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理论α系数法波长色散X射线荧光测定土壤中的重金属 被引量:3
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作者 肖杰 杨利元 王天铖 《四川地质学报》 2019年第B06期156-159,共4页
近年来,重金属带来的土壤污染问题日益严重,快速、准确、有效地测定土壤中重金属种类及含量对土壤重金属污染评估及后续污染防治具有重要意义。本研究建立了波长色散X射线荧光光谱法同时测定土壤样品中铬、铅、锌、铜、钴、镍、锰、钒8... 近年来,重金属带来的土壤污染问题日益严重,快速、准确、有效地测定土壤中重金属种类及含量对土壤重金属污染评估及后续污染防治具有重要意义。本研究建立了波长色散X射线荧光光谱法同时测定土壤样品中铬、铅、锌、铜、钴、镍、锰、钒8种重金属元素含量的检测方法,通过经验法与理论α系数法的结合,优化了实验条件,方法线性良好,准确度与精密度较高,并且极大的简化了测定过程,提高了工作效率。将应用于土壤重金属含量初步评估,与ICP-MS的测定结果吻合度高。土壤监测结果表明,目标区土壤均符合二级土壤限量标准,该区土壤环境质量总体较好。而且该法减少了实验前处理过程中化学试剂的使用,避免了前处理过程中带来的环境污染问题,适用于规模较大的地质、农业、环境监测分析等生产单位进行土壤中重金属元素的快速测定。 展开更多
关键词 土壤 重金属 X射线荧光 理论α系数 ICP-MS
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R-α系数法校正铅黄铜合金X荧光分析中的基体效应 被引量:1
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作者 李思威 赖万昌 +1 位作者 翟娟 贾学辉 《四川有色金属》 2013年第4期62-64,共3页
介绍一种将理论α系数法与基本参数法有机结合起来校正基体效应的方法。实验表明:该方法提高了样品分析的精确度,对铅黄铜合金试样中Cu、Zn、Pb元素含量分析的平均相对误差分别为0.11%、0.72%、2.93%;该方法减少了所需标准样品的数量,... 介绍一种将理论α系数法与基本参数法有机结合起来校正基体效应的方法。实验表明:该方法提高了样品分析的精确度,对铅黄铜合金试样中Cu、Zn、Pb元素含量分析的平均相对误差分别为0.11%、0.72%、2.93%;该方法减少了所需标准样品的数量,且能在无纯元素标样的情况下对仪器进行标定。在相同测量条件下,分析效果比基本参数法及理论α系数法好。 展开更多
关键词 X荧光分析 基体效应 理论α系数 基本参数 黄铜合金
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X射线荧光光谱法测定铁矿石中各组分 被引量:22
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作者 张飙飞 《冶金分析》 CAS CSCD 北大核心 2003年第3期53-54,50,共3页
采用高温熔融对铁矿石试样进行预处理,以消除矿物效应。X射线荧光光谱法测定铁矿石中TFe,Al2O3,CaO,MgO,SiO2,P,Cu,Pb,Zn,As,Sn,Ti,Mn时,应用SUPERQ软件中的理论系数法、经验系数法对各组分进行校正,计算出各组分分析曲线的校正常数和... 采用高温熔融对铁矿石试样进行预处理,以消除矿物效应。X射线荧光光谱法测定铁矿石中TFe,Al2O3,CaO,MgO,SiO2,P,Cu,Pb,Zn,As,Sn,Ti,Mn时,应用SUPERQ软件中的理论系数法、经验系数法对各组分进行校正,计算出各组分分析曲线的校正常数和拟和精度,得到最佳工作曲线,取得满意的结果。 展开更多
关键词 铁矿石 X射线荧光光谱 测定 理论系数法 经验系数
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应用X射线荧光光谱法测定常见金属基体中合金组分
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作者 胡祖国 曹攽 彭超 《浙江冶金》 2023年第4期26-29,33,共5页
本文应用X射线荧光光谱法制作通用工作曲线,测定铜、铁、铝、镍和钛基体金属中多种主要合金元素的含量,通过优选干扰小的谱峰、结合数学公式校正,降低了重叠干扰;并采用变化的理论α系数法校正了多金属基体条件下的基体效应影响。该方... 本文应用X射线荧光光谱法制作通用工作曲线,测定铜、铁、铝、镍和钛基体金属中多种主要合金元素的含量,通过优选干扰小的谱峰、结合数学公式校正,降低了重叠干扰;并采用变化的理论α系数法校正了多金属基体条件下的基体效应影响。该方法分析了包括铜、铁、铝、镍和钛基材料在内的5个标准样品,测定值与认定值相符,测定值的相对标准偏差(n=7)在0.28%~24.2%之间。 展开更多
关键词 X射线荧光光谱 多金属基体 通用工作曲线 理论α系数
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基于突变理论的改进极限平衡法边坡稳定分析
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作者 王瑞 《山西建筑》 2014年第4期72-73,共2页
结合某工程边坡,通过考虑边坡在破坏时突然失稳的变化特征,结合突变理论,分析了该边坡在天然状态和保水状态下的各自稳定性,通过对比发现,在考虑滑坡的突变特征的前提下,对滑坡的稳定性计算更加真实可靠。
关键词 传递系数 突变理论 稳定性 对比分析
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熔融制样-X射线荧光光谱法测定海洋沉积物中氯等元素 被引量:13
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作者 李小莉 陈曦 +3 位作者 葛江洪 吴彦涛 冼啸林 韩伟 《理化检验(化学分册)》 CAS CSCD 北大核心 2011年第12期1420-1423,共4页
应用X射线荧光光谱法测定了海洋沉积物中12种元素(即硫、铝、铁、钙、钾、磷、钛、锰、氯、硅、钠及镁)。样品预先在120℃烘8h后,称取0.500 0g与5.000g混合熔剂(四硼酸锂67g与偏硼酸锂33g混合)置于铂-金坩埚中混匀后,先在600℃预氧化20... 应用X射线荧光光谱法测定了海洋沉积物中12种元素(即硫、铝、铁、钙、钾、磷、钛、锰、氯、硅、钠及镁)。样品预先在120℃烘8h后,称取0.500 0g与5.000g混合熔剂(四硼酸锂67g与偏硼酸锂33g混合)置于铂-金坩埚中混匀后,先在600℃预氧化200s,使还原性物质充分氧化,随即升温至1 000℃熔融9min。熔融物自动在坩埚内成型为样品,自动脱出后即可用于X射线荧光光谱法测定。用理论α系数法校正基体效应及元素间谱线重叠干扰。应用此方法分析了2个深海沉积物标准物质,所测得12种组分的结果与标准值一致。 展开更多
关键词 X射线荧光光谱 海洋沉积物 融熔制样 理论α系数
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X射线荧光光谱法测试重晶石中的多元素 被引量:1
