs/cm in electric conductivity were studied. Urines were frozen by a digital refrigerated circulator bath. Ice crystals were purified by ice-water steep and vacuum filtration. The COD, NH3 - N, and electric conductivity levels of the melted ices were measured to reflect ice crystal purity. Effects of coolant temperature, ice crystal shape, initial solution temperature, solution concentration, ice seeding, re-crystallization process and crystallization time on ice crystal purity were analyzed. The results show that an appropriate coolant temperature, suspended ice crystals, an initial solution temperature of about 6 ℃, introduction of seed ice, addition of re-crystallization process, and crystallization time of less than 30 min axe in favor of producing ice crystals with high purity. Under such conditions, more than 99 percent of inorganic salts, COD and NH3 - N sources in raw urine could he removed.
基金Project (No. Z505060) supported by the Natural Science Foundation of Zhejiang Province, China
文摘An improved configuration of the membrane stack was adopted in the electrodeionization (EDI) cell to prevent precipitation of bivalent metal hydroxide during the running. The operational parameters that influenced the removal of copper ions from the dilute solution were optimized. The result showed that a moderate decrease in the inlet pH value and a moderate increase in the applied voltage could achieve a better removal effect. The steady process of electroplating wastewater treatment could be achieved with a removal efficiency of more than 99.5% and an enrichment factor of 5-14. The concentration of copper in purified water was less than 0.23 mg/L. This demonstrated the applicability of recovering heavy metal ions and purified water from electroplating effluent for industrial reuse.
文摘This study investigated selected properties of soils affected by wastewater and its relationship with some heavy metals. A free survey technique involving target sampling was used in siting soil profile pits. Soil samples were collected based on horizon differentiation and analyzed using routine and special analytical techniques. Soil data were subjected to correlation analysis using SAS program. Results show that all heavy metals studied had values above critical limits in the polluted soils using known standards and that these biotoxic metals decreased with soil depths. Highly significant (P=0.01 and 0.05) relationships were established between investigated heavy metals and some soil properties, especially soil pH and organic matter. Further studies involving more edaphic properties, biotoxic metals and their bioaccessibility in crops growing on wastewater soils will surely enhance knowledge and management of these highly anthropogenically influenced soils of the study site.
基金Projects 200457 supported by the Planning Foundation of Hebei Water Conservancy Bureau in ChinaOP4476 by the Youth Foundation of China Univer- sity of Mining & Technology
文摘The characteristics of membrane fouling and cleaning, in a hybrid MBR process, was investigated. Under the condition of sub-critical flux operation, a characteristic three-stage trans-membrane pressure (TMP) profile is observed as time passes. The initially extended period of slow pressure rise, followed by a somewhat faster rise, is then sup- planted by a sudden transition to rapid pressure rise. Membrane cleaning experiments and SEM examination make it apparent that the rapid TMP rise is mainly caused by the accumulation of a surface cake layer, which is a reversible fouling that can be removed by tap water washing. Fouling caused by a gel layer, which is an irreversible fouling, can be removed efficiently by chemical cleaning. NaC10 can oxidize the gel layer, which is formed mainly of macromo-lecular organic substances. The HC1 can remove inorganic particles formed by Ca^2+, Mg^2+ ions etc. The sequence of chemicals used in membrane cleaning has an influence on the cleaning result. The effect of the NaC1O+HC1 cleaning procedure is superior to that of the HCI+NaC1O one. Particle size distribution measurements (PSD) reveal that fine particles are inclined to deposit or attach on the membrane surface, or in the membrane pores, and caused rapid fouling.
文摘Remote sensing techniques and geographic information systems offer a good means of collecting and manipulating the data required for assessing conservation practices. A method for automatic generation of most of the data required by the Agricultural Non point Source erosion model is developed from three sources:(1) file with contour lines from the topographic maps(TM), (2) soil mapping units from the soil surveys, and (3)land cover from land sat TM image classification.
