A discussion on producing agro-residue composites with isocyanate resins

With the urgent shortage of forest resource in China, using agro-residues as raw materials of composite become increasingly important. Agro-residue is the most potential fiber resource, which is helpful to sustainable development of composite industries in China. Based on a great deal of researches, this paper summarized and discussed some problems in using agro-residues as raw materials of composites, including raw material preparation, hot-pressing, bonding technology, preventing composite from going moldy. It is proposed that to manufacture the composite of rice straws or wheat straws, the isocayante resin is a suitable adhesive, and the appropriate technologies, bonding, and treatment measures are also needed.

Study and Application of Fingerprints of Ginkgo biloba Leaves Preparations

Aim To establish a method for determination of Ginkgo biloba L, its extractand preparations with HPLC fingerprints, so as to control the quality of the preparations. MethodsHPLC-DAD method was used to determine the constituents in preparations. Diamonsil? C_(18) (200mm X 4.6 mm, 5 μm) was used as analytical column, and acetonitrile/KH_2PO_4 was used as mobilephase with gradient elu-tion. The column temperature was at 24 ℃. The HPLC profile of chemicalconstituents of control sample and preparations were analyzed using similarity software. Results Thefingerprints of different preparations from different companies were slightly different because ofthe different preparing procedures. Mean while, the fingerprints of different batches of the samepreparation from the same company were similar to each other and the technology of each preparationwas stable. Conclusion This method is accurate, reproducible , simple, and can be used as ananalytical method for the routine quality control of Ginkgo biloba preparations.

时代与设计:新中国白酒包装演变研究

白酒是中国最具民族特色的产业之一。白酒包装也同酒文化一样，具有独特的民族性、文化性和时代性。每一个时代的酒包装设计都有其独特的内涵与特色，都具备符合当时消费理念的观念体系，都有自己品牌的历史发展传承，都满足当前时代的生产工艺，并深深烙印上鲜明的时代特点。酒包装设计以其独特的商品性，能够对品牌及所在国家、

Strategies and Suggestions for the Development of Mechanized Rapeseed Production in Sichuan

Mechanization is the future direction of rapeseed production in Sichuan. A series of technology tests for rapeseed mechanized production have been carried out in terms of variety selection, key agronomic measures and machinery in the main production area of Sichuan in recent years. In the research, the agronomic techniques, including variety selection for mechanical production, key agronomic measures and mechanical harvesting were analyzed. Based on the present condi- tions, strategy and suggestions for the development of mechanized rapeseed produc- tion in Sichuan also were presented.

Manifestations in Yield and Agronomic Traits of Sorghum 'Jia141' in Jiamusi Area

The suitable plant density was favorable for sorghum yield increase. In order to clarify the suitable plant density of dwarf-stem, early-maturing sorghum variety ＇Jiza141 ＇, in the open field condition,150 000, 200 000, 250 000, 300 000 and 350 000 plants/hm^2 tests were set to study the effect of different densities on yield and yield traits. The results showed that with the increase of planting density, LAI increased, chlorophyll content decreased, plant length had no significant difference, era length and era diameter tended to decrease, while biomass increased with the increase of density. The 1000-grain weight and single panicle weight had the maximum effects on yield, and both of them showed a significantly positive correlation with the yield. In Jiamusi growing areas, the optimal plant density of sorghum ＇Jiza141＇ was 200 000 plants/hm^2, and the yield could reach 9 183.00 kg/hm^2. The study provides a theo- retical basis and technical support for the ＇Jiza141＇ variety in the Jiamusi ecological region.

Advances in the production technology of hydrogen peroxide

This article mainly summarizes various aspects of hydrogen peroxide(H2O2)production through the anthraquinone route,including hydrogenation catalysts,working solution,regeneration technique,hydrogenation reactors,and environmental protection.The advances and breakthrough of SINOPEC in the production of H2O2 through the anthraquinone route is presented in this review,highlighting recent innovative technology on these aspects developed independently.The technical prospect and scientific challenges associated with the direct synthesis method from hydrogen and oxygen are also briefly discussed.