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作者 周国兴 赵恩好 +3 位作者 岳明新 曹丹红 肖刚 张泉 《地质与资源》 CAS 2014年第3期292-295,共4页
采用玻璃熔片法制样,建立了重晶石中多元素X射线荧光光谱分析方法.准确称取待测样品0.5000 g,X射线荧光专用熔剂5.000 g;二者混合后,通过高频熔样机在1150℃进行熔片处理8 min;将最终得到的样片放入干燥器中冷却至室温,然后准确称取玻... 采用玻璃熔片法制样,建立了重晶石中多元素X射线荧光光谱分析方法.准确称取待测样品0.5000 g,X射线荧光专用熔剂5.000 g;二者混合后,通过高频熔样机在1150℃进行熔片处理8 min;将最终得到的样片放入干燥器中冷却至室温,然后准确称取玻璃片质量;上机测试,所得到的数据为该元素在玻璃片中的含量;通过换算最终得到实际样品中的该元素含量.使用理论α系数法和经验系数法相结合来回归校正共存元素间的吸收增强效应.本方法对于重晶石中各元素的测试相对标准偏差处于0.2%-4.7%之间,方法检出限在3.3×10^-6-170.6×10^-6之间.测试数据通过与国家标准物质比对,结果合理. 展开更多
关键词 X射线荧光光谱 玻璃熔片 理论α系数 重晶石 高频熔样机
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一种用X-射线荧光光谱法测定硅酸盐及碳酸盐类样品中氧化物的通用方法 被引量:10
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作者 吴小红 徐永宏 高新华 《冶金分析》 EI CAS CSCD 北大核心 2008年第12期17-22,共6页
宽范围氧化物定量分析是一种基于理论α法"表观浓度"概念(即元素浓度与谱线强度间的线性相关原理)适用于硅酸盐和碳酸盐类物料中多种氧化物的高精度定量分析方法。用硼酸盐为熔剂的熔融法制备样品,以单一纯元素氧化物或多元... 宽范围氧化物定量分析是一种基于理论α法"表观浓度"概念(即元素浓度与谱线强度间的线性相关原理)适用于硅酸盐和碳酸盐类物料中多种氧化物的高精度定量分析方法。用硼酸盐为熔剂的熔融法制备样品,以单一纯元素氧化物或多元素氧化物合成方法配制标样,用基本参数法(FP)或理论α系数法校正残余基体影响。本文介绍以表观浓度概念为基础的宽范围氧化物分析方法,特别是以单元素或多元素氧化物合成的单点或多点标样校准仪器,取代多组分相似标样校准方法,实现精确的定量分析。根据冶金分析原辅材料的特点与要求,参照宽范围氧化物分析方法,加以适当的修改和调整,建立了一种以基本参数法为基础,适合于硅酸盐中多种氧化物的X-射线荧光光谱通用分析方法,用于对硅酸盐及碳酸盐类样品中氧化物的测定,结果与认定值均符合。 展开更多
关键词 表观浓度 宽范围氧化物 X-射线荧光光谱(XRF) 理论α系数 基本参数(FP) 熔融
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X射线荧光光谱法测定纯铜中微量杂质元素 被引量:4
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作者 宋洪霞 《冶金分析》 CAS CSCD 北大核心 2009年第8期56-62,共7页
对X射线荧光光谱法测定纯铜中微量杂质元素的实验条件,背景和光谱重叠干扰及校正进行研究。通过以纯铜标准样品绘制校准曲线,采用专用空白试样测量背景强度,多项式(多点)拟合计算峰底背景,专用的标准样品计算与分析线的重叠干扰量并加... 对X射线荧光光谱法测定纯铜中微量杂质元素的实验条件,背景和光谱重叠干扰及校正进行研究。通过以纯铜标准样品绘制校准曲线,采用专用空白试样测量背景强度,多项式(多点)拟合计算峰底背景,专用的标准样品计算与分析线的重叠干扰量并加以校正,理论α系数法或基本参数法校正样品中元素间的吸收-增强效应,选择高反射率的人工晶体PX-10测定部分重金属痕量元素,成功地用X射线荧光光谱法测定纯铜中微量杂质元素。样品的分析结果与推荐值或火花源原子发射光谱的测定值符合,回收率在95%~102%范围,各元素的相对标准偏差(RSD)均小于5.0%。 展开更多
关键词 X射线荧光光谱 纯铜 理论α系数 基体效应校正
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熔片法测地质样品中的多元素 被引量:2
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作者 江伟 杜婷婷 《新疆有色金属》 2007年第A01期82-82,84,共2页
采用熔融玻璃法,选用国家标准样品,用经验α系数法和理论α系数法校正谱线干扰及基体效应,用ARLADVANT`XP+型X射线光谱仪对样品中的Al2O3、K2O、Na2O、CaO、TFe2O3、SiO2、MnO、P2O5、MgO等组分进行分析,分析结果与标准值相符,12次测定... 采用熔融玻璃法,选用国家标准样品,用经验α系数法和理论α系数法校正谱线干扰及基体效应,用ARLADVANT`XP+型X射线光谱仪对样品中的Al2O3、K2O、Na2O、CaO、TFe2O3、SiO2、MnO、P2O5、MgO等组分进行分析,分析结果与标准值相符,12次测定的相对标准偏差小于10%。 展开更多
关键词 X射线荧光光谱仪 经验α系数 理论α系数 地质样 熔融
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Calculation of ion diffusion coefficient related to concrete deterioration based on Debye-Hückel-Onsager theory
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作者 左晓宝 孙伟 +1 位作者 李华 周文键 《Journal of Southeast University(English Edition)》 EI CAS 2010年第4期569-573,共5页
This paper applies the Debye-Hückel-Onsager electrolyte solution theory to investigate the diffusivity of ions in concrete pore solutions.First,a model of the diffusion coefficient associated with the ionic speci... This paper applies the Debye-Hückel-Onsager electrolyte solution theory to investigate the diffusivity of ions in concrete pore solutions.First,a model of the diffusion coefficient associated with the ionic species,solution concentration and ambient temperature is proposed in the saturated