基金Projects(2006AA06Z374, 2007AA021304) supported by the National High-Tech Research and Development Program of ChinaProject(2008SK2007) supported by the Key Program of Science and Technology of Hunan Province, China
文摘Sugarcane pulp residue (SPR), a waste from sugar-refinery, which possesses a large surface area, can be used for removing chromium (Cr(Ⅲ) and Cr(Ⅵ)) from wastewater. In this work, the kinetics, isotherms of Cr(Ⅲ) and Cr(V[) adsorption and their removal by SPR were investigated. The results show that the removal percentages of Cr(Ⅵ) and Cr(Ⅲ) increase with increasing SPR dosage and temperature and decrease with increasing SPR particle size and the initial concentration of chromium ions. However, the influence of pH value on the Cr(Ⅵ) removal differs from that of the Cr(Ⅲ) removal. The Cr(Ⅵ) removal percentage decreases with increasing pH values, while the Cr(Ⅲ) removal percentage increases with increasing pH value. The adsorption kinetics of Cr(Ⅵ) and Cr(Ⅲ) well fits with pseudo-second-order model. Langmuir adsorption isotherm can well describe the adsorption phenomena of chromium ions with the maximum adsorption capacity of 0.567 mg/g for Cr(Ⅵ) and 3.446 mg/g for Cr(Ⅲ). Moreover, SPR reveals higher adsorption capacity for Cr(Ⅲ) than that for Cr(Ⅵ), which implies that SPR has more potential application for Cr(Ⅲ)-containing wastewater treatment than that for Cr(Ⅵ)-containing wastewater treatment.
基金Project (No. GA02C201) supported by the Key Project of Scienceand Technology Commission of Heilongjiang Province China
文摘The performance of the Dongying multi-stage ponds-wetlands ecosystem was investigated in this work. Study of the removal of different pollutants (BOD5, COD, SS, TP, TN, NH3-N, etc.) in different temperature seasons and different units in this system indicated that effluent BOD5 and SS were constant to less than 11 mg/L and 14 mg/L throughout the experimental proc- esses; but that the removal efficiencies of pollutants such as TP, TN, NH3-N, COD varied greatly with season. The higher the temperature was, the higher was the observed removal in this system. Additionally, each unit of the system functioned differently in removing pollutants. BOD5 and SS were mainly removed in the first three units (hybrid facultative ponds, aeration ponds and aerated fish ponds), whereas nitrogen and phosphates were mainly removed in hydrophyte ponds and constructed reed wetlands. The multi-stage ponds-wetlands ecosystem exhibits good potential of removing different pollutants, and the effluent quality meet several standards for wastewater reuse.
文摘Solid-liquid hydrocyclones are mainly used to separate large particles, such as the particles of drilling fluid in petroleum industry, and large mineral particles. Till now the hydrocyclonic separation for fine particles is still a big problem. Basic separation principle of hydrocyclones and experimental research facility are simply introduced. The difficulty of separating fine particle is analyzed. Based on a solid-liquid hydrocyclone used for separating fine particles, relationships of dimensionless pressure characteristic parameters, i.e. Euler number and pressure drop ratio, with several main dimensionless parameters, such as split ratio, swirl number and gas-liquid ratio, were experimentally studied in detail. The research was carried out by using the hydrocyclonic separation experimental rig at the University of Bradford. It is shown that the less the size of particle, the less the value of radius of the balance orbit occupied by the particle, and then the more difficult for the particle to be separated. Experiments indicate that Euler number of the tested hydrocyclone increases with the rise of Reynolds number, split ratio, swirl number and gas-liquid ratio respectively, and the pressure drop ratio falls with the increase of Reynolds number, split ratio and swirl number respectively. It is concluded that the most effective way to decrease the unit energy dissipation of hydrocyclone is to reduce swirl number or gas-liquid ratio of the mixed media.