Advances in the Research and Development of Acrylic Acid Production from Biomass

The shortage of petroleum has resulted in worldwide efforts to produce chemicals from renewable resources. Among these attempts, the possibility of producing acrylic acid from biomass has caught the eye of many researchers. Converting the carbohydrates first to lactic acid by fermentation and then dehydrating lactic acid to acrylic acid is hitherto the most effective way for producing acrylic acid from biomass. While the lactic acid fer- mentation has been commercialized since longer times, the dehydration process of lactic acid is still under development because of its low yield. Further efforts should be made before this process became economically feasible. Because of the existence of acrylic acid pathways in some microorganisms, strain improvement and metabolic engineering provides also a possibilitv to produce acrylic acid directly from biomass by fermentation.

Kinetics of Levulinic Acid Formation from Glucose Decomposition at High Temperature

Levulinic acid is a kind of new green platform chemical with wide application. The kinetics of levulinic acid formation from glucose decomposition at high temperature was investigated. Glucose containing 1%, 3% or 5% H2SO4 was treated at 170℃ or 190℃. For the various experimental conditions assayed, the time-courses of glucose and glucose degradation products (including 5-hydroxymethylfurfural and levulinic acid) were established. These variables were cor-related with the reaction time based on the equations derived from a pseudo-homogeneous, first-order kinetic model, which provided a satisfactory interpretation of the experimental results. The set of kinetic parameters from regression of experimental data provided useful information for understanding the levulinic acid formation mechanism.

Exergy Analysis and Retrofitting of Natural Gas-based Acetylene Process

This article presents an acetylene production process by partial oxidation/combustion of natural gas. The thermodynamic performance and exergy analysis in the process are investigated using the flow-sheeting program Aspen Plus. The results indicate that the most important destruction of exergy is found to occur in the reactor and water quenching scrubber, amounting to 8.23% and 10.39%, respectively, of the entire system. Based on the results of thermodynamic and exergy analysis, the acetylene reactor has been retrofitted. The improvement ratios of molar 02 to CH4 and molar CO to CN4 are 0.65 and 0.20, respectively. An improvement of the acetylene production system is proposed. Adopting the improvement operation conditions and using oil to realize the reaction heat recovery, the feedstock of natural gas is reduced by 9.88% and the exergy loss in the retrofitting process is decreased by 19.71% compared to the original process.

The Characteristics of a Sorption-enhanced Steam-Methane Reaction for the Production of Hydrogen Using CO_2 Sorbent

The objective of the present study is to characterize the production of hydrogen with a sorptionenhanced steam-methane reaction process using Ca(OH)2 as the CO2 adsorbent. Theoretical equilibrium compositions at different operation conditions were calculated using an iterative method. It was found that with Ca(OH)2 as the CO2 sorbent, the concentration of CO2 adsorption was reduced in the product stream, that gave rise to higher methane conversion and higher H2 concentration. An experimental setup was built to test the theoretical calculation. The effects of sorbents and the particle size of Ca(OH)2 on the concentration of CO2 and H2 were investigated in detail. Results showed that the reactor packed with catalyst and Ca(OH)2 particles produced H2 concentration of 94%. It was nearly 96% of the theoretical equilibrium limit, much higher than H2 equilibrium concentration of 67.5% without CO2 sorption under the same conditions of 500℃, 0.2 MPa pressure and a steam-to-methane ratio 6. In addition, the residual mole fraction of CO2 was less than 0.001.

Recovery of coal particles from a tailing dam for environmental protection and economical beneficiations

Considerable amounts of coal particles are accumulated in the tailing dams of washing plants which can make serious environmental problems. Recovery of these particles from tailings has economically and environmentally several advantages. Maintaining natural resources and reducing discharges to the dams are the most important ones. This study was examined the possibility to recover coal particles from a tailing dam with 56.29% ash content by using series of processing techniques. For this purpose, gravity separation （jig, shaking table and spiral） and flotation tests were conducted to upgrade products. Based the optimum value of these processing methods, a flowsheet was designed to increase the rate of recovery for a wide range of coal particles. Results indicated that the designed circuit can recover over 90% of value coal particles and reduce ash content of product to less than 14%. These results can potentially be used for designing an industrial operation as a recycling plant and an appropriate instance for other areas to reduce the environmental issues of coal tailing dams.