concrete.Secondly,as an example,the effects of sodium chloride solution concentration,which are associated with influencing factors such as the ionic cloud radius,electrophoresis and relaxation,on the chloride diffusion coefficient are analyzed.It is found that the diffusion coefficient decreases with the increase in solution concentration,and the electrophoresis and ionic cloud radius are two important factors influencing the ionic diffusivity.Finally,the experiments,in which the chloride diffusion coefficients in specimens under different water-cement ratios are measured by the rapid chloride migration(RCM)method,are carried out to validate the effectiveness of the proposed model,and the results indicate that there is a generally reasonable agreement between the experimental and the proposed model results. 展开更多
关键词 ion diffusion coefficient Debye-Hückel-Onsager theory rapid chloride migration(RCM)method CONCRETE
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General formulas for drag coefficient and settling velocity of sphere based on theoretical law 被引量:3
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作者 Yang Hongli Fan Minqiang +1 位作者 Liu Airong Dong Lianping 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2015年第2期219-223,共5页
The settlement of particles is of great importance in many areas. The accurate determination of drag coefficient and settling velocity in wide Reynolds number (Re) range remains a problem. In this paper, a series of... The settlement of particles is of great importance in many areas. The accurate determination of drag coefficient and settling velocity in wide Reynolds number (Re) range remains a problem. In this paper, a series of new formulas for drag coefficient of spherical particles based on theoretical laws, such as the Stokes law, the Oseen law, and the Goldstein law, were developed and fitted using 480 groups of experimental data (Re 〈 2 × 10^5). The results show that the 2nd approximation of a rational function containing only one parameter can describe Co-Re relationship accurately over the whole Re range of 0-2× 10^5. The new developed formulas containing five parameters show higher goodness over wide Re range than presently existing equations. The introduction of the Oseen law is helpful for improving the fitting goodness of the empirical formulas. On the basis of one of the Oseen-based Co-Re formulas giving the lowest sum of squared relative errors Qover the whole Re range (Re 〈 2 × 10^5), a general formula for settling velocity ut based on dimensionless parameters was proposed showing high goodness. 展开更多
关键词 Sphere Drag coefficient Settling velocity Reynolds number Theoretical equation
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Research on the fully fuzzy time-cost trade-off based on genetic algorithms 被引量:1
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作者 JIN Chao-guang JI Zhuo-shang +2 位作者 LIN Yan ZHAO Yuan-min HUANG Zhen-dong 《Journal of Marine Science and Application》 2005年第3期18-23,共6页