基金We wish to thank the National Basic Research Program of China (973 Program) for Grant 2007CB311203, the National Natural Science Foundation of China for Grant 60821001, the Specialized Research Fund for the Doctoral Program of Higher Education for Grant 20070013007 under which the present work was possible.
文摘A novel semi-fragile audio watermarking algorithm in DWT domain is proposed in this paper.This method transforms the original audio into 3-layer wavelet domain and divides approximation wavelet coefficients into many groups.Through computing mean quantization of per group,this algorithm embeds the watermark signal into the average value of the wavelet coefficients.Experimental results show that our semi-fragile audio watermarking algorithm is not only inaudible and robust against various common images processing,but also fragile to malicious modification.Especially,it can detect the tampered regions effectively.
文摘This study examines the possibility of using live spirulina to biologically remove aqueous lead of low concentration (below 50 mg/L) from wastewater. The spirulina cells were first immersed for seven days in five wastewater samples containing lead of different concentrations, and the growth rate was determined by light at wavelength of 560 nm. The 72 h-EC50 (72 h medium effective concentration) was estimated to be 11.46 mg/L (lead). Afterwards, the lead adsorption by live spirulina cells was conducted. It was observed that at the initial stage (0–12 min) the adsorption rate was so rapid that 74% of the metal was bio- logically adsorbed. The maximum biosorption capacity of live spirulina was estimated to be 0.62 mg lead per 105 alga cells.
基金Project (No. 30270767) supported by the National Natural Science Foundation of China
文摘Detoxification of chlorinated organic compounds via reaction with nickel/iron powder was implemented in aqueous solution. Compared to iron, nickel/iron bimetallic powder had higher hydrodechlorination activities for both atrazine (ATR) and p-chlorophenol (pCP); nickel/iron (2.96%, w/w) was shown to have the largest specific surface area and the optimum proportion for the dechlorination of both ATR and pCP. Electrochemical measurements showed that the adsorbed hydrogen atom on the nickel must have been the dominant reductive agent for the dechlorination of both ATR andpCP in this system.
基金the National High Technology Research and Development Program (863 Program) of China(No2002AA601012-01)
文摘The low removal efficiency of total nitrogen (TN) is one of the main disadvantages of traditional single stage subsurface infiltration system, which combines an anaerobic tank and a soil filter field. In this study, a full-scale, two-stage anaerobic tank and soil trench system was designed and operated to evaluate the feasibility and performances in treating sewage from a school campus for over a one-year monitoring period. The raw sewage was prepared and fed into the first anaerobic tank and second tank by 60% and 40%, respectively. This novel process could decrease chemical oxygen demand with the dichromate method by 89%-96%, suspended solids by 91%-97%, and total phosphorus by 91%-97%. The denitrification was satisfactory in the second stage soil trench, so the removals of TN as well as ammonia nitrogen (NH4^+-N) reached 68%-75% and 96% 99%, respectively. It appeared that the removal efficiency of TN in this two-stage anaerobic tank and soil trench system was more effective than that in the single stage soil infiltration system. The effluent met the discharge standard for the sewage treatment plant (GB18918-2002) of China.
文摘A new type of dehydration unit for natural gas was briefly described and its basic structure and working principles were presented. An indoor test rig for testing the unit performance was set up and the experimental results were given. The results showed that the unit could attain a maximum dew point depression of about 20℃ without any need of external mechanical power and chemicals. The pressure loss ratio, shock wave and the flow rate had great influence on the dehydration characteristics. From the systematic analysis of the factors that affect the dehydration efficiency of the unit, the suggestions for improving the unit are put forward.
文摘Method for decolrizing dyed wastewater was researched and the affecting factors dicussed. The result shows that the conditions for getting an optimum decolorization effect are: a reaction time of 60 min, a coke size of 5~10 mm, a solid/liquid ratio of 1∶10, an air blast volume of 4 m3/h, and proper Fe/coke ratio determined by the type of dye material. The system acidity influences dyed wastewater in different ways, i.e., acid condition is good for the decolorization of scarlet 3R and methyl orange simulated wastewater but bad for that of alkali violet 5BN simulated wastewater, while the decolorization of dispersed yellow E-RGFL simulated wastewater has nothing to do with pH.