Effect of hydrodynamic desulphurisation of low parameters on the oxidative rank coal

In this paper, the desulphurisation of high sulphur low-rank coal is proposed as a raw material for pulverised coal injection technology. Therefore, the influence of oxidant linear velocity and the size of the coal grain was investigated in a fluidised bed. The hydrodynamic parameters of the fluidised bed including： porosity, Sherwood criterion （diffusion Nusselt number）, and mass transfer coefficient （external surface） were calculated. Furthermore, the study examined the effects of intensity and efficiency on the desulphurised coal properties; organic matter, ash, and volatile matter contents. The key changes during the conversion of pyritic sulphur and coal organic matter were subsequently examined. The results showed that the sulphur content （St^d 3.16 wt%） of the low-rank coal, was transformed to （St^d 〈 1.5 wt%） after desulfurization. Other enhanced properties were： V^daf ≤ 38.0 wt%; A^d 〈 10.0 wt%, now suitable for pulverised coal injection technology.

A Hybrid Model Predictive Control for Handling Infeasibility and Constraint Prioritization

A hybrid approach using MLD (mixed logical dynamical) framework to handle infeasibility and constraint prioritization issues in MPC (model predictive control) based on input-output model is introduced. By expressing constraint priorities as propositional logics and by transforming the propositional logics into inequalities,the infeasibility and constraint prioritization issues are solved in the MPC. Constraints with higher priorities are met first, and then these with lower priorities are satisfied as much as possible. This new approach is illustrated in the control of a heavy oil fractionator-Shell column. The overall control performance has been significantly improved through the infeasibility and control priorities handling.

A Novel Method for Production of 3-Hydroxydecanoic Acid by Recombinant Escherichia coli and Pseudomonas putida

3-hydroxydecanoic acid (3HD) is an interesting intermediate for chemical synthesis of many valuable compounds. A novel method to produce 3HD by recombinant bacteria was constructed in Escherichia coli HB101 and Pseudomonas putida GPpl04, respectively. Simultaneous expression of both phaG encoding (R)-3-hydroxydecanoyl-ACP:CoA transacylase and tesB encoding thioesteraseⅡin E. coli HB101 increased 3HD production approximate 1.7-folds compared with the expression of phaG gene alone under identical conditions. In addition, when the tesB gene was introduced into the strain, the polyhydroxyalkanoate synthase negative strain P. putida GPpl04 produced extracellular 3HD. Thus, a novel pathway to produce 3HD by recombinant Pseudomonas was constructed. It was also found that the ratio of carbon source to nitrogen source affected the production of 3HD by recombinant P. putida harboring tesB gene. Nitrogen limitation seemed to promote the extracellular 3HD production.

Chemical Reaction Route Selection Based on Green Chemical Engineering

In the preliminary stage of chemical process design, the choice of chemical reaction route is the key design decision, and the concepts of atom utilization and environmental quotient have become extremely useful tools. However, the waste quality such as chemical toxicity and other engineering factors have not been taken into account. Therefore, a synthetic route selection index, Iroute, is proposed to determine the suitability of a chemical route in this paper. Iroute considers the effects of 'extended atom economy', material renewability, chemical characteristics and some engineering factors. The extended atom economy concept regards not only the value of the desired product but also the value of byproducts. The methodology by using Iroute to compare different routes is illustrated in case study of cyclohexanone oxime and acrylonitrile manufacture.

Commercial Application of Novel FDFCC Grid Packing Type Stripper

The novel FDFCC grid packing stripper is used to raise the stripping efficiency of the equipment. This technology aims to increase the gas-solid contact area and improve the gas-solid contact efficiency. This technology has been applied in the revamped 1.05 Mt/a No. 1 FCC unit at the SINOPEC Changling Branch Company. The outcome on application of this equipment has revealed that the fluidization of the stripper was stable coupled with smooth operation. At a steam stripping load of less than 50% of the design value the spent catalyst had a lower H/C ratio, and the hydrogen content in the coke after revamp of the FCC unit decreased by 8.1% compared to the case before the equipment revamp. The spent catalyst had higher activity with the dry gas and coke yields reduced by over 0.5%, resulting in goodeconomic benefits.

