The methanol-to-gasoline (MTG) process is an efficient way to produce liquidfuel. The academic basis of the coal-to-liquid process is described and two different synthesis processes are focused on: Fixed MTG process a...The methanol-to-gasoline (MTG) process is an efficient way to produce liquidfuel. The academic basis of the coal-to-liquid process is described and two different synthesis processes are focused on: Fixed MTG process and Fluid Bed MTG process. Then,the superiority of the Fluid Bed MTG Process is pointed out relative to the Fixed MTGProcess. In addition, the development of the coal-to-liquid technique in China is brieflysummarized.展开更多
Influence of reaction temperature, pressure and space velocity on the direct synthesis of dimethyl ether (DME) from syngas is studied in an isothermal fixed-bed reactor. The catalyst is a physical mixture of C301 copp...Influence of reaction temperature, pressure and space velocity on the direct synthesis of dimethyl ether (DME) from syngas is studied in an isothermal fixed-bed reactor. The catalyst is a physical mixture of C301 copper-based methanol (MeOH) synthesis catalyst and ZSM-5 dehydration catalyst. The experimental results show that the chemical synergy between methanol synthesis reaction and methanol dehydration reaction is evident. The conversion of carbon monoxide is over 90%.展开更多
Transesterification is the most common production process for biodiesel. From this reaction, a glycerin phase is produced that is impure, thus lowering market value. However, because it is rich in carbon, it is an alt...Transesterification is the most common production process for biodiesel. From this reaction, a glycerin phase is produced that is impure, thus lowering market value. However, because it is rich in carbon, it is an alternative for generating bioproducts with a higher added value through bioconversion by microorganisms. The aim of this study was to screen parameters, such as pH (4, 5, 6, 7 and 8) and the initial glycerol concentration at 30 ± ℃ with agitation at 150 rpm for bioemulsifier and lipid synthesis in a submerged medium by Yarrowia lipolytica IMUFRJ 50678 from crude glycerin. The best conditions for bioemulsifier production were 30 ± ℃ at pH: 6 with 50 g/L of initial substrate, which produced 2.7 g/L of lipids, from which the optimum 300.5 mg/L of triglycerides was produced over 48 h of microorganism growth.展开更多
The process of production of lactide from butyl lactate was investigated. The process consists of two stages: oligomerisation of butyl lactatean and depolymerisation of oligomers. The type catalysts of the series of ...The process of production of lactide from butyl lactate was investigated. The process consists of two stages: oligomerisation of butyl lactatean and depolymerisation of oligomers. The type catalysts of the series of Lewis acid were tested. It was found that SnCI4 is the most efficient catalyst for both stages.展开更多
The scattering and resonance reactions of ^22Mg+p and ^22Mg+α play crucial roles for studying deeply not only in the structure of proton-rich nuclei of ^23A1 and ^26Si but also for the interest of astrophysics. It ...The scattering and resonance reactions of ^22Mg+p and ^22Mg+α play crucial roles for studying deeply not only in the structure of proton-rich nuclei of ^23A1 and ^26Si but also for the interest of astrophysics. It is believed that ^22Mg nucleus is a waiting point in the αp-process of nucleosynthesis in novae. We supposed to perform direct measurement the ^22Mg+α system in invert kinematics using radioactive ion (RI) beam. The ^22Mg beam of 3.73 MeV/u was produced at CRIB facility of the University of Tokyo located at RIKEN, Japan in 2011. In this paper, we report the results the scattering and resonance reactions with the alpha target. of the ^22Mg beam production used for the direct measurement of展开更多
文摘The methanol-to-gasoline (MTG) process is an efficient way to produce liquidfuel. The academic basis of the coal-to-liquid process is described and two different synthesis processes are focused on: Fixed MTG process and Fluid Bed MTG process. Then,the superiority of the Fluid Bed MTG Process is pointed out relative to the Fixed MTGProcess. In addition, the development of the coal-to-liquid technique in China is brieflysummarized.
文摘Influence of reaction temperature, pressure and space velocity on the direct synthesis of dimethyl ether (DME) from syngas is studied in an isothermal fixed-bed reactor. The catalyst is a physical mixture of C301 copper-based methanol (MeOH) synthesis catalyst and ZSM-5 dehydration catalyst. The experimental results show that the chemical synergy between methanol synthesis reaction and methanol dehydration reaction is evident. The conversion of carbon monoxide is over 90%.
文摘Transesterification is the most common production process for biodiesel. From this reaction, a glycerin phase is produced that is impure, thus lowering market value. However, because it is rich in carbon, it is an alternative for generating bioproducts with a higher added value through bioconversion by microorganisms. The aim of this study was to screen parameters, such as pH (4, 5, 6, 7 and 8) and the initial glycerol concentration at 30 ± ℃ with agitation at 150 rpm for bioemulsifier and lipid synthesis in a submerged medium by Yarrowia lipolytica IMUFRJ 50678 from crude glycerin. The best conditions for bioemulsifier production were 30 ± ℃ at pH: 6 with 50 g/L of initial substrate, which produced 2.7 g/L of lipids, from which the optimum 300.5 mg/L of triglycerides was produced over 48 h of microorganism growth.
文摘The process of production of lactide from butyl lactate was investigated. The process consists of two stages: oligomerisation of butyl lactatean and depolymerisation of oligomers. The type catalysts of the series of Lewis acid were tested. It was found that SnCI4 is the most efficient catalyst for both stages.
文摘The scattering and resonance reactions of ^22Mg+p and ^22Mg+α play crucial roles for studying deeply not only in the structure of proton-rich nuclei of ^23A1 and ^26Si but also for the interest of astrophysics. It is believed that ^22Mg nucleus is a waiting point in the αp-process of nucleosynthesis in novae. We supposed to perform direct measurement the ^22Mg+α system in invert kinematics using radioactive ion (RI) beam. The ^22Mg beam of 3.73 MeV/u was produced at CRIB facility of the University of Tokyo located at RIKEN, Japan in 2011. In this paper, we report the results the scattering and resonance reactions with the alpha target. of the ^22Mg beam production used for the direct measurement of