基金Supported by the National Natural Science Foundation of China (No. 20406021, No. 20236050 and No. 20221603).
文摘Two nonfoaming bubble separation techniques, air stripping and solvent sublation, are presented and discussed in order to recover butyl acetate (BA) from discharged wastewater after solvent extraction of penicillin. Results show air stripping is not suitable for the recovery of BA from the wastewater. Axial concentration of BA had a noted maximum point along the column. In contrast, solvent sublation is very effective to recover BA from the wastewater. In solvent sublation experiments, axial concentration of BA along the column first increased and then decreased from the bottom to the top because of two primary mass transport processes. One is the transport by adsorption or attachment to ascending bubbles, and the other is by dispersion at water-solvent interface and by water film in organic solvent layer. In order to elucidate the high removal efficiency in solvent sublation, the microstructure of the wastewater was studied with optic microscope, which was showed to be an emulsion of BA in water at large concentration of BA. Solvent sublation can be successfully used in the removal of BA from its emulsion in the wastewater. The surface tension of simulated solution composed of lysozyme and BA was studied to understand mutual effect of biological materials and BA. Results show that lysozyme affects the adsorption of BA at air-water interface and they may form a complex between BA and lysozyme molecules.
基金supported by the National Moon Exploration Program of China (No. TY3Q20110020)in part supported by the 13th Five-Year Community Technology Research Program of National Equipment Development Department of China (No.41409020301)the National Natural Science Foundation of China (50971094)
文摘With the development of EMC technology, EMC assessment has become increasingly important in EMC design. Although numerous EMC assessment models are available today, few of them can provide a tradeoff between efficiency and accuracy for the specific case of military vehicular communication systems. Face to this situation, a modified four-level assessment model is proposed in the paper. First, the development of EMC assessment technology is briefly reviewed, and the theoretical mechanism of EMI environment is introduced. Then, the architecture of the proposed model is outlined, and the assessment methods are explored. To demonstrate the application of it, an example involving a communication system in a military vehicle is presented. From the physical layer to the signal layer, a hierarchical assessment on the entire system is successfully performed based on the proposed model, and we can make a qualitative EMC assessment on the EMC performance of the system. Based on a comparison with the traditional model, we conclude that the proposed model is more accurate, more efficient and less time-consuming, which is suitable for the EMC assessment on militaryvehicular communication systems. We hope that the proposed model will serve as a useful reference for system-level EMC assessments for other systems.
基金Project (20377013) supported by the National Natural Science Foundation of China project (020959) supported by Department of Science and Technology of Guangdong Province
文摘Large amounts of ammonium and a low content of biodegradable chemical oxygen demand(COD) are contained in leachate from aged landfills, together with the effluent containing high concentration of nitric nitrogen after biochemical treatment. Treatment effect of anaerobic ammonium oxidation (anammox) process on the mixture of the leachate and its biochemical effluent was investigated. The results show that the average removal efficiencies of ammonium, nitric nitrogen and total nitrogen are 87.51%, 74.95% and 79.59%, respectively, corresponding to the average ratio of removed nitric nitrogen to ammonium, i.e. 1.14 during the steady phase of anammox activity. The mean removal efficiency of COD is only 24.01% during the experimental period. Thc,dcmand of total phosphorous for the anammox process is unobvious. Especially, the alkalinity and pH value of the effluent are close to those of the inftuent during the steady phase of anammox activity. In addition, it is demonstrated that the status of the anammox bioreactor can be indicated by the alkalinity and pH value during the course of the experiment. The anammox bioreactor has shown potential for nitrogen removal in the leachate mixture. However, COD and total phosphorous in the leachate mixture need further treatment for removal efficiencies of COD and total phosphorous are not good in the anammox bioreactor.