CO_2 Emissions Embodied in China-U.S.Trade

After the Kyoto Protocol was implemented,carbon leakage exerts great influences on international trade and economy.Trade creates a mechanism for consumers to shift environmental pollution associated with their consumption to other countries.China has overtaken the U.S.as the world's biggest CO2 emitter since 2006.As China's second largest trade partner,the U.S.has the biggest trade deficit with China which has aroused a lot of disputes between the two parties.But so far the assessments of the trade imbalance of China-U.S.have paid little attention to environmental impacts associated with the trade imbalance.Applied an input-output approach,the article estimates the amount of CO2 embodied in China-U.S.trade during 1997-2007.It was found that through trade with China,the U.S.reduced its CO2 emissions compared with a non-trade scenario.Due to the greater carbon-intensity and relatively less efficient production processes of Chinese industry,China-U.S.trade resulted in more CO2 emissions in China and the world.In the end,the article gives some suggestions:it is equal and sustainable that the international accounting methodologies should be improved,for CO2 emissions responsibility must be designed to account for the dynamic nature of international trade.

Novel Ferricenium Tetrafluoroborate Salt as Latent Thermal Cationic Initiator for Curing of Epoxy Resins

A novel latent thermal initiator, ferricenium tetrafluoroborate salt (FcBF4), for cationic polymerization of epoxides is reported. The activities of FcBF4 for different epoxides, including bisphenol-A-type epoxy oligomer E44, cycloaliphatic epoxy ERL4221, and glycidylether epoxy GGE, were evaluated by differential scanning calorimetry (DSC). The results showed a moderate thermal initiation activity for E44 and GGE at 78℃ and 108℃ respectively. When adding GGE to E44, the reaction was enhanced. The temperature of thermal degradation of the cured specimens for the system of E44/FcBF4, E44+10%GGE/FcBF4 and E44+10%ERL4221/FcBF4 is higher than 350℃.

Nwomu： Hand-Made Embroidery Technique in Asanteland

The study sought to investigate the historical background of the traditional hand-made embroidery technique, the production process, and its changing trends amongst the Asantes of Ghana. Interview and observation were used in collecting the needed data at selected craft centres in the Kwabre East District, Ejisu-Juaben municipality, Kumasi sub-metro and metropolitan in the Ashanti region of Ghana. The study employed both descriptive and experimental research methods based on the qualitative research approach. It was revealed that Kente and Adinkra enjoy wide reputation and therefore are considered as prestigious clothes. However, Nwomu cloth does not have this fame, only indigenes understand its usage and the philosophy behind its production. In view of this, it is recommended that the elders who are endowed with this unique craft must open their doors to the youth to learn the craft.

Effects of Different Biochar Dosages and Types on Growth, Yield and Output Value of Flue-cured Tobacco in Hanzhong Area

[Objective] This study was to investigate the effects of different biochar dosages and trpes on growth, yield and output value of flue-cured tobacco in Hanzhong. [Methods] In May-September of 2013, Xiaonanhai Town, Nanzheng County, Hanzhong City, a field experiment was carded out to study the effects of- biochardosage and type on tobacco agronomic traits, yield and output value in each growth period. [Results] Biochar application significantly increased plant height, stem diameter and leaf size in the early growth pedod, and raised tobacco yield, output value and the proportion of high grade leaf： With the increase of biochar dosage, tobacco agronom~ traits were significantly improved, and yield, output value and proportion of high-grade tobacco leaves also increased significantly, and the highest tobacco yield and output value occurred at the dosage of 900 kg/hm2. Agronomic traits of tobacco leaves with the application of rice husk char and wheat straw char were significantly better than those with the application of peanut shell char, appli- cation of rice husk char was more conducive to the development of leaves in the vigorous pedod and stems in the squaring period, but straw char was beneficial to improvement of plant height and leaf number in the vigorous period and leaf growth in the squaring period, and application of rice husk char had the best effect on the increases of yield and output value of tobacco leaves. [Conclusion] Application of biochar is an effective measure forimproving tobacco-planting soil and promoting the growth and development of tobacco in Hanzhong, biochar application amount should be controlled at about 600-900 kg/hm2, and rice husk char is the preferred choice as soil improvement material.