It is very difficult to estimate exact values of time and cost of an activity in project scheduling process because many uncertain factors, such as weather, productivity level, human factors etc. , dynamically affect ... It is very difficult to estimate exact values of time and cost of an activity in project scheduling process because many uncertain factors, such as weather, productivity level, human factors etc. , dynamically affect them during project implementation process. A GAs-based fully fuzzy optimal time-cost trade-off model is presented based on fuzzy sets and genetic algorithms (GAs). In tihs model all parameters and variables are characteristics by fuzzy numbers. And then GAs is adopted to search for the optimal solution to this model. The method solves the time-cost trade-off problems under an uncertain environment and is proved practicable through a giving example in ship building scheduling. 展开更多
关键词 fuzzy sets ranking fuzzy number genetic algorithms time-cost trade-off
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Filtering detecting signal of rockbolt with harmonic wavelet 被引量:5
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作者 WANG Jiyan ZHAO Yucheng +1 位作者 YAO Banghua XU Jinhai 《Mining Science and Technology》 EI CAS 2010年第3期411-414,共4页
Harmonic wavelets not only possess the traditional advantages of a wavelet function,they also have other merits such as clear expressions,more flexible time-frequency divisions,a simple transformation algorithm,a fine... Harmonic wavelets not only possess the traditional advantages of a wavelet function,they also have other merits such as clear expressions,more flexible time-frequency divisions,a simple transformation algorithm,a finer box-like frequency spectrum and others.Given the frequency distribution characteristics of the nondestructive testing signals from a rockbolt support system and based on the discrete harmonic wavelet transformation theory,we have effectively abstracted signals from frequency ranges concerned by removing useless high and low frequency signals from the testing signals of the rockbolt support system and obtained filtered signals with a reconstruction algorithm of harmonic wavelets.Finally,we applied the harmonic wavelet transformation in filtering analog signals and measured response signals of rockbolts.The results indicate that harmonic wavelets also have excellent filtering characteristics. 展开更多
关键词 rockbolt support system TESTING harmonic wavelet FILTERING
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用Simultix10X射线荧光光谱仪分析高合金钢
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作者 余群英 李新荣 《上海钢研》 1998年第6期44-47,共4页
本文叙述了用Rigaku Simultix 10型多道X射线荧光光谱仪分析钢铁及合金时,用理学软件中的L-T、DJ、JIS三种模式计算相应理论校正系数,分别进行了共存元素之间基体吸收—增强效应的校正,并用三种模式对不同基体钢铁试样进行了分析比较。
关键词 X射线荧光光谱 理论校正系数 高合金钢
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X—射线荧光光谱仪联机自动分析系统
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作者 才书林 郭玉林 《地质实验室》 1992年第4期252-256,221,共6页
关键词 X-射线荧光光谱仪 自动分析系统 软件 数据处理 理论影响系数 基本参数
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An analytical p-y curve method based on compressive soil pressure model in sand soil 被引量:1
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作者 JIANG Jie FU Chen-zhi +2 位作者 WANG Shun-wei CHEN Chao-qi OU Xiao-duo 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第6期1987-2004,共18页
With the high-quality development of urban buildings,higher requirements are come up with for lateral bearing capacity of laterally loaded piles.Consequently,a more accurate analysis to predict the lateral response of... With the high-quality development of urban buildings,higher requirements are come up with for lateral bearing capacity of laterally loaded piles.Consequently,a more accurate analysis to predict the lateral response of the pile within an allowable displacement is an important issue.However,the current p-y curve methods cannot fully take into account the pile-soil interaction,which will lead to a large calculation difference.In this paper,a new analytical p-y curve is established and a finite difference method for determining the lateral response of pile is proposed,which can consider the separation effect of pile-soil interface and the coefficient of circumferential friction resistance.In particular,an analytical expression is developed to determine the compressive soil pressure by dividing the compressive soil pressure into two parts:initial compressive soil pressure and increment of compressive soil pressure.In addition,the relationship between compressive soil pressure and horizontal displacement of the pile is established based on the reasonable assumption.The correctness of the proposed method is verified through four examples.Based on the verified method,a parametric analysis is also conducted to investigate the influences of factors on lateral response of the pile,including internal friction angle,pile length and elastic modulus of pile. 展开更多
关键词 laterally loaded piles compressive soil pressure model separation effect of pile-soil interface coefficient of circumferential friction resistance analytical p-y curve finite difference method
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An embedded estimating equation for the additive risk model with biased-sampling data 被引量:1
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作者 Feipeng Zhang Xingqiu Zhao Yong Zhou 《Science China Mathematics》 SCIE CSCD 2018年第8期1495-1518,共24页
This paper presents a novel class of semiparametric estimating functions for the additive model with right-censored data that are obtained from general biased-sampling. The new estimator can be obtained using a weight... This paper presents a novel class of semiparametric estimating functions for the additive model with right-censored data that are obtained from general biased-sampling. The new estimator can be obtained using a weighted estimating equation for the covariate coefficients, by embedding the biased-sampling data into left-truncated and right-censored data. The asymptotic properties(consistency and asymptotic normality) of the proposed estimator are derived via the modern empirical processes theory. Based on the cumulative residual processes, we also propose graphical and numerical methods to assess the adequacy of the additive risk model.The good finite-sample performance of the proposed estimator is demonstrated by simulation studies and two applications of real datasets. 展开更多
关键词 additive risk model biased-sampling data missing covariates estimating equation model checking
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